(+)-B-CHLORODIISOPINOCAMPHENYLBORANE (+)二异松蒎基氯硼烷

CAS 112246-73-8 MFCD00074808

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 540234
(+)-Diisopinocampheylchloroborane (+)二异松蒎基氯硼烷
1.8 M solution in hexanes, SpcSeal 25mL 150
1.8 M solution 己烷
INFI 540234
(+)-Diisopinocampheylchloroborane (+)二异松蒎基氯硼烷
1.8 M solution in hexanes, SpcSeal 100mL 390
1.8 M solution 己烷
INFI 540234
(+)-Diisopinocampheylchloroborane (+)二异松蒎基氯硼烷
1.8 M solution in hexanes, SpcSeal 500mL 1,150
1.8 M solution 己烷
TCI 261531
(+)- B -Chlorodiisopinocampheylborane (58% in Hexane, ca . 1.6mol/L) >
ca. 1.6mol/L) 100mL 1,990
SH-CN BJ-CN TK-JP
中国国内现货 0
J&K 381886
(+)-Diisopinocampheylchloroborane, 1.8 M solution in hexanes, J&KSeal;
N/A 25mL 656
HB
中国国内现货 0
J&K 381886
(+)-Diisopinocampheylchloroborane, 1.8 M solution in hexanes, J&KSeal;
N/A 100mL 2,184
0
J&K 381886
(+)-Diisopinocampheylchloroborane, 1.8 M solution in hexanes, J&KSeal;
N/A 800mL 10,482
0
Acros 307387
(+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes, AcroSeal?
100mL 1,847
SH-CN
中国国内现货 0
Acros 307387
(+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes, AcroSeal?
800mL 19,548
0
Adamas 473127
1.8M solution in hexanes 100mL 300
SH-CN CN
中国国内现货 0
Adamas 473128
1.8M solution in hexanes 500mL 1,280
SH-CN CN
中国国内现货 0
Adamas 473129
1.8M solution in hexanes 25mL 559
0
Energy-chemical 473130
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 25mL 108
CN-BJ CN-SH
中国国内现货 60
Energy-chemical 473130
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 100mL 255
CN-BJ CN-SH
中国国内现货 60
Energy-chemical 473130
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 500mL 845
CN-BJ CN-SH
中国国内现货 60
Aladdin 473131
(+)-B-Chlorodiisopinocampheylborane (+)二异松蒎基氯硼烷
60% in Heptane,ca. 1.7mol/L 5mL 108
60
Aladdin 473131
(+)-B-Chlorodiisopinocampheylborane (+)二异松蒎基氯硼烷
60% in Heptane,ca. 1.7mol/L 25mL 108
CN-SH
中国国内现货 60
Aladdin 473131
(+)-B-Chlorodiisopinocampheylborane (+)二异松蒎基氯硼烷
60% in Heptane,ca. 1.7mol/L 100mL 255
CN-SH
中国国内现货 60
Aladdin 473131
(+)-B-Chlorodiisopinocampheylborane (+)二异松蒎基氯硼烷
60% in Heptane,ca. 1.7mol/L 500mL 842
CN-SH
中国国内现货 60
Adamas 516484
60% in Heptane, ca. 1.7mol/L, SafeSeal 500mL 1,398
60+ % solution Heptane
Adamas 516486
60% in Heptane, ca. 1.7mol/L, SafeSeal 100mL 559
SH-CN BJ-CN
中国国内现货 60+ % solution Heptane
HY 530294
(+)-Diisopinocampheylchloroborane (+)二异松蒎基氯硼烷
1.7 M solution in heptane, SpcSeal 25mL -
1.7 M solution Heptane
HY 530294
(+)-Diisopinocampheylchloroborane (+)二异松蒎基氯硼烷
1.7 M solution in heptane, SpcSeal 100mL -
1.7 M solution Heptane
HY 530294
(+)-Diisopinocampheylchloroborane (+)二异松蒎基氯硼烷
1.7 M solution in heptane, SpcSeal 500mL -
1.7 M solution Heptane
Energy-chemical 573841
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
1.7mol/L in Heptane,Energyseal 100mL 295
CN-BJ CN-SH
中国国内现货 1.7 M solution Heptane
Energy-chemical 573841
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
1.7mol/L in Heptane,Energyseal 500mL 975
CN-SH
中国国内现货 1.7 M solution Heptane
Energy-chemical 577158
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
95% 5g 108
90+ %
Energy-chemical 577158
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
95% 25g 295
90+ %
Energy-chemical 577158
(+)-Diisopinocampheyl chloroborane (+)-二异松蒎基氯硼烷
95% 100g 975
90+ %
Aladdin 632863
100mL 295
SH-CN
中国国内现货
Aladdin 632864
500mL 970
SH-CN
中国国内现货
Aladdin 632865
25mL 108
SH-CN BJ-CN
中国国内现货
Acros 712534
100mL 2,693
BJ-CN
中国国内现货
Acros 712535
800mL 19,939
TRC 712536
1mL 630
TRC 712536
5mL 840
TRC 712536
10mL 1,330
TRC 712536
25mL 2,730
TRC 712536
50mL 5,250
Aldrich 712537
5g 642
Aldrich 712538
25g 2,201

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261305+351+338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P280305+351+338310
  • P308+313 IF exposed or concerned: Get medical advice/attention. 如接触到或有疑虑:求医/就诊。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P301+330+331+310
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P304+340+310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+310+331
Packing GroupII
Storage condition
  • 0-10
  • 2-8°C
  • 0-10°C
  • 储存温度2-8°C
  • 2-8℃保存
UN Number
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Hazard Codes
Hazard Class3/8

其他信息

  • Sigma Aldrich:112246-73-8(sigmaaldrich)
  • MOL 文件:112246-73-8.mol
  • 和水剧烈反应
  • (+)-二异松蒎基氯硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1614 (+)-B-二异松蒎基氯硼烷(58%的己烷溶液,约1.6mol/L) (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L) 100ML 2570元 2010/06/21 388428000 (+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane , 1.8M solution in hexanes, AcroSeal® 800 ML 20648元 2010/06/21 388421000 (+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane , 1.8M solution in hexanes, AcroSeal® 100 ML 6938元
  • 稳定性:(+)-二异松蒎基氯硼烷(112246-73-8)对水较敏感, 极易与空气中或溶剂中的水分反映生成氯化氢。受到空气中氧气氧化作用使其对酮的还原性降低。
  • TCI Shanghai:(+)-二异松蒎基氯硼烷(58%的正己烷溶液,约1.6mol/L) (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)(112246-73-8)
  • 用途一:(+)-二异松蒎基氯硼烷(112246-73-8) are used for high enantiselective asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.
  • F:10-21
  • 外观:无色透明液体
  • Acros Organics:(+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes, AcroSeal?(112246-73-8)
  • Alfa Aesar:(+)-DIP chloride, 97%(112246-73-8)

化学结构图

CAS 112246-73-8  MFCD00074808
SMILES: CC1(C)[C@@H]2C[C@H]1C[C@H](B(Cl)[C@H]1C[C@@H]3C[C@H]([C@@H]1C)C3(C)C)[C@H]2C

化学属性

Mol. FormulaC20H34BCl
Mol. Weight320.75
Density0.90
Flash Point>;230 °F
Melting Point53-55 °C(lit.)

别名和识别编码

Chemical Name(+)-Diisopinocampheylchloroborane
MDL NumberMFCD00074808
CAS Number112246-73-8
EC Number250-023-7
Beilstein Registry Number2384789
Reaxys-RN13205713
PubChem Substance ID 87566609
Chemical Name Translation(+)二异松蒎基氯硼烷
Synonym
  • (+)-Diisopinocampheyl chloroborane
  • (+)-IPC2BCL
  • (+)-氯化二异松蒎基硼烷
  • (+)-DIP CHLORIDE
  • (+)-Diisopinocampheylchloroborane
  • (+)-beta-Chlorodiisopinocampheylborane (ca. 65% in n-hexane)
  • (+)-DIP chloride
  • (+)-DIP-CHLORIDE IN HEPTANES, 2M SOLUTION
  • (+)-B-氯二异蒎莰硼烷
  • (+)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
  • (+)-DIP chloride[R]
  • (+)二异松蒎基氯硼烷
  • (+)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
  • (+)-B-二异松蒎基氯硼烷

    系列性分类


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