Picloram 4-氨基-3,5,6-三氯吡啶羧酸

CAS 1918-02-1 MFCD00012101

化学结构图

1918-02-1
SMILES: Nc1c(Cl)c(Cl)nc(C(=O)O)c1Cl

化学属性

Mol. FormulaC6H3Cl3N2O2
Mol. Weight241.46
Melting Point200
Solubility420 MG/L
Density1.811
Flash Point208.1±28.7 °C

别名和识别编码

Chemical NamePicloram
Synonym Picloram {LY} Picloram {} {LY} Picloram {} {} {LY} Picloram {} {} {} {LY} Picloram {} {} {} {} {LY} Picloram {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Picloram {} {} {} {} {} {} {} {} {} {} {}
CAS Number1918-02-1
PubChem Substance ID15965
EC Number217-636-1
Beilstein Registry Number479075
MDL NumberMFCD00012101
Reaxys-RN479075
Merck Number7397
Alfabeta NameAMINOTRICHLOROPYRIDINECARBOXYLICACID 43562-----,,
Chemical Name Translation4-氨基-3,5,6-三氯吡啶羧酸
Wiswesser Line NotationT6NJ BVQ CG DZ EG FG
InChIInChI=1S/C6H3Cl3N2O2/c7-1-3(10)2(8)5(9)11-4(1)6(12)13/h(H2,10,11)(H,12,13)
Canonical SMILESO=C(C1=NC(Cl)=C(Cl)C(N)=C1Cl)O
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Analytical Standards, Aromatic acid, N-P, Pyridine, 农残和代谢标准品,
  • {SNA} Auxins, Plant Biotechnology, Plant Growth Regulators, 分子生物学, 植物组织培养
  • Auxins, Plant Biotechnology, Plant Growth Regulators, Plant Tissue Culture
  • {SNA} All Herbicide Standards, Analytical Standards, Aromatic acid, N-P, N-S, Pyridine, 农残和代谢标准品, 分析/色谱, 按照字母排序, 灭草剂
  • {SNA} Auxins, Molecular Biology,
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography,

产品应用

  • 毒莠定及其盐可迅速地通过叶和根吸收与传导，除十字化科作物外大多数阔叶作物都对该药敏感，大多数禾本科作物是耐药的。

相关文献及参考

  • Zhang Y, Zeng GM, Tang L, et. al., Highly sensitive fluorescence quantification of picloram using immunorecognition liposome. Talanta 83 , 210-215, (2010) 摘要
  • Merck 14 ,7397
  • Merck: 14,7397 Beilstein:22(5)13,585
  • Alvarez MA, Eraso NF, Pitta-Alvarez SI, et. al., Two-stage culture for producing berberine by cell suspension and shoot cultures of Berberis buxifolia Lam. Biotechnol. Lett. 31 , 457-463, (2009) 摘要
  • Merck: 14,7397

安全信息

GHS Symbol
WGK Germany2
Hazard Codes 9
Hazard statements
  • H303 May be harmfully swallowed 吞食可能有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSTJ7525000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P319
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning {} {} {} {} {} {} {TCI}
UN Number 3077
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
Warnings IRRITANT
Packing GroupIII
Hazard Class9 
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 416 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
   Endocrine - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-23,1978

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 417 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Endocrine - tumors
   Endocrine - thyroid tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 7,207,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 208 mg/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Endocrine - tumors
   Endocrine - thyroid tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 7,207,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 340 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Endocrine - tumors
   Endocrine - thyroid tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >4 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOEAAH Down to Earth.  (Dow Chemical USA, Agricultural Products Dept.,
   Midland, MI 48640) V.1-    1945-  Volume(issue)/page/year: 35,25,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,414,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - duck
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOEAAH Down to Earth.  (Dow Chemical USA, Agricultural Products Dept.,
   Midland, MI 48640) V.1-    1945-  Volume(issue)/page/year: 35,25,1979

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 200 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 57,277,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mg/L
REFERENCE :
   TGANAK Tsitologiya i Genetika.  Cytology and Genetics.  For English
   translation, see CYGEDX. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-    1967-  Volume(issue)/page/year: 18,455,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,797,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 7500 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - urogenital system
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,797,1972

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 用途一:毒莠定及其盐可迅速地通过叶和根吸收与传导，除十字化科作物外大多数阔叶作物都对该药敏感，大多数禾本科作物是耐药的。
  • MOL 文件:1918-02-1.mol
  • 类别:农药
  • 职业标准:TLTLV-TWA 10毫克/ 立方米; STEL 20 毫克/ 立方米
  • 毒性分级:中毒
  • 灭火剂:干粉、泡沫、砂土
  • 急性毒性:口服- 大鼠 LD50: 2898 毫克/ 公斤; 口服- 小鼠 LD50: 1061 毫克/公斤
  • MSDS 信息:4-氨基-3,5,6-三氯-2-皮考林酸(1918-02-1).msds
  • 外观性质:白色粉末或浅褐色颗粒,带有氯气气味。
  • 可燃性危险特性:燃烧产生有毒含氯化物和氮氧化物气体
  • Sigma Aldrich:1918-02-1(sigmaaldrich)
  • 4-氨基-3,5,6-三氯吡啶羧酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1864 毒莠定 Picloram 5G 931元 2014/06/02 P1864 毒莠定 Picloram 25G 2820元

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. N-P - Alpha sort
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridines - Halogenated Heterocycles
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PER - POLA - P
  1. Life Science 生命科学
  2. Plant Biotechnology 植物生物技术
  3. Plant Tissue Culture - Plant Biotechnology
  4. Plant Growth Regulators - Plant Tissue Culture
  5. Auxins - Plant Growth Regulators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Heterocyclic Acids 杂环酸
  5. Pyridine Acids

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