Triphenylphosphine, polymer supported 1.4-2.0mmol/g on polystyrene 200-400 mesh 2% DVB loading 聚合物键合型三苯基膦

CAS 39319-11-4 MFCD00148025

化学结构图

39319-11-4
SMILES:

化学属性

Mol. Weight262.29
Mol. Formula-C6H4P(C6H5)2
TSCANo

别名和识别编码

Synonym 二苯基膦-聚苯乙烯 聚苯乙烯交联二乙烯基苯,二苯基磷化 苯乙烯-二乙烯基苯共聚物,二苯基磷化 聚苯乙烯交联二乙烯基苯,二苯基磷化 聚合物键合型三苯基膦 苯乙烯-二乙烯基苯共聚物,二苯基磷化 二苯基膦-聚苯乙烯
MDL NumberMFCD00148025
PubChem Substance ID24862656
CAS Number39319-11-4
Chemical Name Translation聚合物键合型三苯基膦
Chemical NameTriphenylphosphine, polymer supported 1.4-2.0mmol/g on polystyrene 200-400 mesh 2% DVB loading
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ligands, Phosphine Compounds, Phosphine Ligands, Solid Supported Synthesis, Specialty Synthesis, Supported Reagents
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ligands, Phosphine Compounds, Phosphine Ligands,

相关文献及参考

  • 1. Clark, H.C., et al. J. Organomet. Chem. 322 , 393, (1987)
  • Bernard, M. et. al. J. Org. Chem. 48 , 326, (1983)
  • Relles, H.M.; Schuenz, R.W. J. Am. Chem. Soc. 96 , 6469, (1974)
  • Regen, S.L.; Lee, D.P. J. Am. Chem. Soc. 40 , 1669, (1975)
  • Landi, J.J. Jr.;Brinkman, H.R. Synthesis , 1093, (1992)
  • Support for nickel, rhenium and rhodium in hydrogenation: J. Am. Chem. Soc., 97, 1742 (1975); dimerization of alkenes: J. Am. Chem. Soc., 97, 341 (1974) and hydroformylation: J. Am. Chem. Soc., 98 5402 (1976). For the halogenation of carboxylic acid and alkanes in carbon tetrachloride: Synthesis, 1093 (1992). Addition of iodine in DMF esterifies primary and secondary alcohols to their respective formate esters: Med. Res. Rev., 19, 97 (1999).
  • For use in the Mitsunobu reaction: Tetrahedron Lett., 8751 (1998), and the Wittig reaction: J. Org. Chem., 48, 326 (1983); J. Chem. Soc. Perkin 1, 2243 (1998).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S37 Wear suitable gloves 戴适当手套;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类


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