Silver fluoride 氟化银

CAS 7775-41-9 MFCD00003410

化学结构图

7775-41-9
SMILES: F[Ag]

化学属性

Mol. FormulaAgF
Mol. Weight126.87
Boiling Point1150 °C at 760 mmHg
TSCAT
Melting Point≥300°C
Density5.85
SolubilitySoluble in HF, ammonia, CH3CN
Flash Point1150°C
Appearance 它是黄棕色固体，熔点435℃，暴露于潮湿空气时变黑。与其他卤化银不同，氟化银可溶于水，溶解度为1.8 kg/L[1]，也可溶于乙腈。Ag-F键长:246pm,小于其它卤化银．共价半径为246pm，与Ag-F键长相同，应区别于其它卤化银．键型为离子键，也与其它卤化银相异．晶格类型类似于氯化钠，与氯化银／溴化银相同（碘化银晶格类型类似于硫化锌．）（其它卤化银均有共价键倾向：氯化银／溴化银的键型为过渡键，碘化银键型为共价键）

别名和识别编码

Chemical NameSilver fluoride
CAS Number7775-41-9
Alfabeta NameSILVERFLUORIDE I()
MDL NumberMFCD00003410
EC Number231-895-8
PubChem Substance ID165912
Synonym Silver(I) fluoride {LY} Silver(I) fluoride {} {LY} Silver(I) fluoride {} {} {LY} Silver(I) fluoride {} {} {} {LY} Silver(I) fluoride {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY}
Merck Number14,8514
Beilstein Registry Number2384789
Chemical Name Translation氟化银
LabNetwork Molecule IDLN00117348
InChIInChI=1S/Ag.FH/h;1H/q+1;/p-1
Canonical SMILES[Ag]F
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分类

  • {SNA} Chemical Synthesis, Fluorination, Fluorination Reagents, Materials Science, Metal and Ceramic Science, Salts, Silver Salts, Synthetic Reagents
  • {SNA} Analytical Reagents for General Use,
  • {SNA} Chemical Synthesis, Essential Chemicals, Fluorination, Fluorination Reagents, Materials Science, Metal and Ceramic Science, Research Essentials, Salts, Silver Salts, Synthetic Reagents
  • {SNA} Crystal Grade Inorganics
  • {SA} Crystal Grade Inorganics, Materials Science, Metal and Ceramic Science, Salts, Silver, Silver Salts
  • {SNA} Chemical Synthesis, Essential Chemicals,

产品应用

  • 用于由大位阻的三烷基甲硅烷基乙炔制备溴乙炔.也用于乙酰苯胺与三烷氧基硅烷的钯催化交叉偶联反应.

相关文献及参考

  • 1. Tetrahedron 62 , 4081, (2006)
  • 2. J. Am. Chem. Soc. 129 , 6066, (2007) 摘要
  • Corp MSDS 1 (2), 3095:B / RegBook 1 (3), 3311:D / Sax 6 , 2403
  • Fieser 2 ,364 / Fieser 5 ,581 / Fieser 6 ,514
  • Merck 14 ,8514
  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: III/23C1 Title: Electronic Structure of Solids: Photoemission Spectra and Related Data: Noble Metals, Noble Me

安全信息

Warnings HYGROSCOPIC, CORROSIVE
GHS Symbol
WGK Germany3
Hazard Codes 8 C
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H301+H311+H331
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSVW4250000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P303+P361+P353
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S25 Avoid contact with eyes 避免眼睛接触；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
UN Number 3260
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light & Moisture Sensitive & Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupII

其他信息

  • 敏感性:Moisture Sensitive & Hygroscopic
  • F:3-8-10-21
  • Sigma Aldrich:7775-41-9(sigmaaldrich)
  • Alfa Aesar:氟化银,98% Silver(I) fluoride, 98%(7775-41-9)
  • TSCA:T
  • Acros Organics:氟化银 Silver(I) fluoride, 99+%(7775-41-9)
  • 储运特性:库房低温通风干燥; 与氧化剂分开存放
  • MSDS 信息:Silver monofluoride(7775-41-9).msds
  • 可燃性危险特性:不燃; 火场释放含银和氟化物烟雾
  • 毒性分级:高毒
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 85.9g/0℃;120g/10℃;172g/20℃;190g/30℃;203g/40℃
  • 类别:腐蚀物质
  • Hazard Note:Corrosive
  • 灭火剂:水, 干粉, 二氧化碳, 泡沫
  • MOL 文件:7775-41-9.mol
  • 氟化银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 210450250 氟化银 Silver(I) fluoride 99+% 25 GR 4105元 2010/06/21 210450050 氟化银 Silver(I) fluoride 99+% 5 GR 1183元 2010/05/25 11609 氟化银, 98% Silver(I) fluoride, 98% 5g 620元
  • 职业标准:TWA 0.01 毫克/立方米; STEL 0.03 毫克/立方米

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Silver 银
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  5. Q-S, Puriss p.a. - Puriss p.a.
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Crystal Grade Inorganics 晶体级无机物
  4. Silver - Crystal Grade Inorganics
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Silver Salts - Salts
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents