Cyclopentadienylmolybdenum(II) Tricarbonyl, Dimer 三羰基(η-环戊二烯基)合锰二聚体

CAS 12091-64-4 MFCD00009947

化学结构图

12091-64-4
SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mo][Mo].[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 |^1:14,15,16,17,18,19,20,21,22,23|

化学属性

TSCAYes
Mol. Formula[C5H5Mo(CO)3]2
Mol. Weight490
Appearance red to purple xtl.
Stabilityair sensitive
Melting Point220°C dec.

别名和识别编码

Chemical NameCyclopentadienylmolybdenum(II) Tricarbonyl, Dimer
PubChem Substance ID24847336
EC Number235-156-0
Synonym Bis(tricarbonylcyclopentadienylmolybdenum) Hexacarbonylbis(eta5-cyclopenta-2,4-dien-1-yl)dimolybdenum 三羰基(环戊二烯基)合钼二聚体
Chemical Name Translation三羰基(η-环戊二烯基)合锰二聚体
MDL NumberMFCD00009947
CAS Number12091-64-4
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分类

  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Molybdenum, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Molybdenum, Molybdenum Catalysts, Vapor Deposition Precursors, 材料科学
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Molybdenum, Vapor Deposition Precursors, 材料科学

相关文献及参考

  • Beil. 16 ,IV,1775
  • FT-IR 1 (2), 1297:C / FT-IR 2 (3), 4582:B / IR-Spectra (2), 1338:H / IR-Spectra (3), 1566:H / RegBook 1 (2), 3135:A / Structure Index 1 , 495:B:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302+H312+H332
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S4 Keep away from living quarters 远离生活区；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
UN Number 3466 UN3466
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Storage condition Air Sensitive
Packing GroupII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Molybdenum 钼
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Molybdenum - CVD and ALD Precursors by Metal
  1. Metallocenes, Derivatives & Cp Precursors
  2. Molybdenum

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