Triethoxyvinylsilane 乙烯基三乙氧基硅烷

CAS 78-08-0 MFCD00009063

化学结构图

78-08-0
SMILES: C=C[Si](OCC)(OCC)OCC

化学属性

Mol. FormulaC8H18O3Si
Mol. Weight190
Density0.903
Refractive index1.3980 to 1.4000
Boiling Point160-161
Flash Point34°C(lit.)
TSCAYes
Solubility分解
Stability对湿度敏感
Melting Point<0°C

别名和识别编码

Chemical NameTriethoxyvinylsilane
Synonym (Triethoxysilyl)ethylene,Vinyltriethoxysilane A 151 CV-4910 Dynasylan VTEO Dynasylan VTEU Ethenyltriethyloxy-silane Ethenyltriethyloxy-silane; VTEO KBE 1003 NV 1107 Polyscience VTES Silane A 151 Silane, ethenyltriethoxy- Silane, triethoxyvinyl- Silquest A 151 TRIETHOXYVINYLSILANE TSL 8311 V 4910 VINYLTRIETHOXYSILANE YGO 1203 ethenyltriethoxy-Silane ethenyltriethoxy-silan nv1107 silane,vinyltriethoxy1-151 triethoxy-vinyl-silane {} {} {ALF} 三乙氧基乙烯基硅烷 三乙氧基乙烯基硅烷,(三乙氧基甲硅烷基)乙烯 三乙氧基乙烯硅烷 乙烯三乙氧基硅烷 乙烯基三乙氧基硅烷 乙烯基三乙氧基硅烷, 97%
CAS Number78-08-0
EC Number201-081-7
Beilstein Registry Number1767229
MDL NumberMFCD00009063
PubChem Substance ID6516
Reaxys-RN1767229
Chemical Name Translation乙烯基三乙氧基硅烷
Wiswesser Line Notation2O-SI-O2&O2&1U1
LabNetwork Molecule IDLN00225127
InChIInChI=1S/C8H18O3Si/c1-5-9-12(8-4,10-6-2)11-7-3/h8H,4-7H2,1-3H3
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分类

  • {SNA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Silanes, Silicon, Solution Deposition Precursors, Trialkoxysilanes
  • {SNA} Chemical Synthesis, Micro/NanoElectronics, Nanomaterials, Organometallic Reagents, Organosilicon, POSS Precursors and Intermediates, RSi(OR&#8243;)3, Self Assembly and Lithography, Self-Assembly Materials, Silane Coupling Agents/Adhesion Promoters, Silanes, Silsesquioxanes: POSS Nanohybrids, Tri-Alkoxy & Greater Silanes, Trialkoxysilanes, 材料科学
  • {SNA} Chemical Synthesis,

产品应用

  • 憎水剂。玻璃布表面处理剂。无线电零件的防潮绝缘材料等。

相关文献及参考

  • Beilstein: 4,IV,4256
  • O-Protected 2-hydroxyacetophenones can be ortho-alkylated in the presence of a ruthenium catalyst to give the 6-(triethoxysilylethyl) derivatives in moderate to high yields: J. Organomet. Chem., 506, 339 (1996).
  • Short: EINECS
  • Short: III/35E

安全信息

Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV6700000
Packing GroupIII
UN Number 1993
Storage condition Moisture Sensitive 对湿度敏感,密封保存。 Flammables area
Hazard Codes 3
Hazard Class3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 23 gm/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JBMRBG Journal of Biomedical Materials Research.  (John Wiley & Sons, Inc.,
   605 Third Ave., New York, NY 10158)  V.1-    1967- Volume(issue)/page/year:
   8,11,1974

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5700 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JBMRBG Journal of Biomedical Materials Research.  (John Wiley & Sons, Inc.,
   605 Third Ave., New York, NY 10158)  V.1-    1967- Volume(issue)/page/year:
   8,11,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JBMRBG Journal of Biomedical Materials Research.  (John Wiley & Sons, Inc.,
   605 Third Ave., New York, NY 10158)  V.1-    1967- Volume(issue)/page/year:
   8,11,1974

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其他信息

  • 乙烯基三乙氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80149328 乙烯基三乙氧基硅烷;三乙氧基乙烯基硅烷;(三乙氧基甲硅烷基)乙烯 500ml 307元 2011/04/16 V0044 三乙氧基乙烯基硅烷 Triethoxyvinylsilane 500ML 814元 2011/04/16 V0044 三乙氧基乙烯基硅烷 Triethoxyvinylsilane 25ML 131元
  • TCI Shanghai:乙烯基三乙氧基硅烷 Triethoxyvinylsilane,>;98.0%(GC)(78-08-0)
  • MSDS 信息:乙烯三乙氧基硅烷(78-08-0).msds
  • 毒性分级:低毒
  • 用途二:用作憎水剂和玻璃布表面处理剂
  • Alfa Aesar:乙烯基三乙氧基硅烷,97% Vinyltriethoxysilane, 97%(78-08-0)
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧排放刺激烟雾
  • 用途四:兼有偶联剂和交联剂的作用,适用的聚合物类型有聚乙烯、聚丙烯、不饱和聚酯等,常用于玻纤、塑料、玻璃、电缆、陶瓷、橡胶等。
  • 灭火剂:泡沫、二氧化碳、砂土
  • 用途五:憎水剂。玻璃布表面处理剂。无线电零件的防潮绝缘材料等。
  • 类别:可燃物品
  • 图谱信息:乙烯基三乙氧基硅烷(78-08-0)红外图谱(IR1) 乙烯基三乙氧基硅烷(78-08-0)核磁图( 1 HNMR) 乙烯基三乙氧基硅烷(78-08-0)核磁图( 13 CNMR) 乙烯基三乙氧基硅烷(78-08-0)质谱(MS) 乙烯基三乙氧基硅烷(78-08-0)红外图谱(IR2)
  • TSCA:Yes
  • 储运特性:包装完整、轻装轻卸; 库房通风、远离明火、高温、与氧化剂分开存放
  • Acros Organics:乙烯基三乙氧基硅烷 Triethoxyvinylsilane, 97%(78-08-0)
  • F:21
  • 用途一:作为RTV单组份硅橡交联剂,(醇型),作为交联剂应用在聚合物中(如PE)
  • 上游原料:乙醇
  • 具有酯味。对湿敏感,在空气中遇水蒸气缓慢水解,生成相应硅醇。能与乙醇、乙醚和苯混溶,不溶于水。易燃。
  • 下游产品:2-(二苯基羟亚膦基)乙基三乙氧基硅烷
  • 刺激数据:皮肤- 兔子 500 毫克 轻度; 眼- 兔子 500 毫克/ 24小时 轻度
  • 外观性质:无色透明液体。
  • 用途三:广泛用于硅烷交联聚乙烯电缆和管材
  • 急性毒性:口服- 大鼠 LD50: 22500 毫克/ 公斤
  • Sigma Aldrich:78-08-0(sigmaaldrich)
  • MOL 文件:78-08-0.mol
  • 敏感性:Moisture Sensitive
  • 海关编码:29310095

系列性分类


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