Trioctylphosphine oxide 三辛基氧化磷

CAS 78-50-2 MFCD00002083

化学结构图

78-50-2
SMILES: CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC

化学属性

Boiling Point201-202 °C at 2 mmHg
TSCAYes
Solubility不溶
Mol. FormulaC24H51OP
Mol. Weight386.65
Density0.88
Flash Point>230°F
Appearance white to off-white solid off-white xtl.
Stabilityhygroscopic
Melting Point50-52 °C

别名和识别编码

Chemical NameTrioctylphosphine oxide
Synonym Tri-n-octylphosphine oxide {LY} Tri-n-octylphosphine oxide {} {LY} Tri-n-octylphosphine oxide {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-n-octylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number201-121-3
Beilstein Registry Number1796648
PubChem Substance ID87576434
Reaxys-RN1796648
Chemical Name Translation三辛基氧化磷
InChIKeyZMBHCYHQLYEYDV-UHFFFAOYSA-N
LabNetwork Molecule IDLN00198141
MDL NumberMFCD00002083
CAS Number78-50-2
Canonical SMILESCCCCCCCCP(CCCCCCCC)(CCCCCCCC)=O
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分类

  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands
  • {SNA} Ion Sensor Materials, Ionophores Potentiometric for ISE, Plasticizer for ISE, 分析/色谱
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands,
  • {S
  • {SNA} Catalysis, Catalysis and Inorganic Chemistry,
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis,
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Pho
  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Essential Chemicals, Inorganic Salts, Solutions and Reagents,

产品应用

  • 用于萃取金属和氢键结合的有机化合物。

相关文献及参考

  • Short: EINECS
  • Short: IV/18A
  • Beilstein: 4,IV,3466
  • Used in the extraction of various metals into organic solvents.

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R50/53
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P330+P331
  • P302+P350
  • P305+P351+P338+P310
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H313 May be harmful in contact with skin 皮肤接触可能有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSSZ1662500
Hazard Codes Xi
Packing GroupIII
UN Number
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • MOL 文件:78-50-2.mol
  • TCI Shanghai:三辛基氧化膦 Tri-n-octylphosphine Oxide,>;95.0%(GC)(78-50-2)
  • 不溶于水。溶于环己烷。
  • Sigma Aldrich:78-50-2(sigmaaldrich)
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 磷 运动营养食品 营养强化剂 105-1000
  • Acros Organics:三辛基氧化磷 Tri-n-octylphosphine oxide, 99%(78-50-2)
  • Alfa Aesar:三正辛基氧化磷,98% Tri-n-octylphosphine oxide, 98%(78-50-2)
  • 图谱信息:三正辛基氧膦(78-50-2)红外图谱(IR3) 三正辛基氧膦(78-50-2)红外图谱(IR2) 三正辛基氧膦(78-50-2)质谱(MS) 三正辛基氧膦(78-50-2)核磁图( 13 CNMR)
  • 用途一:用于萃取金属和氢键结合的有机化合物。
  • 海关编码:32019090
  • MSDS 信息:TOPO(78-50-2).msds
  • 三正辛基氧膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 LA1106201 三辛基氧化膦;三正辛基氧化膦 25g 350元 2011/08/23 L0387701 三正辛基氧化膦98% 25g 403元 2011/04/16 T0504 三正辛基氧化膦 Tri-n-octylphosphine Oxide 100G 1270元

系列性分类


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