Ditin butyl dilaurate 二月桂酸二丁基锡

CAS 77-58-7 MFCD00008963

化学结构图

77-58-7
SMILES: CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC

化学属性

Mol. FormulaC32H64O4Sn
Mol. Weight631.56
Density1.066
Refractive index1.4670 to 1.4710
Vapor Pressure0.2 mmHg ( 160 °C)
Flash Point236°C(lit.)
SolubilitySoluble in benzene and ether. Insoluble in water and methanol
TSCAYes
Boiling Point>204°/12mm
Melting Point<10°

别名和识别编码

Chemical NameDitin butyl dilaurate
Synonym Bis(lauroyloxy)di(n-butyl)stannane Butynorate Cata-Chek 820 DBTL DIBUTYLTIN DIDODECANOATE DIBUTYLTIN DILAURATE DIBUTYLTIN LAURATE Davainex Di-n-b Di-n-butyltin didodecanoate Dibutylstannium dilaurate Dibutyltin dilaurate Dibutyltin laurate Fomrez sul-4 Kosmos 19 Lauric acid, dibutylstannylene salt Lauric acid, dibutyltin deriv. Ongrostab BLTM SM 2014C Stabilizer D-22 Stanclere DBTL Stavincor 1200 SN TN 12 Thermolite T 12 Tin dibutyl dilaurate Tinostat davainex 二丁基二月桂酸锡 二月桂酸二丁基锡 二月桂酸二丁基锡/T12 二月桂酸二正丁基锡 月桂酸二丁基锡
CAS Number77-58-7
EC Number201-039-8
Beilstein Registry Number4156980
MDL NumberMFCD00008963
PubChem Substance ID87566998
Merck Number3038
Reaxys-RN4156980
Chemical Name Translation二月桂酸二丁基锡
Wiswesser Line Notation11VO-SN-4&4&OV11
LabNetwork Molecule IDLN01741332
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分类

  • {SNA} Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Organometallic Reagents, Organotin, Organotins
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins

产品应用

  • 用于有机合成,用作聚氯乙烯树脂的稳定剂。

相关文献及参考

  • Accelerator for polyurethane resins.
  • Merck: 14,3038

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R26 Very toxic by inhalation 吸入极毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R50/53
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P304+P340+P310
  • P305+P351+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H315 Causes skin irritation 会刺激皮肤
  • H330 Fatal if inhaled 吸入致命
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H370 Causes damage to organs 导致器官损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSWH7000000
Packing GroupIII
UN Number 2788 2922 UN 2922 8/PG 3
Hazard Codes 8 T,C,N
Storage condition 阴凉通风处存储。
Hazard Class6.1
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 175 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 10,44,1960

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 85 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 10,16,1955

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Gastrointestinal - hypermotility, diarrhea
   Skin and Appendages - dermatitis, other (after systemic exposure)
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555424

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50532 ug/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 85,149,1993

Restrict 危险品

其他信息

  • 有机锡添加剂:二月桂酸二丁基锡 是一种有机锡添加剂,能溶于苯、甲苯、四氯化碳、乙酸乙酯、氯仿、丙酮、石油醚等有机溶剂和所有工业增塑剂,不溶于水。市面上流 通的高沸点多用途有机锡催化剂二月桂酸二丁基锡通常都是经过特殊液化处理的,常温下为浅黄色或无色油状液体,低温成白色结晶体,可用于聚氯乙烯塑料助剂 ,具有优良的润滑性、透明、耐候性。耐硫化物污染较好。在软质透明制品中作稳定剂,在硬质透明制品中作高效润滑剂,还可用作丙烯酸酯橡胶和羧基橡胶交联 反应、聚氨酯泡沫塑料合成及聚酯合成的催化剂,室温硫化硅橡胶催化剂。
  • 灭火剂:二氧化碳、砂土、水、泡沫
  • 方法一:由氧化二丁基锡和月桂酸在60℃左右缩合而成。缩合后,减压脱水,冷却,压滤即得成品。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 可燃性危险特性:明火可燃
  • 急性毒性:口服-大鼠 LD50: 175 毫克/公
  • 刺激数据:皮肤-兔子 100 毫克/24小时 中度
  • 蒸气压:0.2 mm Hg ( 160 °C)
  • 用途三:可用作聚氯乙烯的热稳定剂,是有机锡类稳定剂中使用最早的品种,耐热必不及马来酸丁基锡,但润滑性优良,耐候性和透明性亦可,与增塑剂有良好的相容性,不喷霜,无硫化污染性,对热合性和印刷性无不良影响。又因其在常温下为液体,故在塑料中的分散性较固体稳定剂好。该品主要用于软质透明制品或半软质制品,一般用量为1-2%。与硬脂酸镉、硬脂酸钡等金属皂或环氧化合物并用有协同效应。在硬质制品中,该品可作为润滑剂,与马来酸有机锡或硫醇系有机锡并用,改善树脂料的流动性。与其他有机锡相比,该品的初期着色性较大,会造成发黄变色。该品还可以用作聚氨酯材料合成时的催化剂,硅橡胶的熟化剂。为的提高本品的热稳定性、透明性、与树脂的相容性,以及提高其用于硬质制品时的冲击强度等性能,现已发展了许多改性品种。一般是在纯品中加入月桂酸之类的脂肪酸,有的还加入环氧酯或其他金属皂类稳定剂等。该品有毒。大白鼠经口LD50为175mg/kg。
  • 类别:有毒物品
  • 图谱信息:二月桂酸二丁基锡(77-58-7)红外图谱(IR1) 二月桂酸二丁基锡(77-58-7)核磁图( 1 HNMR) 二月桂酸二丁基锡(77-58-7)质谱(MS) 二月桂酸二丁基锡(77-58-7)核磁图( 13 CNMR)
  • 二月桂酸二丁基锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80044627 二丁基二月桂酸锡;月桂酸二丁基锡 250g 64.4元 2011/04/16 D0303 二月桂酸二丁基锡 Dibutyltin Dilaurate 500G 1160元 2011/04/16 D0303 二月桂酸二丁基锡 Dibutyltin Dilaurate 25G 215元
  • 用途二:用作聚氯乙烯的热稳定剂、硅橡胶的熟化剂、聚氨酯泡沫塑料的催化剂等
  • F:10-21
  • 外观性质:无色到淡黄色结晶或黄色液体。
  • TSCA:Yes
  • Sigma Aldrich:77-58
  • MOL 文件:77-58-7.mol
  • 用途四:用于有机合成,用作聚氯乙烯树脂的稳定剂。
  • 下游产品:聚氨酯涂饰剂PUC系列 --> QD-200系嵌段甲基室温硫化硅橡胶粘合剂
  • A
  • 职业标准:TWA 0.1 毫克 (锡)/立
  • 不溶于水、甲醇、溶于乙醚、丙酮、苯、四氯化碳、石油醚、酯。
  • 凝固点:8℃
  • MSDS 信息:二丁基二月桂酸锡(77-58-7).msds
  • 毒性分级:高毒
  • 上游原料:月桂酸 --> 二丁基氧化锡 --> 四丁基锡
  • TCI Shanghai:二月桂酸二丁基锡 Dibutyltin Dilaurate(77-58-7)
  • 用途一:用作塑料稳定剂、橡胶熟化剂

系列性分类


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