1,2-Bis(Dimethylphosphino)Ethane 1,2-双（二甲基瞵）乙烷

CAS 23936-60-9 MFCD00008511

化学结构图

23936-60-9
SMILES: CP(C)CCP(C)C

化学属性

Refractive indexn20/D 1.507(lit.)
TSCANo
Melting Point179-180°
Mol. FormulaC6H16P2
Mol. Weight150.14
Density0.90
Flash Point2°F
Appearance colorless liq.
Stabilityair sensitive
Boiling Point180°C

别名和识别编码

Chemical Name1,2-Bis(Dimethylphosphino)Ethane
Synonym 1,2-双(二甲基磷)乙烷 DMPE Dimethyl-2-(dimethylphosphino)ethylphosphine 乙烯双(二甲膦) 乙烯双(二甲膦) 1,2-双(二甲基膦)乙烷 Dimethyl-2-(dimethylphosphino)ethylphosphine DMPE Dimethyl-2-(dimethylphosphino)ethylphosphine; Ethylenebis(dimethylphosphine)
PubChem Substance ID87564114
Beilstein Registry Number1732994
Chemical Name Translation1,2-双（二甲基瞵）乙烷
Reaxys-RN1732994
MDL NumberMFCD00008511
CAS Number23936-60-9
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
Signal word Danger
Packing GroupII
UN Number 1993 UN1993
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S37 Wear suitable gloves 戴适当手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Storage condition Moisture Sensitive
Hazard Codes F,Xi
Hazard Class3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Polydentate Phosphine Ligands 多齿膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Polydentate Phosphine Ligands 多齿膦配体
  1. Analytical & Chromatography 分析化学与色谱
  2. Ligands for Pharmaceutical Research
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphorus Precursors
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  3. Bridged Phosphine Ligands

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