Copper(I) Bromide-Dimethyl Sulfide 溴化亚铜二甲硫醚

CAS 54678-23-8 MFCD00043295

化学结构图

54678-23-8
SMILES: CSC.[Cu]Br

化学属性

Melting Point132°C
Density1.422
TSCANo
Mol. FormulaC2H6BrCuS
Appearance off-white to light-green pwdr.
Mol. Weight205.58
Stabilitymoisture sensitive

别名和识别编码

Chemical NameCopper(I) Bromide-Dimethyl Sulfide
Synonym Bromo[thiobis[methane]]copper {LY} Bromo[thiobis[methane]]copper {} {LY} Bromo[thiobis[methane]]copper {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number4386581
PubChem Substance ID2724234
EC Number259-292-5
MDL NumberMFCD00043295
Chemical Name Translation溴化亚铜二甲硫醚
InChIKeyPMHQVHHXPFUNSP-UHFFFAOYSA-M
LabNetwork Molecule IDLN00222683
InChIInChI=1S/C2H6S.BrH.Cu/c1-3-2;;/h1-2H3;1H;/q;;+1/p-1
CAS Number54678-23-8
Canonical SMILESCSC.[Cu]Br
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Materials Science, Metal and Ceramic Science, Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学

相关文献及参考

  • 1. Org. Synth. 83 , 80, (2006)
  • Rossiter, B. E. et al.B. E.; Swingle, N. M. Chem. Rev. 92 , 771, (1992)
  • Robert, T.; Velder, J.; Schmalz, H.-G. Angew. Chem. Int. Ed. Engl. 47 , 7718, (2008)
  • Pacheco B.; Piguel, S. et al. Org. Lett. 12 , 4038, (2010) 摘要
  • Fieser 6 ,225 / Fieser 8 ,117 / Fieser 10 ,104 / Fieser 15 ,100 / Fieser 16 ,96
  • Aldrich MSDS 1 , 485:C / Corp MSDS 1 (1), 911:B / FT-IR 1 (2), 1248:B / FT-IR 2 (3), 4517:C / RegBook 1 (2), 3079:E / Structure Index 1 , 488:C:4

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes 9
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3335 UN3335
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored un
Packing GroupIII

系列性分类