(Trimethylsilyl)ethoxymethyl triphenylphosphonium chloride 2-(三甲基硅烷)乙氧三苯甲基氯化膦

CAS 82495-75-8 MFCD00043159

化学结构图

82495-75-8
SMILES: [Cl-].C[Si](C)(C)CCOC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC24H30ClOPSi
Mol. Weight429.01
Melting Point145-149 °C(lit.)

别名和识别编码

Chemical Name(Trimethylsilyl)ethoxymethyl triphenylphosphonium chloride
Synonym SEM-三苯基氯化磷 2-(三甲基硅烷)乙氧三苯甲基氯化膦
Beilstein Registry Number4632507
PubChem Substance ID87577220
CAS Number82495-75-8
MDL NumberMFCD00043159
Reaxys-RN4632507
Chemical Name Translation2-(三甲基硅烷)乙氧三苯甲基氯化膦
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Becker, M. H.; et al. J. Am. Chem. Soc. 129 , 11987, (2007)
  • 2. Lindenschmidt, A. Sci. Synth. 25 , 237, (2007)
  • 3. Kuba, M.; et al. Chem. Lett. , 1248, (2002)
  • 4. Muller, P.; et al. Tetrahedron Asymmetry 13 , 551, (2002)
  • FT-IR 2 (3), 4431:D / FT-NMR 1 (3), 712:C / RegBook 1 (2), 3003:J / Structure Index 1 , 476:D:3

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


相关产品推荐