2-Butene, 2,3-dichlorohexafluoro- 六氟-2,3-二氯-2-丁烯

CAS 303-04-8 MFCD00000440

化学结构图

303-04-8
SMILES: FC(F)(F)/C(Cl)=C(\Cl)C(F)(F)F

化学属性

Mol. FormulaC4Cl2F6
Mol. Weight232.94
Refractive indexn20/D 1.3458(lit.)
Vapor Density8 (vs air)
Boiling Point66-68 °C(lit.)
Vapor Pressure4.42 psi ( 20 °C)
Density1.605 g/mL at 25 °C(lit.)
Melting Point-67 °C

别名和识别编码

Chemical Name2-Butene, 2,3-dichlorohexafluoro-
Synonym (2E)-2,3-Dichloro-1,1,1,4,4,4-hexafluoro-2-butene 1,1,1,4,4,4-Hexafluoro-2,3-dichloro-2-butene 2,3-DICHLOROHEXAFLUORO-2-BUTENE 2,3-DICHLOROHEXAFLUORO-2-BUTENE, 98%, MIXTURE OF CIS AND TRANS 2,3-DICHLOROHEXAFLUOROBUT-2-ENE 2,3-DICHLOROHEXAFLUOROBUTENE-2 2,3-Dichlorhexafluor-2-buten, cis/trans-Gemisch 2,3-Dichloro-1,1,1,4,4,4-hexafluoro-2-butene, cis and trans 2,3-Dichloro-1,1,1,4,4,4-hexafluorobutene-2 2,3-Dichlorohexafluoro-2-butene 2,3-Dichlorohexafluoro-2-butene, mixture of cis and trans 2,3-Dichlorohexafluorobut-2-ene 99% 2,3-Dichlorohexafluorobut-2-ene99% 2,3-Dichlorohexafluorobutene-2 2,3-dichloro-1,1,1,4,4,4-hexafluoro-2-buten 2,3-dichlorohexafluoro-2-buten 2,3-dichlorohexafluo
PubChem Substance ID2733252
EC Number206-133-2
MDL NumberMFCD00000440
CAS Number303-04-8
Chemical Name Translation六氟-2,3-二氯-2-丁烯
Wiswesser Line NotationFXFFYGUYGXFFF
InChIInChI=1S/C4Cl2F6/c5-1(3(7,8)9)2(6)4(10,11)12/b2-1+
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEM4910000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Hazard Codes T+ T+,Xi,T,C
Risk Statements
  • R26 Very toxic by inhalation 吸入极毒
  • R34 Causes burns 会导致灼伤
Packing GroupIII
Hazard Class8
UN Number UN 3389 6.1/PG 1
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 26 ppm/4H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   BJANAD British Journal of Anesthesia.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1923-  Vol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 182 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis)
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   JETOAS Journal Europeen de Toxicologie.  (Paris, France)  V.1-6, 1968-72.
   For publisher information, see TOERD9.  Volume(issue)/page/year: 4,517,1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOWCC* Dow Chemical Company Reports.  (Dow Chemical USA, Health and
   Environment Research, Toxicology Research Lab., Midland, MI 48640)
   Volume(issue)/page/year: -,-,1963

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 16 ppm/4H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   BJANAD British Journal of Anesthesia.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1923-  Volume(issue)/page/year:
   37,716,1965

其他信息

  • 蒸气压:4.42 psi ( 20 °C)
  • 图谱信息:六氟-2,3-二氯-2-丁烯(303-04-8)红外图谱(IR1) 六氟-2,3-二氯-2-丁烯(303-04-8)质谱(MS) 六氟-2,3-二氯-2-丁烯(303-04-8)核磁图( 13 CNMR)
  • 下游产品:三氟乙酸
  • 蒸气密度:8 (vs air)
  • MSDS 信息:六氟-2,3-二氯-2-丁烯(303-04-8).msds
  • Hazard Note:Irritant
  • MOL 文件:303-04-8.mol
  • 外观性质:无色液体。
  • Sigma Aldrich:303-04-8(sigmaaldrich)

系列性分类


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