Hexachloropropene 六氯丙烯

CAS 1888-71-7 MFCD00000835

化学结构图

1888-71-7
SMILES: ClC(Cl)=C(Cl)C(Cl)(Cl)Cl

化学属性

Mol. FormulaC3Cl6
Mol. Weight248.73
Vapor Density8.3 (vs air)
Density1.765
Refractive index1.5490
Boiling Point209-210°
Melting Point-73°
TSCAYes
Flash Point209-210°C
Appearance 无色液体。沸点209-210℃，99℃（1.33kPa），相对密度1.765，折光率1.5490（20℃），不溶于水。

别名和识别编码

Chemical NameHexachloropropene
Synonym 1,1,1,2,3,3-hexachloropropene 1,1,2,3,3,3-Hexachloro-1-propene 1,1,2,3,3,3-hexachloro-1-propen 1,1,2,3,3-Hexachloro-1-propene 1-Propene, 1,1,2,3,3,3-hexachloro- 1-Propene, hexachloro- 1-propene,1,1,2,3,3,3-hexachloro 1-propene,1,1,2,3,3,3-hexachloro- HEXACHLOROPROPENE HEXACHLOROPROPYLENE Hexachloropropene Hexachloropropylene Hexachlorpropen PERCHLOROPROPENE Perchloropropene Perchloropropylene Perchlorpropen Propene, hexachloro- Propene,hexachloro- RCRA waste number U243 Rcra waste number U243 hexachloro-1-propene hexachloro-propen hexachloro-propene hexachloropropene perchloropropylene {} {} {} {} {}
MDL NumberMFCD00000835
Beilstein Registry Number1766640
EC Number217-560-9
CAS Number1888-71-7
PubChem Substance ID15902
Chemical Name Translation六氯丙烯
Wiswesser Line NotationGYGUYGXGGG
LabNetwork Molecule IDLN02145209
InChIInChI=1S/C3Cl6/c4-1(2(5)6)3(7,8)9
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Dat

安全信息

RTECSUD0175000
WGK Germany3
Packing GroupI
UN Number UN 3382 6.1/PG 1 UN3382
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23 Toxic by inhalation 吸入有毒
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
GHS Symbol
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes T
Hazard Class6.1 
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 85 ppm/30M
TOXIC EFFECTS :
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and
   Development Reports. (Rochester, NY)  Volume(issue)/page/year: MDDC-1715

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 400 uL/kg
TOXIC EFFECTS :
   Liver - hepatitis (hepatocellular necrosis), diffuse
   Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
   acute tubular necrosis)
REFERENCE :
   XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and
   Development Reports. (Rochester, NY)  Volume(issue)/page/year: MDDC-1715

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 ppm/30M
TOXIC EFFECTS :
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and
   Development Reports. (Rochester, NY)  Volume(issue)/page/year: MDDC-1715

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 425 ppm/30M
TOXIC EFFECTS :
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
   Liver - hepatitis (hepatocellular necrosis), diffuse
REFERENCE :
   XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and
   Development Reports. (Rochester, NY)  Volume(issue)/page/year: MDDC-1715

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 15 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,1,1986

其他信息

  • F:19
  • 用途一:用于有机合成。
  • 方法一:将1,1,1,2,2,3,3-七氯丙烷溶于乙醇，保持30-40℃，滴加乙醇钾溶液，然后加热回流1h。将反应物中乙醇蒸出回收，冷却后倾入水中分层，取有机层用水洗涤，干燥，减压蒸馏，收集98-100℃（2.67kPa）馏分，得六氯丙烯，收率86.7-89.2。
  • Acros Organics:Hexachloropropene, 96%(1888-71-7)
  • Sigma Aldrich:1888-71-7(sigmaaldrich)
  • 蒸气密度:8.3 (vs air)
  • Alfa Aesar:六氯丙烯,95% Hexachloropropene, 95%(1888-71-7)
  • 上游原料:乙醇钾 --> 1,1,1,2,2,3,3-七氯丙烷
  • MOL 文件:1888-71-7.mol
  • 六氯丙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 120450050 六氯丙烯 Hexachloropropene 96% 5 ML 132元 2010/05/25 L07808 六氯丙烯, 95% Hexachloropropene, 95% 50g 385元 2010/05/25 L07808 六氯丙烯, 95% Hexachloropropene, 95% 250g 1554元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl - Halogenated Hydrocarbons
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl - Halogenated Hydrocarbons

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