Palladium hydroxide 氢氧化钯/碳

CAS 12135-22-7 MFCD00064599

化学结构图

12135-22-7
SMILES: O[Pd]O

化学属性

Mol. FormulaH2O2Pd
Mol. Weight140.43
TSCAYes
Density1.527
Solubility不溶
Boiling Point100°C at 760 mmHg
RedoxReduction

别名和识别编码

Chemical NamePalladium hydroxide
Synonym Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {} {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {} {} {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {} {} {} {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted with ca. 55% Water) {} {} {} {} {} {} {} {} {} {LY} Palladium hydroxide on activated carbon(10%)(wetted w
MDL NumberMFCD00064599
PubChem Substance ID9942167
EC Number235-219-2
CAS Number12135-22-7
Beilstein Registry Number2384789
Reaxys-RN11342936
Merck Number7060
Chemical Name Translation氢氧化钯/碳
LabNetwork Molecule IDLN00003383
InChIInChI=1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
Canonical SMILESO[Pd]O
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Heterogeneous Pd Catalysts, Palladium

产品应用

  • Usually used as a catalyst for arylation reactions.

相关文献及参考

  • Merck: 14,7060
  • Gave superior yields to Pd on carbon as catalyst for the heterogeneous hydrostannylation of alkenes with tri-n-butyltin hydride: Angew. Chem. Int. Ed., 35, 1329 (1996).
  • Preferred catalyst for hydrogenolysis of benzylamines. For use in the catalytic transfer hydrogenolysis of allylic acetates, see: Tetrahedron Lett., 30, 1405 (1989).

安全信息

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
Hazard Codes Xi
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 不溶于水,溶于酸。

系列性分类


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