Clopyralid 3,6－二氯吡啶－2－羧酸

CAS 1702-17-6 MFCD00078655

化学结构图

1702-17-6
SMILES: O=C(O)c1nc(Cl)ccc1Cl

化学属性

Mol. FormulaC6H3Cl2NO2
Mol. Weight192.00
Melting Point151-152°C
Flash Point>100°(212°F)
TSCAYes
Solubility1.0 G/L
Boiling Point323.7°C at 760 mmHg
Density1.612

别名和识别编码

Chemical NameClopyralid
CAS Number1702-17-6
Alfabeta NameDICHLOROPYRIDINECARBOXYLICACID 362---,
MDL NumberMFCD00078655
Synonym Clopyralid {LY} Clopyralid {} {LY} Clopyralid {} {} {LY} Clopyralid {} {} {} {LY} Clopyralid {} {} {} {} {LY} Clopyralid {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Clopyralid {} {} {} {} {} {} {} {} {}
PubChem Substance ID15553
EC Number216-935-4
Beilstein Registry Number0473755
Reaxys-RN473755
Merck Number2400
Chemical Name Translation3,6－二氯吡啶－2－羧酸
Wiswesser Line NotationT6NJ BVQ CG FG
LabNetwork Molecule IDLN00122984
InChIInChI=1S/C6H3Cl2NO2/c7-3-1-2-4(8)9-5(3)6(10)11/h1-2H,(H,10,11)
Canonical SMILESC1=CC(=NC(=C1Cl)C(O)=O)Cl
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分类

  • {SA} Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Aromatic acid, C, CI - CL, Chromatography, Environmental Standards, Herbicides, Pesticides & Metabolites, Pyridine
  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Aromatic acid, C, CI - CL, Chromatography, Environmental Standards, Herbicides, Pesticides & Metabolites, Pyridine
  • {SNA}
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards,

产品应用

  • Systemic post-emergence herbicide for use in food crops and mesquite.

相关文献及参考

  • Merck: 14,2400
  • Bovey, R.W., et al.: Weed. Sci., 33, 349 (1985),
  • Pik, A.J., J. Agric. Food Chem., 25, 1054 (1977),

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes Xi,N Xi;N Xi;N,Xi,N,X Xi
Hazard statements
  • H318 Causes serious eye damage 严重伤害眼睛
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSTJ7550700
Precautionary statements
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S2 Keep out of the reach of children 避免儿童触及；
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R51/53
UN Number 3077 UN 3077
Packing GroupIII
Hazard Class9
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8° 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de
   Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France)
   V.1-  1947-  Volume(issue)/page/year: 31,387,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de
   Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France)
   V.1-  1947-  Volume(issue)/page/year: 31,387,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A433,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - duck
DOSE/DURATION           : 1465 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,182,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 150 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   4,91,1984

其他信息

  • Sigma Aldrich:1702-17-6(sigmaaldrich)
  • 用途一:用于防治油菜田的阔叶杂草
  • 上游原料:氯
  • 3,6-二氯吡啶羧酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 H27146 3,6-二氯吡啶-2-羰酸,96% 3,6-Dichloropyridine-2-carboxylic acid, 96% 5g 3290元 2010/05/25 H27146 3,6-二氯吡啶-2-羰酸,96% 3,6-Dichloropyridine-2-carboxylic acid, 96% 1g 1117元
  • MOL 文件:1702-17-6.mol
  • Alfa Aesar:3,6-二氯吡啶-2-羰酸,96% 3,6-Dichloropyridine-2-carboxylic acid, 96%(1702-17-6)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. L - Alphabetic
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Herbicides for Use in Environmental Chromatography Standards
  7. Aromatic acid - Herbicides
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Heterocyclic Acids 杂环酸
  5. Pyridine Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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