N,N,N’,N’-Tetramethylchloroformamidinium-Hexafluorophosphate N,N,N’,N’-四甲基氯甲脒六氟磷酸盐

CAS 207915-99-9 MFCD01862891

化学结构图

207915-99-9
SMILES:

化学属性

Mol. FormulaC5H12ClF6N2P
Mol. Weight280.58
Melting Point100-106

别名和识别编码

Chemical NameN,N,N’,N’-Tetramethylchloroformamidinium-Hexafluorophosphate
Synonym TCFH N,N,N′,N′-四甲基氯甲脒六氟磷酸盐
MDL NumberMFCD01862891
PubChem Substance ID24846375
Beilstein Registry Number7896715
CAS Number207915-99-9
Chemical Name TranslationN,N,N’,N’-四甲基氯甲脒六氟磷酸盐
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分类

  • {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents

产品应用

  • 用于肽合成的偶联剂以及制备其他偶联剂的原料

相关文献及参考

  • 1. Ayman El-Faham, et al Eur. J. Org. Chem. 19 , 3641-3649, (2010)
  • 2. Ayman El-Faham, et al Chem. Eur. J. 15 , 9404-9416, (2009) 摘要
  • 3. J. Phillip Kennedy and Craig W. Lindsley Tetrahedron Lett. 51 , 2493-2496, (2010)
  • 4. Judit Tulla-Puche, et al Bioconjug. Chem. 19 , 1968-1971, (2008) 摘要
  • 5. L.A. Carpino, L.A. Carpino J. Am. Chem. Soc. 117 , 5401, (1995)
  • 6. J. Habermann, H. Kunz J. Prakt. Chem./Chem.-Ztg. 340 , 233, (1998)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 阴凉干燥处保存。

系列性分类


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