ALLYLMAGNESIUM BROMIDE 1M 烯丙基溴化镁2-甲基四氢呋喃溶液

CAS 1730-25-2 MFCD00000044

化学结构图

1730-25-2
SMILES: C=CC[Mg]Br

化学属性

Mol. FormulaCH2=CHCH2MgBr
Mol. Weight145.28
Density0.851
Flash Point-40 ºC
Stability对湿度敏感
Density0.851
Mol. FormulaCH2=CHCH2MgBr
Mol. Weight145.28
Mol. FormulaCH2=CHCH2MgBr
Mol. Weight145
Appearance liq.
Stabilityair sensitive, moisture sensitive

别名和识别编码

Chemical NameALLYLMAGNESIUM BROMIDE
CAS Number1730-25-2
EC Number217-046-4
Beilstein Registry Number969335
MDL NumberMFCD00000044
PubChem Substance ID74413
Synonym Allylbromomagnesium Allyl magnesium bromide Magnesium, allylbromo- 烯丙基溴化镁 溶液 Bromo(2-propenyl)magnesium 烯丙基溴化镁 Allylmagnesiumbromid Magnesium, bromo-2-propenyl- 2-Propenylmagnesium bromide Allylmagnesium bromide
Chemical Name Translation1M 烯丙基溴化镁2-甲基四氢呋喃溶液
InChIKeyFEMBXICCJNZMMC-UHFFFAOYSA-M
LabNetwork Molecule IDLN01314619
InChIInChI=1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q-1;;+2/p-1
MDL NumberMFCD00000044
CAS Number1730-25-2
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
  • Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

产品应用

  • 格氏试剂

相关文献及参考

  • Beilstein: 4,II,1042
  • Short: EINECS
  • Short: III/35D5

安全信息

Signal word
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S29 Do not empty into drains 不要排入下水道;
Risk Statements
  • R12 Extremely flammable 极端易燃
  • R22 Harmful if swallowed 吞咽有害
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P334
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P335+P334
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,C F+;C F+,C
UN Number
Packing GroupI
Storage condition 密封充氩保存

系列性分类


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