2-Methyl-4-methoxyaniline 4-甲氧基-2-甲基苯胺

CAS 102-50-1 MFCD00007735

化学结构图

102-50-1
SMILES: COc1ccc(N)c(C)c1

化学属性

Mol. FormulaC8H11NO
Mol. Weight137.18
Boiling Point248-249°C at 760 mmHg
Refractive indexn20/D 1.565(lit.)
Density1.065
Melting Point13-14°C
Flash Point109°C
TSCAYes
Solubility不溶, <0.1 G/100 ML AT 21.5 ºC

别名和识别编码

Chemical Name2-Methyl-4-methoxyaniline
CAS Number102-50-1
Alfabeta NameMETHOXYMETHYLANILINE 42---
MDL NumberMFCD00007735
Synonym 4-Methoxy-2-methylaniline {LY} 4-Methoxy-2-methylaniline {} {LY} 4-Methoxy-2-methylaniline {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy-2-methylaniline {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87573409
EC Number203-036-7
Beilstein Registry Number13(4)1698
Chemical Name Translation4-甲氧基-2-甲基苯胺
Reaxys-RN774727
Wiswesser Line NotationZR B1 DO1
LabNetwork Molecule IDLN00008136
InChIInChI=1S/C8H11NO/c1-6-5-7(10-2)3-4-8(6)9/h3-5H,9H2,1-2H3
Canonical SMILESC1=C(OC)C=CC(=C1C)N
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分类

  • {SNA} Amines, Building Blocks, C8, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

安全信息

Warnings TOXIC
GHS Symbol
WGK Germany3
Hazard statements
  • H301+H311+H331
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSBZ6730000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+
  • P305+P351+P338+P337+P313
  • P332+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Packing GroupIII
UN Number 2810 UN2810
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
Hazard Codes Xn Xi Xi,Xn
Hazard Class6.1
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Refrigerator {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 29800 mg/kg/53W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,91,1982

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 30800 mg/kg/77W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,91,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 62 gm/kg/77W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-105,1978

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 14900 mg/kg/53W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 51500 ng/plate
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 1,190,1981

其他信息

  • 用途一:用作医药及染料中间体
  • TCI Shanghai:4-甲氧基-2-甲基苯胺 4-Methoxy-2-methylaniline,>;98.0%(GC)(T)(102-50-1)
  • Sigma Aldrich:102-50-1(sigmaaldrich)
  • 2-甲基-4-甲氧基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1474 4-甲氧基-2-甲基苯胺 4-Methoxy-2-methylaniline 500G 2900元 2014/06/02 M1474 4-甲氧基-2-甲基苯胺 4-Methoxy-2-methylaniline 25G 331元 2010/06/21 125910050 2-甲基-4-甲氧基苯胺 4-Methoxy-2-methylaniline 98% 5 GR 722元
  • Alfa Aesar:4-甲氧基-2-甲基苯胺,98% 4-Methoxy-2-methylaniline, 98%(102-50-1)
  • MOL 文件:102-50-1.mol
  • 下游产品:色酚 AS-LT --> 2-羟基-N-(4-甲氧基-2-甲基苯基)-11H-苯并[a]咔唑-3-甲酰胺
  • 上游原料:盐酸 --> 甲醇 --> 钠 --> 碳酸氢钠 --> 钯 --> 硫酸二甲酯 --> 铁粉 --> 水合肼 --> 甲醇钠 --> 4-硝基间甲苯酚
  • 图谱信息:2-甲基-4-甲氧基苯胺(102-50-1)红外图谱(IR1) 2-甲基-4-甲氧基苯胺(102-50-1)核磁图( 1 HNMR) 2-甲基-4-甲氧基苯胺(102-50-1)核磁图( 13 CNMR) 2-甲基-4-甲氧基苯胺(102-50-1)质谱(MS)
  • Acros Organics:4-甲氧基-2-甲基苯胺 4-Methoxy-2-methylaniline, 98%(102-50-1)
  • MSDS 信息:2-Methyl-4-methoxybenzenamine(102-50-1).msds
  • 检测方法:HPLC,NMR

系列性分类


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