2-Bromopyrimidine 2-溴嘧啶

CAS 4595-60-2 MFCD00014601

化学结构图

4595-60-2
SMILES: Brc1ncccn1

化学属性

Mol. FormulaC4H3BrN2
Mol. Weight158.98
Boiling Point249.9°C at 760 mmHg
Melting Point55-57°C
TSCAYes
Density1.422
Flash Point62-64°C/1.5mm
Appearance 淡黄色至黄色结晶。熔点69-73℃ 白色晶体, 熔点55-57℃

别名和识别编码

Chemical Name2-Bromopyrimidine
CAS Number4595-60-2
Alfabeta NameBROMOPYRIMIDINE 2-
MDL NumberMFCD00014601
PubChem Substance ID78345
EC Number224-993-7
Reaxys-RN605945
Beilstein Registry Number23(5)5,347
Synonym 2-Bromopyrimidine {LY} 2-Bromopyrimidine {} {LY} 2-Bromopyrimidine {} {} {LY} 2-Bromopyrimidine {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bro
Chemical Name Translation2-溴嘧啶
InChIKeyPGFIHORVILKHIA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00005667
InChIInChI=1S/C4H3BrN2/c5-4-6-2-1-3-7-4/h1-3H
Canonical SMILESBrC1=NC=CC=N1
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分类

  • {Chemicalbook} 农药中间体: 植物生长调节剂中间体
  • Building Blocks, C4 to C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyrimidines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, C4 to C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyrimidines

相关文献及参考

  • 1. Tetrahedron Lett. 48 , 2339, (2007)
  • Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster; Physical Ch

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition -20°C {LY} -20°C 0-10 0-10°C Keep Cold {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

其他信息

  • 2-溴嘧啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010141 2-溴嘧啶 1g 150元 2011/04/16 B2832 2-溴嘧啶 2-Bromopyrimidine 25G 1990元 2011/04/16 B2832 2-溴嘧啶 2-Bromopyrimidine 5G 663元
  • 用途一:5-溴代嘧啶是植物生长调节剂呋嘧醇的中间体。
  • Alfa Aesar:2-溴嘧啶,98+% 2-Bromopyrimidine, 98+%(4595-60-2)
  • Hazard Note:Irritant
  • Sigma Aldrich:4595-59-9(sigmaaldrich)
  • Sigma Aldrich:4595-60-2(sigmaaldrich)
  • Acros Organics:2-溴嘧啶 2-Bromopyrimidine, 97+%(4595-60-2)
  • TCI Shanghai:5-溴嘧啶 5-Bromopyrimidine,>;98.0%(GC)(4595-59-9)
  • 方法一:其制备方法是以二溴二氢呋喃酮与甲酰胺在B 2 O 2 催化剂存在下,180~185℃反应得产品。
  • 图谱信息:5-溴嘧啶(4595-59-9)质谱(MS) 5-溴嘧啶(4595-59-9)红外图谱(IR2) 5-溴嘧啶(4595-59-9)核磁图( 13 CNMR) 5-溴嘧啶(4595-59-9)核磁图( 1 HNMR) 5-溴嘧啶(4595-59-9)红外图谱(IR1)
  • MOL 文件:4595-59-9.mol
  • Acros Organics:5-Bromopyrimidine, 98%(4595-59-9)
  • TSCA:T
  • MOL 文件:4595-60-2.mol
  • 检测方法:HPLC
  • MSDS 信息:2-Bromopyrimidine(4595-60-2).msds
  • 下游产品:2-甲基嘧啶
  • MSDS 信息:5-Bromopyrimidine(4595-59-9).msds
  • 下游产品:嘧啶-5-甲醛 --> 5-羟基嘧啶 --> 5-羟基嘧啶 --> 嘧啶-5-羧酸 --> 5-嘧啶硼酸
  • 上游原料:2,3-二氢呋喃 --> 呋喃酮
  • Alfa Aesar:5-溴嘧啶,98% 5-Bromopyrimidine, 98%(4595-59-9)
  • 5-溴嘧啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2229 5-溴嘧啶 5-Bromopyrimidine 25G 701元 2010/06/21 204301000 5-溴嘧啶 5-Bromopyrimidine 98% 100 GR 2392元 2010/06/21 204300250 5-溴嘧啶 5-Bromopyrimidine 98% 25 GR 732元

系列性分类


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