Disulfoton 乙拌磷

CAS 298-04-4 MFCD00036234

化学结构图

298-04-4
SMILES: CCSCCSP(=S)(OCC)OCC

化学属性

Mol. FormulaC8H19O2PS3
Mol. Weight274.42
Density1.0
Flash Point133 °C
Solubility不溶于水。

别名和识别编码

Chemical NamePhosphorodithioic acid, O,O-diethylS-(2-(ethylthio)ethyl) ester
Synonym {uni_hamburg} M-74 Ethylthiometon B Ekatin TD 敌死通 Frumin G Disipton {Chemica BAYER 19639 M 74 二硫松 O,O-Diethyl-S-(2-(ethylthio)-ethyl)-dithiophos O,O-Diethyl S-(2-eththioethyl) thiothionophosphate Di-Syston Disyston ETHYLTHIOMETHON 乙拌磷 THIODEMETON(R) O,O-Diethyl S-[2-(ethylthio)ethyl] dithiophosphate Di-Syston G M 74 (pesticide) Solvirex S276 Dimaz O,O-diethyl S-[2-(ethylthio)ethyl]dithiophosphate Frumin AL {h DISYSTON O,O-diethyl S-2-ethylthioethyl phosphorodithioate Dithiodemeton Dithiophosphate de O,O-diethyle et de S-(2-ethylthio-ethyle) Vuagt 1964 Disulfoton S-2-(Ethylthio)ethyl O,O-diethyl ester of phosphorodithioic acid Phosphorodithioic acid, O,O-diethyl S-[2-(ethylthio) O,O-Diethyl S-(2-ethylmercaptoethyl) dithiophosphate ENT 23,437 二硫代磷酸-O,O-二乙基-S-[2-(乙基硫代)乙基]酯(6CI,7CI,8CI,9CI) DISULFOTON Phosphorodithionic acid, S-2-(ethylthio)ethyl-O,O-diethyl ester {uni_ {C VUAgT 1964 Phosphorodithioic acid, O, Disulfaton Vuagt 1-4 Bay 19639 O,O-Dietil-S-(2-etiltio-etil)-ditiofosfato DI-SYSTON(R) BAY S 276 Dution BAY 19639 bay19639 O,O-Diaethyl-S-(2-aethylthio-aethyl)-dithiophosphat Glebofos Dithiophosphorsäure-O,O-diethyl-S-(2-ethylthio)ethylester ENT-23437 thiometon-ethyl {hazard_co
PubChem Substance ID3118
EC Number206-054-3
Beilstein Registry Number1709167
MDL NumberMFCD00036234
CAS Number298-04-4
Chemical Name Translation乙拌磷
Merck Number13,3400
Wiswesser Line Notation2S2SPS&O2&O2
InChIInChI=1S/C8H19O2PS3/c1-4-9-11(12,10-5-2)14-8-7-13-6-3/h4-8H2,1-3H3
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分类

  • {uni_hamburg} no charge; sulfide; 1fragment
  • {SA} Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Baby Food Directives 13/2003 EC & 14/2003 EC, Chromatography, D, DIO - DIZ, EPA, Endocrine Disruptors (Draft), Environmental Standards, European Community: ISO, DIN and DL 152, Insecticides, Method Specific, Organophorous, Pesticides, Pesticides & Metabolites
  • {SNA} Alphabetical Index of Analytical Standards, Method and Regulation Specific, Acaricides, All alphabetically sorted, Analytical Standards, Analytical/Chromatography,

相关文献及参考

  • Short: IV/20A
  • Short: IV/20B
  • Merck: 14,3365
  • Short: EINECS

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTD9275000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Hazard Codes T+,N
Risk Statements
  • R50/53
  • R27/28 Very toxic in contact with skin and if swallowed 皮肤接触及吞食都有剧毒
Storage condition 2-8℃ 0-6°C 储存温度2-8℃
Packing GroupI
Hazard Class6.1(a)
UN Number 3018
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 7(5),38,1963

{h

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 10800 ug/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - fasciculations
   Behavioral - convulsions or effect on seizure threshold
   Kidney, Ureter, Bladder - urine volume increased
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 17,192,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 28 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C113,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 15600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKYUA6 Yakkyoku.  Pharmacy.  (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo,
   Japan)  V.1-    1950-  Volume(issue)/page/year: 37,717,1986

{hazard_com

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5720 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,185,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5720 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 1 gm/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB80-133226

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 40 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB84-138973

其他信息

  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 杀虫剂单一组分标准液
  • 类别:农药
  • 图谱信息:乙拌磷(298-04-4)质谱(MS) 乙拌磷(298-04-4)核磁图( 13 CNMR) 乙拌磷(298-04-4)核磁图( 1 HNMR)
  • 外观性质:棕黄色油状液体,有特殊气味。
  • 中毒症状:急性中毒多在12小时内发病,口服立即发病。轻度:头痛、头昏、恶心、呕吐、多汗、无力、胸闷、视力模糊、胃口不佳等,全血胆碱酯酶活力一般降 至正常值的70-50%。中度:除上述症状外还出现轻度呼吸困难、肌肉震颤、瞳孔缩小、精神恍惚、行走不稳、大汗、流涎、腹疼、腹泻。重者还会出现昏迷、抽搐、呼吸困难、口吐白沫、大小便失禁,惊厥,呼吸麻痹。
  • 职业标准:TWA 0.1 毫克/立方米; STEL 0.3 毫克/立方米
  • 产品特性:剧毒二硫代磷酸酯类杀虫、杀螨剂。商品名称西梅脱,鼍曾广泛称人三九一一。对高等动物剧毒,对人体口服、皮肤接触、溅入眼睛、呼吸摄入等都有中毒危险。对鱼毒性高,对蜜蜂有毒。对害虫害螨具有内吸、触杀、胃毒及熏蒸作用。
  • 用途:乙拌磷主要以颗粒剂随播种土壤处理或乳油配成药液作种子处理,用于棉花及其他大田作物防治土壤害虫及苗期刺吸式口器害虫,也能兼治线虫。用于棉花种处理或土壤处理防治棉苗蚜虫、叶螨,持效期可达45~50天。小麦用粉粒剂种子处理防治土壤害虫及麦苗蚜虫,持效期可达30天以上。对甜菜作种子处理,可防治蒙古灰象乙及土壤害虫。高梁地用颗粒剂配成毒土撒施,每12垄施药土1垄,可熏蒸防治蚜虫。乙拌磷使用时要特别注意安全操作,不可用于叶面喷雾,药剂处理过的种子不可作其他用途。并严禁在果树、蔬菜、烟草、茶树、桑 树、药材的生长期使用。
  • 急救治疗:[1]用阿托品1~5mg皮下或静脉注射(按中毒轻重而定) [2]用解磷定0.4-1.2g静脉注射(按中毒轻重而定) [3]禁用吗啡、茶硷、吩噻嗪、利血平。 [4]误服立即 引吐、洗胃、导泻(清醒时才能引吐)。
  • Sigma Aldrich:298-04-4(sigmaaldrich)
  • 可燃性危险特性:明火可燃; 受热放出有毒氧化磷、氧化硫气体
  • MOL 文件:298-04-4.mol
  • MSDS 信息:乙拌磷(298-04-4).msds
  • 下游产品:异拌磷
  • 毒性分级:剧毒
  • 注意事项:在我国未登记
  • 急性毒性:口服-大鼠 LD50: 4 毫克/公斤; 口服-小鼠 LD50: 4.8 毫克/公斤

系列性分类


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