Samarium(II) iodide 碘化钐

CAS 32248-43-4 MFCD00058873

高端品牌产品

品牌质保精细包装    现货库存    一流品牌服务   
包装筛选
规格筛选
现货筛选
产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H50977
Samarium(II) iodide 碘化钐
0.1 M solution in THF, stabilized with Samarium powder, SpcSeal 25mL ¥ 140
0.1 M solution 四氢呋喃
INFI H50977
Samarium(II) iodide 碘化钐
0.1 M solution in THF, stabilized with Samarium powder, SpcSeal 100mL ¥ 390
0.1 M solution 四氢呋喃
INFI H50977
Samarium(II) iodide 碘化钐
0.1 M solution in THF, stabilized with Samarium powder, SpcSeal 500mL ¥ 1,400
0.1 M solution 四氢呋喃
INFI H26805
Samarium(II) iodide 碘化钐
99% 1g ¥ 980
96-99 %
INFI H26805
Samarium(II) iodide 碘化钐
99% 5g ¥ 2,980
96-99 %
TCI S0494
Samarium(II) Iodide ( ca . 0.1mol/L in Tetrahydrofuran) >
25mL ¥ 404
库存 上海市 Tokyo, Japan
中国国内现货 96-99 %
TCI S0494
Samarium(II) Iodide ( ca . 0.1mol/L in Tetrahydrofuran) >
100mL ¥ 1,450
96-99 %
Alfa 022360
Samarium(II) iodide
0.07 - 0.12M in THF, stab. 0.01mole ¥ 608
库存 北京 China, PRC
中国国内现货 96-99 %
Alfa 022360
Samarium(II) iodide
0.07 - 0.12M in THF, stab. 100mL ¥ 701
96-99 %
Alfa 022360
Samarium(II) iodide
0.07 - 0.12M in THF, stab. 500mL ¥ 2,889
96-99 %
Aldrich 409340
Samarium(II) iodide
anhydrous, 1g ¥ 1,604
99e1
Aldrich 409340
Samarium(II) iodide
anhydrous, 5g ¥ 5,541
99e1
Acros 29499
Samarium(II) iodide, 0.1M solution in THF, stabilized with Samarium powder, AcroSeal
100mL ¥ 820
库存 北京
中国国内现货 96-99 %
Aldrich 347116
Samarium(II) iodide solution 碘化钐(II) 溶液
0.1 M in THF 0.1 M in THF, contains samarium chips as stabilizer 25mL ¥ 475
96-99 %
Aldrich 347116
Samarium(II) iodide solution 碘化钐(II) 溶液
0.1 M in THF 0.1 M in THF, contains samarium chips as stabilizer 100mL ¥ 686
库存 SH
中国国内现货 96-99 %
Aldrich 347116
Samarium(II) iodide solution 碘化钐(II) 溶液
0.1 M in THF 0.1 M in THF, contains samarium chips as stabilizer 4x25mL ¥ 686
96-99 %
Aldrich 347116
Samarium(II) iodide solution 碘化钐(II) 溶液
0.1 M in THF 0.1 M in THF, contains samarium chips as stabilizer 1L ¥ 3,105
96-99 %
Energy-chemical 32248A43A4
0.09-0.11M in THF 25mL ¥ 364
96-99 %
Energy-chemical 32248A43A4
0.09-0.11M in THF 100mL ¥ 1,115
96-99 %
Acros 294991000
AcroSeal? 100mL ¥ 611
96-99 %
Adamas 48130B
0.09-0.11M in THF 100mL ¥ 805
96-99 %
Adamas 48130C
0.09-0.11M in THF 500mL ¥ 2,550
96-99 %
Adamas 48130A
0.09-0.11M in THF 25mL ¥ 251
96-99 %
Strem 62-3100
Samarium(II) iodide
0.1M in THF 50mL ¥ 525
库存 HB
中国国内现货 96-99 %
Strem 62-3100
Samarium(II) iodide
0.1M in THF 250mL ¥ 2,100
96-99 %
TRC S100910
Samarium(II) Iodide (0.1M in THF)
1g ¥ 1,680
96-99 %
TRC S100910
Samarium(II) Iodide (0.1M in THF)
10g ¥ 2,100
96-99 %
TRC S100910
Samarium(II) Iodide (0.1M in THF)
25g ¥ 4,900
96-99 %
Aladdin S128315-500ml
500mL ¥ 2,499
Aladdin S128315-100ml
100mL ¥ 699
3A A01881
Samarium(II) iodide 碘化钐
0.1M solution in THF, stabilized with Samarium powder,SpcSeal 25mL ¥ 230
0.1 M solution THF
3A A01881
Samarium(II) iodide 碘化钐
0.1M solution in THF, stabilized with Samarium powder,SpcSeal 100mL ¥ 650
0.1 M solution THF
Energy-chemical W430029
SAMARIUM(II) IODIDE 碘化钐
25mL ¥ 199
Energy-chemical W430029
SAMARIUM(II) IODIDE 碘化钐
100mL ¥ 350
库存 上海市
中国国内现货
Energy-chemical W430029
SAMARIUM(II) IODIDE 碘化钐
500mL ¥ 1,200
Aladdin S128315-25ml
25mL ¥ 279
Aldrich 347116-4X25ML
4x25mL ¥ 1,342
Aldrich 347116-25ML
25mL ¥ 584
Aldrich 347116-100ML
100mL ¥ 818
Aldrich 347116-1L
1L ¥ 3,498
Aldrich 409340-1G
1g ¥ 1,797
Aldrich 409340-5G
5g ¥ 6,208

分类

  • {SNA} 25mL Sure/Seal Reagents, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Organometallic Reagents, Others, Reduction, Research Essentials, Salts, Samarium, Samarium Salts, Synthetic Reagents, 材料科学
  • {SNA} 25mL Sure/Seal Reagents, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Organometallic Reagents, Other Synthetic Reagents for Reduction, Reduction, Research Essentials, Salts, Samarium,

产品应用

  • ⑴.常温常压下为蓝色至深蓝色液体,具有特殊气味。在极性有机溶剂中有一定的溶解度,通常在THF,HMPA中使用。刺激皮肤和粘膜。 ⑵. 遇水分解生成碱式碘化钐和氢气。有强还原性。具有较强的吸湿性,对氧气特别敏感,需要在惰性气体保护下制备和使用。一般保存于约0.1mol/L的四氢呋喃溶液中。 ⑶. 碘化钐(SmI2)是有机合成中一个具有广泛用途的试剂。它参与的主要反应包括:自由基环化反应;羰基-烯烃偶联反应;频哪偶联反应;羟醛缩合反应;Barbier反应;Reformatsky反应等。 ①. SmI2最基本

相关文献及参考

  • 1. Synthesis , 1309, (2007)
  • Merck 14 ,8349
  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: III/7a Title: Crystal Structure Data of Inorganic Compounds: Key Elements: F, Cl , Br, I ( VII th Main Group) . Halides and Complex Halides Author: Pies, W.; Weiss, A. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/7a Page: 1-647 Year: 1973 ISBN: 3-540-06166-5 ISBN: 978-3-540-06166-3 Internet Resource: DOI:10.1007/b19972 RefComment: 1 fig., XXXII, Hardcover Abstract: Volume III/7 contains structure data on those compounds which contain at least one of the elements F, Cl, Br, I, O, N, and P and cannot be called "organic". The structure data of the remaining inorganic compounds and the elements are dealt with in volumes III/6 and III/14, while the organic compounds are treated in volumes III/5 and III/10. The systematic arrange-ment is bas

安全信息

WGK Germany3
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
  • Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
UN Number
  • UN3271
  • 2056
Signal word
  • {} {} {TCI}
  • Danger
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P301+312+330
  • P337+313 IF eye irritation persists: Get medical advice/attention. 如果眼睛刺激持续:获取医疗咨询/就医。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P302+352+332+313+362+364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+340+312
  • P305+351+338+337+313
  • P308+311
  • P309+311 IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. 如果接触或感到不适:呼叫解毒中心或医生/医师。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
  • P241+242+243
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H351 Suspected of causing cancer 怀疑致癌
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S30 Never add water to this product 切勿将水加入该产品中;
  • S29 Do not empty into drains 不要排入下水道;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
Storage condition
  • Air & Moisture Sensitive
Packing GroupII
GHS Symbol
Hazard Codes
  • F,Xn
  • F,Xi
Hazard Class3

其他信息

  • ⑴. 不要让未稀释或大量的产品接触地下水、水道或污水系统。若无政府许可,勿将材料排入周围环境。 ⑵. 存于阴凉、干燥、通风良好的不燃库房。远离火种、热源。

化学结构图

CAS 32248-43-4  MFCD00058873
SMILES: I[Sm]I

化学属性

Mol. FormulaSmI2
Mol. Weight404.17
Density0.922 g/mL at 25 °C
TSCANo
Mol. FormulaI2Sm
Mol. Weight404.21
Density0.922 g/ml
Appearance
  • liq. stabilized with Sm pwdr.
    Stabilityair sensitive, moisture sensitive

    别名和识别编码

    Chemical NameSamarium(II) iodide
    MDL NumberMFCD00058873
    PubChem Substance ID24861467
    CAS Number32248-43-4
    Merck Number8349
    EC Number203-726-8
    Synonym
    • {uni_hamburg}
    • Samarium(II)-iodid
    • Samarium(II)iodid
    • SmI2
    • samarium (II) iodide
    • Samarium(II) iodide
    • 碘化钐(II)
    • 碘化钐(II) 溶液
    • Samarium diiodide
      Chemical Name Translation碘化钐
      MDL NumberMFCD00058873
      CAS Number32248-43-4
      LabNetwork Molecule IDLN01295309

      系列性分类


      相关产品推荐