Chloromethylsulfonyl Chloride 氯甲磺酰氯

CAS 3518-65-8 MFCD00014727

化学结构图

3518-65-8
SMILES: O=S(=O)(Cl)CCl

化学属性

Mol. FormulaC
Mol. Weight149
Boiling Point175°C(lit.)
Density1.64 g/mL at 20 °C(lit.)
Refractive index1.4880 to 1.4940
TSCANo

别名和识别编码

Chemical NameChloromethylsulfonyl Chloride
CAS Number3518-65-8
Alfabeta NameCHLOROMETHANESULFONYLCHLORIDE
MDL NumberMFCD00014727
Synonym CHLOROMESYL CHLORIDE 氯甲基磺酰氯 (Chloromethyl)sulfonyl chloride Chloromethanesulfonylchloride,98+% CHLOROMETHANESULPHONYL CHLORIDE 氯甲烷硫酰氯 Chlormethansulfonylchlorid Chloromethanesulfonyl chloride Chloromethylsulphonylchloride 氯甲磺酰氯, 98+% chloro-methanesulfonylchlorid 氯甲基磺酸氯 chloromethanesulphonyl chloride Chlormethansulfochlorid CMSC chloridkyselinychlormethansulfonove RARECHEM AW HA 0004 氯甲磺酰氯 氯甲烷磺酰氯 Chlorid kyseliny chlormethansulfonove CHLOROMETHANESULFONYL CHLORIDE CHLOROMETHYLSULFONYL CHLORIDE Chloromesyl chloride Methanesulfonyl chloride, chloro- CHLORMETHYLSULFONYL CHLORIDE
PubChem Substance ID77054
EC Number222-526-1
Beilstein Registry Number1(3)2592
Reaxys-RN1811761
Chemical Name Translation氯甲磺酰氯
InChIKeyKQDDQXNVESLJNO-UHFFFAOYSA-N
Wiswesser Line NotationWSG1G
LabNetwork Molecule IDLN00129510
InChIInChI=1S/CH2Cl2O2S/c2-1-6(3,4)5/h1H2
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分类

  • {SA} Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Other Protecting and Derivatizing Reagents, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.

安全信息

Warnings TOXIC, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C C,Xi
RTECSPB2800000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number UN3265 3265 UN 3265 8/PG 2
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R22 Harmful if swallowed 吞咽有害
Storage condition Moisture Sensitive
Packing GroupII
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 372 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1070,1986

其他信息

  • MOL 文件:3518-65-8.mol
  • 氯甲基磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0924 氯甲烷磺酰氯 Chloromethylsulfonyl Chloride 25G 1800元 2010/05/25 41486 氯甲磺酰氯, 98+% Chloromethanesulfonyl chloride, 98% 50g 6272元 2010/05/25 41486 氯甲磺酰氯, 98+% Chloromethanesulfonyl chloride, 98% 2g 391元
  • 毒性分级:高毒
  • 类别:腐蚀物品
  • TCI Shanghai:氯甲烷磺酰氯 Chloromethylsulfonyl Chloride,>;90.0%(T)(3518-65-8)
  • 储运特性:库房低温, 通风, 干燥 ; 防火; 与氧化剂, 食品原料分开存放
  • 灭火剂:水, 二氧化碳, 干粉
  • Hazard Note:Corrosive
  • 急性毒性:口服-大鼠 LD50： 372 毫克/公斤
  • F:10-21
  • Alfa Aesar:氯甲磺酰氯,98+% Chloromethanesulfonyl chloride, 98%(3518-65-8)
  • 可燃性危险特性:可燃; 火场分解有毒硫氧化物, 氯化物烟雾
  • 敏感性:Moisture Sensitive
  • 刺激数据:皮肤-兔 500 毫克/ 24小时 重度; 眼睛- 兔 0.05 毫克/ 24小时 重度
  • Sigma Aldrich:3518-65-8(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents

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