1,4-Phenylenebisboronic acid 1,4-苯二硼酸

CAS 4612-26-4 MFCD00236018

化学结构图

4612-26-4
SMILES: OB(O)c1ccc(B(O)O)cc1

化学属性

Mol. FormulaC6H8B2O4
Mol. Weight165.75
Melting Point>350°C
TSCANo
Density1.33
Boiling Point420.1±55.0 °C at 760 mmHg

别名和识别编码

Chemical Name1,4-Phenylenebisboronic acid
CAS Number4612-26-4
Alfabeta NamePHENYLENEBISBORONICACID 14()-,
MDL NumberMFCD00236018
Synonym 1,4-Phenylenediboronic acid {LY} 1,4-Phenylenediboronic acid {} {LY} 1,4-Phenylenediboronic acid {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenediboronic acid {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number2836921
PubChem Substance ID87575444
Reaxys-RN2836921
EC Number250-023-7
Chemical Name Translation1,4-苯二硼酸
LabNetwork Molecule IDLN00117601
Canonical SMILESOB(O)C1=CC=C(B(O)O)C=C1
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Yuan, M.; et al. , Constructing Regioregular Star Poly(3-hexylthiophene) via Externally Initiated Kumada Catalyst-Transfer Polycondensation ACS Macro Lett. 3rd ed., 1 , 392-395, (2012)
  • 2. Wan, J.; et al. , Multifunctional electron-transporting indolizine derivatives for highly efficient blue fluorescence, orange phosphorescence host and two-color based white OLEDs J. Mater. Chem. 10th ed., 22 , 4502-4510, (2012)
  • 3. Marques, A. T.; et al., Energy transfer from fluorene-based conjugated polyelectrolytes to on-chain and self-assembled porphyrin units J. Polym. Sci. 7th ed., 50 , 1408-1417, (2012)
  • 4. Kim, B-S.; Lee, S-Y.; Youn, S-W., Pd-Catalyzed Sequential C-C and C-N Bond Formations for the Synthesis of N-Heterocycles: Exploiting Protecting Group-Directed C-H Activation under Modified Reaction Conditions Chem. Asian J. 8th ed., 6 , 1952-1957, (2011)
  • 5. Pradhan, A.; et al., Highly Twisted Arenes by Scholl Cyclizations with Unexpected Regioselectivity Angew. Chem. Int. Ed. Engl. 52th ed., 50 , 12582-12585, (2011)
  • 6. Nakabayashi, K.; Oya, H.; Mori, H., Cross-Linked Core-Shell Nanoparticles Based on Amphiphilic Block Copolymers by RAFT Polymerization and Palladium-Catalyzed Suzuki Coupling Reaction Macromolecules 7th ed., 45 , 3197-3204, (2012)
  • 7. Basak, S.; et al., Micropatterning of metallopolymers: syntheses of back-to-back coupled octylated 2,6-bis(pyrazolyl)pyridine ligands and their solution-processable coordination polymers J. Org. Chem. 7th ed., 77 , 3620-3626, (2012) 摘要
  • 8. Yu, J-T.; et al. , Cyclotricatechylene based porous crystalline material: Synthesis and applications in gas storage J. Mater. Chem. 12th ed., 22 , 5369-5373, (2012)
  • 9. Watanabe, K.; et al. , Helically p-Stacked Thiophene-Based Copolymers with Circularly Polarized F

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Signal word Warning {} {} {} {} {TCI}
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn,C,Xi Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • 1,4-苯二硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw070015 1,4-苯二硼酸 1g 300元 2011/04/16 P1358 1,4-苯二硼酸(含有数量不等的酸酐) 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride) 5G 1380元 2011/04/16 P1358 1,4-苯二硼酸(含有数量不等的酸酐) 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride) 1G 517元
  • Alfa Aesar:1,4-苯二硼酸,96% 1,4-Benzenediboronic acid, 96%(4612-26-4)
  • Sigma Aldrich:4612-26-4(sigmaaldrich)
  • TCI Shanghai:1,4-苯二硼酸(含有数量不等的酸酐) 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride)(4612-26-4)
  • Hazard Note:Corrosive
  • MOL 文件:4612-26-4.mol
  • 上游原料:乙醚 --> 硫酸 --> 四氢呋喃 --> 镁 --> 硼酸三甲酯 --> 1,4-二溴苯

系列性分类


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