Lithium triethylborohydride 三乙基硼氢化锂

CAS 22560-16-3 MFCD00011703

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H74571
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, SpcSeal 25mL ¥ 130
库存 辽宁
中国国内现货 1.0 M solution 四氢呋喃
INFI H74571
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, SpcSeal 100mL ¥ 370
库存 辽宁
中国国内现货 1.0 M solution 四氢呋喃
INFI H74571
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, SpcSeal 500mL ¥ 1,330
库存 辽宁
中国国内现货 1.0 M solution 四氢呋喃
Innochem A71966
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, resealable bottle 100mL ¥ 600
1.00 M solution in THF
Innochem A71966
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, resealable bottle 500mL ¥ 1,930
1.00 M solution in THF
Innochem A71966
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, resealable bottle 800mL ¥ 3,390
1.00 M solution in THF
Innochem A71966
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, resealable bottle 8L ¥ 12,170
1.00 M solution in THF
Innochem A19473
Lithium triethylborohydride
1.0M in THF 25mL ¥ 146
1.0 M solution 四氢呋喃
Innochem A19473
Lithium triethylborohydride
1.0M in THF 100mL ¥ 264
1.0 M solution 四氢呋喃
Alfa 89144
Lithium triethylborohydride
1M in THF 25mL ¥ 349
96-99 %
Alfa 89144
Lithium triethylborohydride
1M in THF 100mL ¥ 716
96-99 %
Alfa 89144
Lithium triethylborohydride
1M in THF 500mL ¥ 3,091
96-99 %
Alfa 089144
Lithium triethylborohydride
1M in THF 25mL ¥ 262
库存 上海市 北京 China, PRC
中国国内现货 96-99 %
Alfa 089144
Lithium triethylborohydride
1M in THF 100mL ¥ 545
库存 北京
中国国内现货 96-99 %
Alfa 089144
Lithium triethylborohydride
1M in THF 500mL ¥ 2,351
96-99 %
Alfa 042491
Lithium triethylborohydride
packaged under Argon in resealable ChemSeal^t bottles 25mL ¥ 250
库存 上海市 北京
中国国内现货 96-99 %
Alfa 042491
Lithium triethylborohydride
packaged under Argon in resealable ChemSeal^t bottles 50mL ¥ 306
库存 上海市 北京
中国国内现货 96-99 %
Alfa 042491
Lithium triethylborohydride
packaged under Argon in resealable ChemSeal^t bottles 100mL ¥ 520
库存 上海市 北京
中国国内现货 96-99 %
Alfa 042491
Lithium triethylborohydride
packaged under Argon in resealable ChemSeal^t bottles 500mL ¥ 2,209
库存 上海市
中国国内现货 96-99 %
TCI L0190
Lithium Triethylborohydride ( ca . 12% in Tetrahydrofuran, ca . 1.0mol/L) >
100mL ¥ 790
库存 Tokyo, Japan 上海市
中国国内现货 96-99 %
TCI L0190
Lithium Triethylborohydride ( ca . 12% in Tetrahydrofuran, ca . 1.0mol/L) >
500mL ¥ 3,100
库存 Tokyo, Japan
中国国内现货 96-99 %
J&K 509190
Lithium triethylborohydride, 1.0 M solution in THF, J&KSeal;
100mL ¥ 618
库存 HB SH
中国国内现货 96-99 %
J&K 509190
Lithium triethylborohydride, 1.0 M solution in THF, J&KSeal;
800mL ¥ 3,937
库存 HB SH
中国国内现货 96-99 %
Aldrich 179728
Super-Hydride? solution
1.0?M 100mL ¥ 903
库存 SH
中国国内现货 96-99 %
Aldrich 179728
Super-Hydride? solution
1.0?M 800mL ¥ 4,652
96-99 %
Acros 450691000
AcroSeal? 100mL ¥ 473
96-99 %
Acros 45069
Lithium triethylborohydride, 1.7M solution in THF, AcroSeal
100mL ¥ 721
96-99 %
Acros 45069
Lithium triethylborohydride, 1.7M solution in THF, AcroSeal
800mL ¥ 3,931
96-99 %
Aladdin L124097
Lithium triethylborohydride 三乙基硼氢化锂
1M in THF 25mL ¥ -
库存 上海市
中国国内现货 96-99 %
Aladdin L124097
Lithium triethylborohydride 三乙基硼氢化锂
1M in THF 100mL ¥ -
库存 上海市
中国国内现货 96-99 %
Aladdin L124097
Lithium triethylborohydride 三乙基硼氢化锂
1M in THF 500mL ¥ -
库存 上海市
中国国内现货 96-99 %
Aladdin L124097
Lithium triethylborohydride 三乙基硼氢化锂
1M in THF 800mL ¥ -
库存 上海市
中国国内现货 96-99 %
HY Y12954
Super-Hydride® solution Super-Hydride® 溶液
1.0 M solution in THF, HSeal 100mL ¥ -
1.00 M solution in THF
HY Y12954
Super-Hydride® solution Super-Hydride® 溶液
1.0 M solution in THF, HSeal 500mL ¥ -
1.00 M solution in THF
HY Y12954
Super-Hydride® solution Super-Hydride® 溶液
1.0 M solution in THF, HSeal 800mL ¥ -
1.00 M solution in THF
HY Y65077
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, HySeal 100mL ¥ -
1.00 M solution in THF
HY Y65077
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, HySeal 500mL ¥ -
1.00 M solution in THF
HY Y65077
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, HySeal 800mL ¥ -
1.00 M solution in THF
HY Y65077
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, HySeal 8L ¥ -
1.00 M solution in THF
Adamas 38780D
1.0 M solution in THF, SafeSeal 100mL ¥ 460
库存 China, PRC
中国国内现货 1.0 M solution 四氢呋喃
Adamas 38780E
1.0 M solution in THF, SafeSeal 500mL ¥ 2,200
1.00 M solution in THF
Adamas 38780F
1.0 M solution in THF, SafeSeal 800mL ¥ 4,000
1.0 M solution 四氢呋喃
Meryer M11112
三乙基硼氢化锂
1M in THF 25mL ¥ 189
96-99 %
Meryer M11112
三乙基硼氢化锂
1M in THF 100mL ¥ 503
96-99 %
Meryer M11112
三乙基硼氢化锂
1M in THF 500mL ¥ 2,269
96-99 %
Energy-chemical W420197
LITHIUM TRIETHYLBOROHYDRIDE 三乙基硼氢化锂
1.0 mol/l in THF , Energyseal 25mL ¥ 158
库存 上海市 北京市
中国国内现货 1.0 M solution 四氢呋喃
Energy-chemical W420197
LITHIUM TRIETHYLBOROHYDRIDE 三乙基硼氢化锂
1.0 mol/l in THF , Energyseal 100mL ¥ 462
库存 北京市
中国国内现货 1.0 M solution 四氢呋喃
Energy-chemical W420197
LITHIUM TRIETHYLBOROHYDRIDE 三乙基硼氢化锂
1.0 mol/l in THF , Energyseal 500mL ¥ 1,670
1.0 M solution 四氢呋喃
Energy-chemical W420197
LITHIUM TRIETHYLBOROHYDRIDE 三乙基硼氢化锂
1.0 mol/l in THF , Energyseal 1L ¥ 2,970
1.0 M solution 四氢呋喃
3A A11059
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, SpcSeal 100ml ¥ 480
1.0 M solution 四氢呋喃
3A A11059
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, SpcSeal 500ml ¥ 1,930
1.0 M solution 四氢呋喃
3A A11059
Lithium triethylborohydride 三乙基硼氢化锂
1.0 M solution in THF, SpcSeal 800ml ¥ 3,390
1.0 M solution 四氢呋喃
Aladdin L124097-25ml
25mL ¥ 158
Aladdin L124097-100ml
100mL ¥ 462
Aladdin L124097-500ml
500mL ¥ 1,670
TRC L469160
Lithium Triethylborohydride (1.0 M in THF)
25mL ¥ 770
1.0 M solution 四氢呋喃
TRC L469160
Lithium Triethylborohydride (1.0 M in THF)
50mL ¥ 1,400
1.0 M solution 四氢呋喃
TRC L469160
Lithium Triethylborohydride (1.0 M in THF)
100mL ¥ 2,380
1.0 M solution 四氢呋喃
TRC L469160
Lithium Triethylborohydride (1.0 M in THF)
250mL ¥ 5,600
1.0 M solution 四氢呋喃
TRC L469160
Lithium Triethylborohydride (1.0 M in THF)
500mL ¥ 9,800
1.0 M solution 四氢呋喃
Acros 450698000
800mL ¥ 2,577
Aladdin L124097-800ml
800mL ¥ 3,599
Aldrich 179728-100ML
100mL ¥ 975
Aldrich 179728-800ML
800mL ¥ 5,025

分类

  • {SNA} Chemical Reagents, Borohydrides, Chemical Synthesis, Development Quantities for Research, Reduction, Synthetic Reagents
  • {SNA} Borohydrides, Chemical Synthesis, Reduction, Synthetic Reagents
  • {SNA} Borohydrides, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Reduction, Synthetic Reagents

产品应用

  • 由环状酮乙烯基三氟甲磺酸酯裂解生成的炔基醇。
  • 本品的化学活性很高。密度是0.892g/ml,闪点是-17°C。 在常温下,它能迅速和水、盐酸、甲磺酸以及甲醇等反应,  放出氢气。它可溶于四氢呋喃等醚类溶剂。它的四氢呋喃溶 液在氮气中非常稳定,但若放置于空气或湿气中,则迅速分 解。本品是一种极强的亲核还原剂,其还原能力比其母体硼  氢化锂强得多,在许多反应中也优于氢化铝锂。
  • 在有机合成中做还原剂,它能还原醛酮、羧酸、羧酸衍生 物、伯酰胺、叔酰胺、脂肪族硝基化合物、酯、内酯、含硫化  合物、磺酸、 由环状酮乙烯基三氟甲磺酸酯裂解生成的炔基醇。

安全信息

WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupI
UN Number
  • 3399
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition
  • Moisture Sensitive
  • Flammables + water-Freezer (-20°C)e area
  • 充氩保存
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P231+232 Handle under inert gas. Protect from moisture. 在惰性气体中。防止受潮。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P301+330+331+310
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word
  • Danger
Hazard Codes
  • F,C
Hazard Class4.3/3

其他信息

  • 高度易燃空气敏感,-20℃冷藏存储; 实验室使用时,建议手套箱或者手套袋中操作并使用盛必诚抽取式安全包装;

化学结构图

CAS 22560-16-3  MFCD00011703
SMILES: CC[BH-](CC)CC.[Li+]

化学属性

Mol. FormulaC6H16BLi
Mol. Weight105.94
Density0.892 g/mL at 25 °C
Flash Point-17°(1°F)
TSCANo
Stability对湿度敏感

别名和识别编码

Chemical NameLithium triethylborohydride
MDL NumberMFCD00011703
Beilstein Registry Number4(4)4359
Synonym
  • super-hydride (lithium triethylboro-hydride
  • 三乙基硼氢化锂, 1M IN THF
  • 三乙基硼氢化锂 溶液
  • lithium triethylhydridoborate, 1m in thf
  • lithiumtriethylborohydride,calselect?lt,intetrahydrofuran
  • lithium triethylhydridoborate, 1m in thf, packaged under argon in resealable chemseal
  • Lithium triethylborohydride, in tetrahydrofuran, 1M solution
  • 三乙基硼氢化锂, 1M IN THF, PACKAGED UNDER ARGON IN RESEALA
  • Borate(1-), triethylhydro-, lithium, (T-4)-
  • LITHIUM TRIETHYLBOROHYDRIDE-SOL. 1 M IN
  • Lithium triethylhydridoborate
  • SUPER-HYDRIDE(R)
  • 三乙基硼氢化锂1M四氢呋喃溶液
  • Lithium triethylhydroborate
  • 三乙基硼氢化锂
  • LITHIUM TRIETHYLHYDROBORATE
  • lithium triethylborohydride solution
  • Super-Hydride® 溶液
  • lithiumtriethylborohydride,calselect?lt,
  • Lithium triethylborohydride, 1M solution in THF
  • Lithium borohydride thiethyl
  • SUPER-HYDRIDE (LITHIUM TRIETHYLBORO-HYDR IDE, 1.0M SOLUTION IN THF)
  • Lithiumtriethylhydroborat
  • 三乙基硼氢化锂溶液;三乙基硼氢化锂
    CAS Number22560-16-3
    Merck Number5544
    PubChem Substance ID253660352
    EC Number250-023-7
    Chemical Name Translation三乙基硼氢化锂
    Reaxys-RN4151240
    LabNetwork Molecule IDLN01330567

    系列性分类


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