Dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin, 4-​hydroxy-​, 4-​oxide, (11bS)​- (S)-(+)-1,1'-二萘基-2,2'基 双磷酸氢酯

CAS 35193-64-7 MFCD00010045

化学结构图

35193-64-7
SMILES:

化学属性

Mol. FormulaC20H13O4P
Mol. Weight348
Melting Point320
TSCANo

别名和识别编码

Chemical NameDinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin, 4-​hydroxy-​, 4-​oxide, (11bS)​-
MDL NumberMFCD00010045
PubChem Substance ID24854963
Beilstein Registry Number4787775
Synonym (+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE (+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE (R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPH (R)-(-)-1,1'-Binaphthalene-2,2'-diyl hydrogen phosphate (R)-(-)-1,1'-Binaphthalene-2,2'-diyl hydrogen phosphate(R)-(-)-BNP acid (R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE (R)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE (S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE (S)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide (S)-4-羟基二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-氧化物 (S)-(+)-1,1′-联萘-2,2′-二基磷酸氢酯 R-联萘酚磷酸酯 S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
CAS Number35193-64-7
EC Number252-425-8
Chemical Name Translation(S)-(+)-1,1'-二萘基-2,2'基 双磷酸氢酯
InChIKeyJEHUZVBIUCAMRZ-UHFFFAOYSA-N
Reaxys-RN2014273
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Catalysts
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Phosphoric Acids, Chiral Resolution Reagents, Chiral Resolving Reagents

安全信息

GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes
RTECSRZ2475100
UN Number
Packing GroupIII

其他信息

  • MOL 文件:35193-63-6.mol
  • F:10-23
  • 图谱信息:联萘酚磷酸酯(35193-63-6)质谱(MS)
  • Sigma Aldrich:35193-63-6(sigmaaldrich)
  • 联萘酚磷酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B2130 (+/-)-1,1'-联萘-2,2'-二基磷酸氢盐 (+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate 5G 835元 2011/04/16 B2130 (+/-)-1,1'-联萘-2,2'-二基磷酸氢盐 (+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate 25G 2480元
  • TCI Shanghai:(+)-1,1'-联萘-2,2'-二酚磷酸酯 (+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate,>;98.0%(LC)(T)(35193-63-6)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Catalysts - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Optical Resolution
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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