Mercury 汞

CAS 7439-97-6 MFCD00011035

化学结构图

7439-97-6
SMILES: [Hg]

化学属性

Mol. FormulaHg
Mol. Weight201
Boiling Point356.6
Melting Point-38.9
TSCAYes
Density13.54
Vapor Density7 (vs air)
Vapor Pressure<;0.01 mmHg ( 20 °C)
SolubilityH2O: soluble

别名和识别编码

Chemical NameMercury
CAS Number7439-97-6
PubChem Substance ID23931
EC Number231-106-7
MDL NumberMFCD00011035
Merck Number14,5898
Synonym Colloidal mercury Hg (mercury) Hydrargyrum KWIK Liquid silver MERCURY Mercure Mercurio Mercury Mercury element Metallisches Quecksilber NCI-C60399 Quecksilber Quick silver Quicksilver RCRA waste number U151 RTEC {} {} {} {} {} {} {} {uni_hamburg} 水银 水银标液 汞标准溶液 试剂汞
Chemical Name Translation
Wiswesser Line NotationHG
LabNetwork Molecule IDLN00194627
InChIInChI=1S/Hg
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分类

  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Electrochemistry, High Purity Reagents for Trace Analysis, I-N, Puriss p.a., Materials Science, Mercury, Metal and Ceramic Science, Metals, Polarography,
  • {SNA} Analytical Reagents for General Use, Electrochemistry, High Purity Reagents for Trace Analysis, I-N, Puriss p.a., Mercury, Metal and Ceramic Science, Metals, Polarography, Puriss p.a., Reagents for Inorganic Trace Analysis, Trace Analysis Reagents & Solvents, 分析/色谱, 分析试剂, 材料科学

产品应用

  • 凯氏定氮法测定氮时催化剂,制造汞盐及汞剂、还原剂,有机化合物氧化反应催化剂,血液非蛋白氮生化检验,农药六六六的异丙体分析。广泛用于各种仪表和温度计。极谱分析滴汞电极。

相关文献及参考

  • Short: III/13b
  • Short: III/13a
  • Short: II/5
  • Merck: 14,5898

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 8 T,N
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H300 Fatal if swallowed 吞食致命
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSOV4550000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P302+P352
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P307+P311
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P337+P313
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
UN Number 2809 3289 UN2809
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R23 Toxic by inhalation 吸入有毒
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R25 Toxic if swallowed 吞咽有毒
  • R26 Very toxic by inhalation 吸入极毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R48/21/22
  • R48/23
  • R50/53
  • R51/53
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Packing GroupIII
Hazard Class8
Storage condition 密封器皿盛装,在阴凉通风处存放。 Poison room
Warnings 危化品目录(2015)
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 400 mg/kg/14D-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   ZEKBAI Zeitschrift fuer Krebsforschung.  (Berlin, Fed. Rep. Ger.)  V.1-75,
   1903-71.  For publisher information, see JCROD7.  Volume(issue)/page/year:
   61,511,1957

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 43 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Liver - jaundice, other or unclassified
   Liver - other changes
REFERENCE :
   JTCTDW Journal of Toxicology, Clinical Toxicology.  (Marcel Dekker, 270
   Madison Ave., New York, NY 10016)  V.19-    1982-  Volume(issue)/page/year:
   31,487,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 571 uL/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - paresthesis
   Lungs, Thorax, or Respiration - dyspnea
   Skin and Appendages - sweating
REFERENCE :
   SMJOAV Southern Medical Journal.  (Southern Medical Assoc., POB 2446,
   Birmingham, AL 35205) V.1-    1908-  Volume(issue)/page/year: 90,1033,1997

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 44300 ug/m3/8H
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Liver - other changes
   Nutritional and Gross Metabolic - body temperature increase
REFERENCE :
   JJOMDZ JOM, Journal of Occupational Medicine.  (American Occupational
   Medicine Assoc., 150 N. Wacker Dr., Chicago, IL 60606)  V.10-    1968-
   Volume(issue)/page/year: 20,532,1978

TYPE OF TEST

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 254 mg/kg
TOXIC EFFECTS :
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 2,243,1969

{hazard_co

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Unreported
TEST SYSTEM             : Human - man
DOSE/DURATION           : 150 ug/m3
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20016)  V.1-    1960-  Volume(issue)/page/year:
   34,461,1979

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 7440 ng/m3/24H
SEX/DURATION            : male 16 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 45(3),72,1980

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1 mg/m3/24H
SEX/DURATION            : female 1-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 35,59A,1987

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 890 ng/m3/24H
SEX/DURATION            : male 16 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 45(3),72,1980

Restrict 危险品

其他信息

  • 蒸气密度:7 (vs air)
  • 汞价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 53206360 汞;水银 100ml 200元 2011/08/23 53206362 汞;水银 100ml 250元 2011/08/23 10013517 汞;水银 250g 350元
  • F:10
  • 毒性分级:剧毒
  • MSDS 信息:汞(7439-97-6).msds
  • 用途一:用于汞盐和汞齐的制造及有机合成,也用作还原剂
  • 外观性质:银白色液态金属,在常温下可挥发。
  • Acros Organics:汞 Mercury(7439-97-6)
  • 下游产品:乙酸 --> 氢氧化钾 --> 邻氯苯甲醛 --> 3-(4-氯苯基)丙酸 --> 氯化汞 --> 6-氯-3-氰基吡啶 --> 14-甲基十五烷酸 --> 二十三烷酸 --> 木焦油酸 --> 褐煤酸 --> 苯基醋酸汞 --> 乙酸汞 --> 1-蒽醌磺酸 --> 蒽醌-1,5-二磺酸 --> 氯化氨汞 --> 氯化氨基汞 --> 碘化汞 --> 乙酸亚汞 --> 硝酸苯汞 --> 一溴化汞 --> 氯化亚汞 --> 碘化汞 --> 硫化汞(II) --> 奈斯勒试剂 --> 硝酸亚汞(I) --> 硝酸汞
  • 在常温下可挥发。不溶于水、盐酸、稀硫酸,溶于浓硝酸,易溶于王水及浓硫酸。
  • 类别:有毒物质
  • 用途三:凯氏定氮法测定氮时催化剂,制造汞盐及汞剂、还原剂,有机化合物氧化反应催化剂,血液非蛋白氮生化检验,农药六六六的异丙体分析。广泛用于各种仪表和温度计。极谱分析滴汞电极。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。
  • Alfa Aesar:汞,Puratronic|r,99.999995%(metalsbasis) Mercury, Puratronic, 99.999995% (metals basis)(7439-97-6)
  • 急性毒性:口服-人 TDL0: 43 毫克/公斤; 吸入- 兔子 LCL0: 29 毫克/ 立方米/ 30小时
  • 储运特性:库房通风低温干燥; 与食品添加剂分开存放
  • 具有挥发性,其蒸汽剧毒。不溶于水、盐酸、稀硫酸,溶于浓硝酸,易溶于王水及浓硫酸。
  • 可燃性危险特性:不燃; 受热放出有毒汞蒸气
  • Sigma Aldrich:7439-97-6(sigmaaldrich)
  • 职业标准:TLV-TWA 0.05 毫克(汞)/ 立方米
  • 灭火剂:水, 二氧化碳, 干粉, 泡沫
  • MOL 文件:7439-97-6.mol
  • 用途二:凯氏定氮法测定氮时催化剂,制造汞盐及汞剂、还原剂,有机化合物氧化反应催化剂,血液非蛋白氮生化检验,农药六六六的异丙体分析。广泛用于各种仪表和温度计。极谱分析滴汞电极。
  • 蒸气压:<;0.01 mm Hg ( 20 °C)

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