Ruthenium(IV) Oxide Xhydrate 氧化钌(Ⅳ)x水合物

CAS 32740-79-7 MFCD00149846

化学结构图

32740-79-7
SMILES: O.[O-2].[O-2].[Ru+4]

化学属性

Mol. Formula2
Mol. Weight151
Melting Point1200° subl.
SolubilityInsoluble in water. Soluble in HCl
TSCAYes

别名和识别编码

Chemical NameRuthenium(IV) Oxide Xhydrate
Synonym Hydrous ruthenium oxide Ruthenium dioxide hydrate
MDL NumberMFCD00149846
PubChem Substance ID24870094
CAS Number32740-79-7
EC Number234-840-6
Chemical Name Translation氧化钌(Ⅳ)x水合物
LabNetwork Molecule IDLN00226215
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Metal and Ceramic Science, Oxides, Ru Catalysts, Ruthenium, Ruthenium Catalysts, 材料科学
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Oxides, Ru Catalysts, Ruthenium, Ruthenium Catalysts

相关文献及参考

  • Fieser 1 ,984 / Fieser 12 ,428 / Fieser 17 ,304
  • Corp MSDS 1 (2), 3061:A / RegBook 1 (3), 3287:F / Sax 6 , 2376
  • Precursor for in situ generation of the powerful oxidant ruthenium(VIII) oxide (see Ruthenium(III)­ chloride hydrate, 11043): Helv. Chim. Acta, 71, 237 (1988). With Oxone. as stoichiometric oxidant in an acetonitrile/ ethyl acetate/ water solvent system, both terminal and internal alkynes can be cleaved to carboxylic acids in high yield: J. Org. Chem., 69, 2221 (2004). Mediates the electrooxidation of primary and secondary alcohols to aldehydes and ketones: Chem. Lett., 369 (1995).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S17 Keep away from combustible material 远离可燃物料;
Packing GroupII
UN Number UN1479
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
RTECSVM2654000

系列性分类