Methyl oleate 油酸甲酯

CAS 112-62-9 MFCD00009578

化学结构图

112-62-9
SMILES: CCCCCCCC/C=C\CCCCCCCC(=O)OC

化学属性

Mol. FormulaC19H36O2
Mol. Weight296
Refractive index1.4510 to 1.4530
Density0.874
Flash Point159°C(lit.)
TSCAYes
Boiling Point218
Vapor Pressure10 mmHg ( 205 °C)
Melting Point-20
Stability对热、光线、空气敏感
Appearance 微黄色油状液体。熔点-19.9℃，沸点218.5℃（2.66kPa），168-170℃（0.267kPa）。相对密度0.8739（20/4℃）。折光率1.4522。能与无水乙醇；乙醇混溶于水。
pH:A

别名和识别编码

Chemical NameMethyl oleate
Synonym CIS-9-OCTADECENOIC ACID METHYL ESTER methyl oleate Emery, oleic acid ester 9-Octadecenoic acid (Z)-, methyl ester Ölsäuremethylester cis-9-Octadecenoic acid methyl est C19H36O2 (cis-octadec-9-enoic acid 9-Octadecenoic ac DELTA 9 CIS OCTADECENOIC ACID METHYL ESTER elaidic acid methyl este {Chemi Methyl cis-9-octadecenoate; (Z) 顺式-9-十八碳烯酸甲酯 cis-9-Octyldecenoic acid, methyl ester Methyl cis-9-octadecenoate 顺-9-十八碳烯酸甲酯 {uni_ha oleic acid methyl ester 油酸甲酯 octadec-9c-enoic acid methyl ester CIS-OLEIC ACID METHYL ESTER C18:1 (CIS-9) METHYL ESTER 顺式-9-十八碳烯酸甲酯;(Z)-9-十八烯酸甲酯;十八烯酸甲脂 9-octadecenoicacid(cis),methylester METHYL OCTADECENOATE Witconol 2301 Ölsäure-methylester Methyl cis-9-octadecenoate Exceparl M-OL Edenor MeTiO5 Emery oleic acid ester 2301 Esterol 112 cis-octadec-9-enoicacidmethylester Priolube 1403 顺式-9-十八碳烯酸甲酯 ；(Z)-9-十八烯酸甲酯；十八烯酸甲脂 {uni_ methyl (Z)-octadec-9-enoate cis-octadec-9-enoic acid Oelsäuremethylester METHYL 9-OCTADECENOATE (Z)-9-Octadecenoic acid methyl ester Oleic acid, methyl ester, cis- EMERY OLEIC ACID ESTER Methyl 9-octadecenoate Emerest 2301 油酸甲酯, TECH (Z)-9-Octadec Methyl (Z)-9-octadecenoate Methyl
CAS Number112-62-9
EC Number203-992-5
Reaxys-RN1727037
Beilstein Registry Number1727037
PubChem Substance ID5364509
MDL NumberMFCD00009578
Merck Number6828
Chemical Name Translation油酸甲酯
Wiswesser Line Notation9U8VO1 -C
LabNetwork Molecule IDLN00194955
InChIInChI=1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h10-11H,3-9,12-18H2,1-2H3/b11-10-
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分类

  • {SNA} Aloe Vera, Biochemicals and Reagents, Building Blocks, C12 to C63, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Esters, Fatty Acids and conjugates, Fatty Acyls, Lipids, Methyl Esters, Nutrition Research, Organic Building Blocks, Phytochemicals by Plant (Food/Spice/Herb), Unsaturated Fatty Acids and Derivatives
  • {SNA} Aloe Vera, Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Esters, Fatty Acids and conjugates,
  • {SNA} Aloe
  • {SNA} Building Blocks,

产品应用

  • Used as a chromatographic reference standard in biochemical research.

相关文献及参考

  • Short: IV/15A
  • Merck:14,6828 Beilstein: 2,IV,1649
  • Merck:14,6828
  • Short: III/38B

安全信息

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes F,Xn,N
GHS Symbol
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
Signal word Danger Warning
WGK Germany1
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves
RTECSRK0895000
Storage condition -20°C 储存温度2-8℃ 储存温度-20℃,充氩保存 0-10°C 0-10 储存温度-20°C 密封保存。99%规格 -20°C保存
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R38 Irritating to skin 刺激皮肤
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R50/53
  • R11 Highly flammable 非常易燃
UN Number UN 1206 3/PG 2 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 54 gm/kg/45W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - leukemia
   Skin and Appendages - tumors
REFERENCE :
   AMBPBZ Acta Pathologica et Microbiologica Scandinavica, Section A:
   Pathology.  (Copenhagen, Denmark) V.78-89, 1970-81.  For publisher
   information, see ACPADQ.  Volume(issue)/page/year: 82,127,1974

其他信息

  • TCI Shanghai:(Z)-9-十八烯酸甲酯[标准物质] Methyl Oleate [Standard Material],>;99.0%(GC)(112-62-9)
  • 用途四:去垢剂、乳化剂、润湿剂及稳定剂的中间体。生化研究。气相色谱固定液(最高使用温度120℃，溶剂为乙醚)。气相色谱分析标准。
  • 蒸气压:10 mm Hg ( 205 °C)
  • MSDS 信息:(Z)-9-Octadecenoic acid methyl ester(112-62-9).msds
  • F:8-23
  • 能与无水乙醇和乙醚混溶，不溶于水。
  • Alfa Aesar:油酸甲酯,tech.75% Methyl oleate, tech. 75%(112-62-9)
  • 用途二:用作塑料增塑剂、抗水剂、树脂的韧化剂，也用于有机合成
  • 方法一:由甲醇与油酸经酯化而得。将油酸和甲醇混合，加入催化剂浓硫酸或对甲苯磺酸，加热回流10h。冷却，用甲醇钠中和至pH值为8-9℃，用水洗至中性，经无水氯化钙干燥后进行减压蒸馏，即得油酸甲酯。
  • Sigma Aldrich:112-62-9(sigmaaldrich)
  • 用途三:该品是去垢剂、乳化剂、润湿剂及稳定剂的中间体。
  • 图谱信息:油酸甲酯(112-62-9)质谱(MS) 油酸甲酯(112-62-9)红外图谱(IR1) 油酸甲酯(112-62-9)核磁图( 1 HNMR) 油酸甲酯(112-62-9)核磁图( 13 CNMR)
  • Acros Organics:油酸甲酯/顺-9-十八碳烯酸甲酯 Methyl oleate, tech.(112-62-9)
  • 海关编码:29161500
  • MOL 文件:112-62-9.mol
  • 用途一:用作表面活性基础原料、皮革添加剂、石油勘探无荧光泥浆润滑剂
  • 下游产品:催杀 --> 催杀
  • 上游原料:甲醇 --> 对甲苯磺酸 --> 甲醇钠 --> 顺式十八碳-9-烯酸 --> 对甲苯
  • 油酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 40033381 油酸甲酯 5ml 1400元 2011/08/23 K7516001 油酸甲酯标准品 1ml 799元 2011/04/16 O0055 油酸甲酯 Methyl Oleate 25ML 131元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C12 to C63 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C12 to C63 - Esters
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Lipids - Biochemicals and Reagents
  4. Fatty Acyls - Lipids
  5. Fatty Acids and conjugates - Fatty Acyls
  6. Unsaturated Fatty Acids and Derivatives - Fatty Acids and conjugates
  7. Esters - Unsaturated Fatty Acids and Derivatives
  8. Methyl Esters - Esters
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Certified Reference Materials (CRMs) - Analytical Standards
  4. Organic CRMs TraceCERT - Certified Reference Materials (CRMs)
  5. CRM for chromatography - Organic CRMs TraceCERT
  6. FA / FAME - CRM for chromatography
  1. Analytical & Chromatography 分析化学与色谱
  2. Applications
  3. Food & Beverage Analysis - Applications
  4. Fats (fatty acids and triglycerides), Edible Oils, and Sterols - Food & Beverage Analysis
  5. cis/trans FAME Isomers - Fats (fatty acids, FAMEs, glycerides), Edible Oils, Sterols
  6. Analytical Standards - cis/trans FAME Isomers
  7. Individual C18:1 FAMEs - Analytical Standards
  1. Analytical & Chromatography 分析化学与色谱
  2. Standard Materials for GC
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters
  6. C10 to C11
  1. Materials Science 材料科学
  2. Plasticizer
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Higher Fatty Acids & Higher Alcohols
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Lipids
  4. Fatty Acids
  5. Unsaturated fatty acids and derivatives
  6. Branched fatty acids (Methyl Branched)