2-Nitroamino-2-imidazoline 2-硝基氨基-2-咪唑啉

CAS 5465-96-3 MFCD00047040

化学结构图

5465-96-3
SMILES: O=[N+]([O-])NC1=NCCN1

化学属性

Mol. FormulaC3H6N4O2
Mol. Weight130.11
Melting Point220 °C
Appearance 咪唑烷纯品为白色结晶，m.p.213～215℃(分解)，工业品为白色或浅黄色粉末，含量≥98.0％，冷水中微溶，易溶于热水。
Boiling Point255.1±23.0 °C at 760 mmHg

别名和识别编码

Chemical Name2-Nitroamino-2-imidazoline
CAS Number5465-96-3
Synonym N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4,5-Dihydro-1H-imidazol-2-yl)nitramide {} {} {} {} {} {} {} {} {} {} {
Alfabeta NameNITROIMIDAZOLIDINIMINE N2---
MDL NumberMFCD00047040
Reaxys-RN134731
Beilstein Registry Number25(5)18,309
PubChem Substance ID87561544
Chemical Name Translation2-硝基氨基-2-咪唑啉
LabNetwork Molecule IDLN00175503
Canonical SMILESO=[N+](NC1=NCCN1)[O-]
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分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 其他杀虫剂

安全信息

Warnings IRRITANT
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P305+P351+P338
GHS Symbol
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:乙二胺 --> 硝酸胍 --> 工业盐酸 --> 硝基胍 --> N-硝基亚氨基咪唑烷
  • 用途一:用作高效低毒农药吡虫啉的中间体
  • 方法一:其制备方法是由硝基胍与乙二胺进行环合得到N-硝基亚氨基咪唑烷。 反应釜中加入硝基胍和碱液，在0℃加入乙二胺和30％工业盐酸，生成盐的悬浮液，缓慢升温至60℃，反应0.5h，立即转移至预冷釜，经结晶、离心过滤、干燥，得到咪唑烷。
  • 用途二:N-硝基亚氨基咪唑烷简称咪唑烷，是杀虫剂吡虫啉的中间体。
  • 2-硝基亚氨基咪唑烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0858 2-硝基氨基-2-咪唑啉 2-Nitroamino-2-imidazoline 5G 1250元 2014/06/02 N0858 2-硝基氨基-2-咪唑啉 2-Nitroamino-2-imidazoline 25G 4240元
  • MOL 文件:5465-96-3.mol

系列性分类

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