(R)-(-)-N-Boc-3-pyrrolidinol N-叔丁氧羰基-(R)-3-吡咯烷醇

CAS 109431-87-0 MFCD01317838

化学结构图

109431-87-0
SMILES: CC(C)(C)OC(=O)N1CC[C@H](O)C1

化学属性

Mol. FormulaC9H17NO3
Mol. Weight187.24
Melting Point62-65°C
TSCANo
pH:A
Boiling Point273.3±33.0 °C at 760 mmHg

别名和识别编码

Chemical Name(R)-(-)-N-Boc-3-pyrrolidinol
CAS Number109431-87-0
Alfabeta NameHYDROXYPYRROLIDINECARBOXYLICACIDTERTBUTYLESTER R31()------
MDL NumberMFCD01317838
Synonym (R)-(-)-N-Boc-3-pyrrolidinol {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID87559627
Chemical Name TranslationN-叔丁氧羰基-(R)-3-吡咯烷醇
Reaxys-RN4670167
LabNetwork Molecule IDLN00005080
Canonical SMILESO[C@@H]1CCN(C1)C(=O)OC(C)(C)C
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines

相关文献及参考

  • 1. Lee, J. et al Bioorg. Med. Chem. Lett. 10 , 1063, (2000) 摘要
  • Bioorg. Med. Chem. 12 , 2099-2114, (2004) 摘要

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P350
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
Signal word
Hazard statements
  • H302+H312+H332
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50/53
UN Number
Packing GroupIII
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrroles 吡咯
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Ketones - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Pyrrolidines - Heterocyclic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块

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