1-Bromo-2-Methoxyethane 2-溴乙基甲基醚

CAS 6482-24-2 MFCD00000236

化学结构图

6482-24-2
SMILES: COCCBr

化学属性

Mol. FormulaC3H7BrO
Mol. Weight138.99
Boiling Point40-41°C at 66 mmHg
TSCAT
Refractive index1.4450 to 1.4490
Density1.479
Flash Point28°C

别名和识别编码

Chemical Name1-Bromo-2-Methoxyethane
CAS Number6482-24-2
Alfabeta NameBROMOETHYLMETHYLETHER 2-
MDL NumberMFCD00000236
Synonym (2-bromo-ethyl)-methyl ether 1-Bromo-2-methoxyethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87564178
EC Number229-339-4
Beilstein Registry Number773654
Reaxys-RN773654
Chemical Name Translation2-溴乙基甲基醚
InChIKeyYZUPZGFPHUVJKC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00118366
Canonical SMILESCOCCBr
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分类

  • {SNA} Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; ether; 1fragment
  • Building Blocks, C2 to C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Aldrich MSDS 1 , 254:A / Corp MSDS 1 (1), 533:B / FT-IR 1 (1), 210:A / FT-IR 2 (1), 311:D / FT-NMR 1 (1), 327:C / RegBook 1 (1), 215:G / Structure Index 1 , 29:B:9 / Vapor Phase 3 , 274:C
  • Beil. 1 ,I,171
  • Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3

安全信息

Warnings KEEP COLD, LACHRYMATOR, FLAMMABLE
GHS Symbol
WGK Germany3
Hazard Codes 3 Xn
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H301 Toxic if swallowed 吞食有毒
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3271 UN3271
Storage condition 0-10 0-10°C Refrigerator Store at room temperature
Packing GroupIII
Hazard Class3

其他信息

  • Hazard Note:Irritant/Flammable
  • 下游产品:N-(2-甲氧基乙基)甲基胺 --> 1-(2-甲氧基乙基)哌嗪 --> 1-(2-甲氧基乙基)肼 --> N-(2-甲氧基乙基)-乙胺
  • MOL 文件:6482-24-2.mol
  • 存储注意事项:热敏感
  • Alfa Aesar:2-溴乙基甲基醚,96%,stab.withsodiumcarbonate 2-Bromoethyl methyl ether, 96%, stab. with sodium carbonate(6482-24-2)
  • TCI Shanghai:2-溴乙基甲基醚 2-Bromoethyl Methyl Ether,>;95.0%(GC)(6482-24-2)
  • Sigma Aldrich:6482-24-2(sigmaaldrich)
  • 2-溴乙基甲基醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1242 2-溴乙基甲基醚 2-Bromoethyl Methyl Ether 25G 175元 2014/06/02 B1242 2-溴乙基甲基醚 2-Bromoethyl Methyl Ether 250G 850元 2010/06/21 402980050 2-溴乙基甲基醚 2-Bromoethyl methyl ether 95% 5 GR 191元
  • Acros Organics:2-溴乙基甲基醚 2-Bromoethyl methyl ether, 95%(6482-24-2)
  • 图谱信息:2-溴乙基甲基醚(6482-24-2)质谱(MS) 2-溴乙基甲基醚(6482-24-2)核磁图( 1 HNMR) 2-溴乙基甲基醚(6482-24-2)核磁图( 13 CNMR) 2-溴乙基甲基醚(6482-24-2)红外图谱(IR1)

系列性分类


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