Triphenylborane 三苯基硼烷

CAS 960-71-4 MFCD00003007

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H69427
Triphenylborane 三苯基硼烷
96% 1g 260
96-99 %
INFI H69427
Triphenylborane 三苯基硼烷
96% 5g 1,080
LN-CN
中国国内现货 96-99 %
INFI H69427
Triphenylborane 三苯基硼烷
96% 25g 3,780
LN-CN
中国国内现货 96-99 %
INFI H71816
Triphenylborane 三苯基硼烷
0.25 M solution in THF, SpcSeal 25mL 980
LN-CN
中国国内现货 0.2 M solution 四氢呋喃
INFI H71816
Triphenylborane 三苯基硼烷
0.25 M solution in THF, SpcSeal 100mL 2,850
LN-CN
中国国内现货 0.2 M solution 四氢呋喃
Alfa 032589
Triphenylborane
96% 1g 629
SH-CN BJ-CN CN
中国国内现货 99
Alfa 032589
Triphenylborane
96% 5g 1,636
BJ-CN CN
中国国内现货 99
Alfa 032589
Triphenylborane
96% 25g 8,180
SH-CN BJ-CN CN
中国国内现货 99
Aldrich 442445
Triphenylborane solution 三苯基硼烷 溶液
0.25 M in THF 25mL 1,100
SH
中国国内现货 0
Aldrich T82201
Triphenylborane 三苯基硼烷
powder, 2.5g 990
0
Aldrich T82201
Triphenylborane 三苯基硼烷
powder, 10g 1,804
0
Strem 93-0543
Triphenylborane, min. 95%
min. 1g 480
HB
中国国内现货 99
Strem 93-0543
Triphenylborane, min. 95%
min. 5g 1,920
HB
中国国内现货 99
Strem 93-0543
Triphenylborane, min. 95%
min. 25g 7,680
99
Gelest GEL-OMBO078
TRIPHENYLBORANE, 95%
95% 10g 3,658
90+ %
Aldrich T82201-2.5G
2.5g 1,091
Aldrich T82201-10G
10g 1,998

分类

  • {SNA} Boron, CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SNA} Boron, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Boron, Micro/NanoElectronics, Solution Deposition Precursors, T, TP - TZ, 分析/色谱, 材料科学
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Boron, Materials Science, Micro/NanoElectronics, Solution D
  • {SNA} Boron, CVD and ALD Pre

相关文献及参考

  • Beil. 16 ,IV,1623
  • Corp MSDS 1 (2), 3516:A / FT-IR 1 (2), 1134:C / FT-IR 2 (3), 4458:D / IR-Spectra (2), 1327:D / IR-Spectra (3), 1552:F / NMR-Reference 2 (2), 1013:B / RegBook 1 (2), 3027:I / Structure Index 1 , 479:E:1
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes
  • Xn;F
  • F
  • F,Xn
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H228 Flammable solid 易燃固体
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
  • P301+312+330
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P261305+351+338
Signal word
  • Danger
  • Warning
RTECSED2367500
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
UN Number
  • UN1325
  • UN 1993 3/PG 2
  • 1993
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R22 Harmful if swallowed 吞咽有害
Storage condition
  • Air Sensitive
Personal Protective Equipment
  • Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupIII
Hazard Class4.1

其他信息

  • 灭火剂:干粉、二氧化碳
  • Alfa Aesar:三苯基硼 Triphenylborane, 96%(960-71-4)
  • Sigma Aldrich:960-71-4(sigmaaldrich)
  • 毒性分级:高毒
  • 三苯基硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 32589 三苯基硼 Triphenylborane, 96% 5g 1375元 2010/05/25 32589 三苯基硼 Triphenylborane, 96% 25g 5936元 2010/05/25 32589 三苯基硼 Triphenylborane, 96% 1g 322元
  • 敏感性:Air Sensitive
  • 下游产品:二苯基酸
  • 储运特性:库房通风低温干燥; 防潮;与食品、氧化剂分开储运
  • F:10-23
  • MOL 文件:960-71-4.mol
  • 可燃性危险特性:遇热、明火燃烧; 火场放出硼化物辛辣刺激烟雾
  • TSCA:No
  • 刺激数据:眼睛- 兔 110 毫克/ 24小时 重度
  • 急性毒性:口服- 大鼠 LD50: 196 毫克/ 公斤
  • 类别:有毒物品

化学结构图

CAS 960-71-4  MFCD00003007
SMILES:

化学属性

Mol. Formula(C6H5)3B
Mol. Weight242.12
Boiling Point203 °C/15 mmHg(lit.)
Density0.898 g/mL at 25 °C
Melting Point145 °C(lit.)
TSCAYes
Flash Point1 °F
Appearance
  • powder

    别名和识别编码

    Chemical NameTriphenylborane
    CAS Number960-71-4
    PubChem Substance ID 24900512
    MDL NumberMFCD00003007
    Synonym
    • triphenyl-boran
    • 三苯基硼烷
    • triphenylborane solution
    • 三苯基硼烷 溶液
    • TRIPHENYLBORON, POWDER, WATER <2%
    • triphenyl-borane
    • Borane, triphenyl-
    • 三苯基硼
    • Triphenyboron
    • Bortriphenyl
    • Borine, triphenyl-
    • Triphenylborine
    • Triphenylboron, min. 95%
    • TRIPHENYLBORINE
    • 三苯硼[烷]
    • BORON TRIPHENYL
    • Methylquecksilber(II)-chlorid 13% Cl
    • TRIPHENYLBORON
    • borine,triphenyl
    • Triphenylboron
    • Triphenylborane
    • Triphenylbor
    • C18H15B
    • Triphenylboron,min.95%
    • TRIPHENYLBORANE
      EC Number213-504-2
      Beilstein Registry Number1961313
      Chemical Name Translation三苯基硼烷
      InChIKeyMXSVLWZRHLXFKH-UHFFFAOYSA-N
      LabNetwork Molecule IDLN01363619

      系列性分类