Chlorotriethylsilane 三乙基氯硅烷

CAS 994-30-9 MFCD00000507

高端品牌产品

品牌质保精细包装    现货库存    一流品牌服务   
包装筛选
规格筛选
现货筛选
产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H44477
Chlorotriethylsilane 三乙基氯硅烷
99% 5mL 40
LN-CN
中国国内现货 96-99 %
INFI H44477
Chlorotriethylsilane 三乙基氯硅烷
99% 25mL 90
BY-CN LN-CN
中国国内现货 96-99 %
INFI H44477
Chlorotriethylsilane 三乙基氯硅烷
99% 100mL 230
BY-CN LN-CN
中国国内现货 96-99 %
INFI H44477
Chlorotriethylsilane 三乙基氯硅烷
99% 500mL 930
96-99 %
Innochem A69433
Chlorotriethylsilane
98% 99% 5g 115
BJ-CN
中国国内现货 99
Innochem A69433
Chlorotriethylsilane
98% 99% 25g 195
BJ-CN
中国国内现货 99
Innochem A69433
Chlorotriethylsilane
98% 99% 25mL 195
BJ-CN
中国国内现货 99
Innochem A69433
Chlorotriethylsilane
98% 99% 100g 350
BJ-CN
中国国内现货 99
Innochem A69433
Chlorotriethylsilane
98% 99% 500g 1,650
BJ-CN
中国国内现货 99
TCI T0589
Chlorotriethylsilane >
>97.0%(GC) 5g 80
SH-CN BJ-CN TK-JP
中国国内现货 99
TCI T0589
Chlorotriethylsilane >
>97.0%(GC) 25g 190
SH-CN BJ-CN TK-JP
中国国内现货 99
TCI T0589
Chlorotriethylsilane >
>97.0%(GC) 100g 580
SH-CN BJ-CN TK-JP
中国国内现货 99
Alfa A15547
Chlorotriethylsilane, 98+%
10g 170
SH-CN BJ-CN CN
中国国内现货 99
Alfa A15547
Chlorotriethylsilane, 98+%
50g 581
SH-CN CN
中国国内现货 99
Alfa A15547
Chlorotriethylsilane, 98+%
250g 2,642
CN
中国国内现货 99
J&K 212710
Chlorotriethylsilane, 99%
99% 5mL 108
HB
中国国内现货 99
J&K 212710
Chlorotriethylsilane, 99%
99% 25mL 280
HB
中国国内现货 99
J&K 212710
Chlorotriethylsilane, 99%
99% 100mL 716
HB
中国国内现货 99
J&K 459545
Chlorotriethylsilane, 1.0 M solution in THF
N/A 25mL 385
HB
中国国内现货 1.00 M solution in THF
J&K 459545
Chlorotriethylsilane, 1.0 M solution in THF
N/A 100mL 1,267
HB
中国国内现货 1.00 M solution in THF
TRC C421750
Chlorotriethylsilane
25g 1,100
0
TRC C421750
Chlorotriethylsilane
250g 6,600
0
Acros 21594
Chlorotriethylsilane, 99%
25mL 526
99
Acros 21594
Chlorotriethylsilane, 99%
100mL 1,839
99
Acros 21594
Chlorotriethylsilane, 99%
500mL 3,921
SH-CN
中国国内现货 99
Acros 43325
Chlorotriethylsilane, 1M solution in THF, AcroSeal
100mL 771
SH-CN
中国国内现货 0
Fluka 90383
Chlorotriethylsilane
for 10x1mL 1,521
99
Fluka 90383
Chlorotriethylsilane
for 50mL 3,317
99
Shao Yuan SY004482
Chlorotriethylsilane 三乙基氯硅烷
97+% 5mL 116
SH-CN
中国国内现货 99
Shao Yuan SY004482
Chlorotriethylsilane 三乙基氯硅烷
97+% 5g 65
SH-CN
中国国内现货 99
Shao Yuan SY004482
Chlorotriethylsilane 三乙基氯硅烷
97+% 25mL 194
SH-CN
中国国内现货 99
Shao Yuan SY004482
Chlorotriethylsilane 三乙基氯硅烷
97+% 25g 110
SH-CN
中国国内现货 99
Shao Yuan SY004482
Chlorotriethylsilane 三乙基氯硅烷
97+% 100mL 581
SH-CN
中国国内现货 99
Shao Yuan SY004482
Chlorotriethylsilane 三乙基氯硅烷
97+% 100g 303
99
Shao Yuan SY004482
Chlorotriethylsilane 三乙基氯硅烷
97+% 500g 1,284
99
Energy-chemical D020047
Chlorotriethylsilane 三乙基氯硅烷
99% 5mL 55
CN-BJ CN-SH
中国国内现货 99
Energy-chemical D020047
Chlorotriethylsilane 三乙基氯硅烷
99% 25mL 108
CN-BJ CN-SH
中国国内现货 99
Energy-chemical D020047
Chlorotriethylsilane 三乙基氯硅烷
99% 100mL 295
CN-BJ CN-SH
中国国内现货 99
Energy-chemical D020047
Chlorotriethylsilane 三乙基氯硅烷
99% 500mL 1,170
CN-BJ CN-SH
中国国内现货 99
Aladdin C107619
Chlorotriethylsilane 三乙基氯硅烷
98% 5mL 190
CN-SH
中国国内现货 99
Aladdin C107619
Chlorotriethylsilane 三乙基氯硅烷
98% 25mL 111
CN-SH
中国国内现货 99
Aladdin C107619
Chlorotriethylsilane 三乙基氯硅烷
98% 100mL 321
CN-SH
中国国内现货 99
Aladdin C107619
Chlorotriethylsilane 三乙基氯硅烷
98% 500mL 190
CN-SH
中国国内现货 99
Acros 215940250
99% 25mL 532
99
Adamas 92440C
98%+ 100g 678
SH-CN CN
中国国内现货 99
Adamas 92440D
98%+ 500g 1,934
SH-CN
中国国内现货 99
Adamas 92440A
98%+, 5g 102
SH-CN BJ-CN CN
中国国内现货 99
Adamas 92440B
98%+ 25g 206
SH-CN CN
中国国内现货 99
Strem 93-1463
Triethylchlorosilane, 99%
99% 5g 570
99
Strem 93-1463
Triethylchlorosilane, 99%
99% 25g 2,355
99
TRC TRC-C421750
Chlorotriethylsilane
25g 1,320
0
TRC TRC-C421750
Chlorotriethylsilane
250g 7,920
0
Gelest GEL-SIT8250.0
TRIETHYLCHLOROSILANE
10g 377
0
Gelest GEL-SIT8250.0
TRIETHYLCHLOROSILANE
50g 1,506
0
Gelest GEL-SIT8250.0
TRIETHYLCHLOROSILANE
750g 9,205
0
Aldrich 90383
10x1mL 1,521
Aldrich 90383
50mL 3,317
3A A12063
Chlorotriethylsilane 三乙基氯硅烷
98% 5g -
96-99 %
3A A12063
Chlorotriethylsilane 三乙基氯硅烷
98% 25g -
96-99 %
3A A12063
Chlorotriethylsilane 三乙基氯硅烷
98% 100g -
96-99 %
3A A12063
Chlorotriethylsilane 三乙基氯硅烷
98% 500g -
96-99 %
Aladdin C107619-25ml
25mL 111
BJ-CN
中国国内现货
Aladdin C107619-500ml
500mL 1,580
Aladdin C107619-5ml
5mL 56
BJ-CN
中国国内现货
Aladdin C107619-100ml
100mL 321
BJ-CN
中国国内现货
Amethyst 950714
Chlorotriethylsilane, 99%
99% 5mL 58
HB
中国国内现货 96-99 %
Amethyst 950714
Chlorotriethylsilane, 99%
99% 25mL 113
HB
中国国内现货 96-99 %
Amethyst 950714
Chlorotriethylsilane, 99%
99% 100mL 346
HB
中国国内现货 96-99 %
Acros 215940050
5mL 355
Acros 215941000
100mL 1,860
Acros 433251000
100mL 764
BJ-CN
中国国内现货
Acros 215945000
500mL 3,965
Accela SY004482
5g 53
BJ-CN
中国国内现货
Accela SY004482
10g 60
BJ-CN
中国国内现货
Accela SY004482
25g 80
BJ-CN
中国国内现货
Accela SY004482
100g 134
BJ-CN
中国国内现货
Accela SY004482
500g 538
BJ-CN
中国国内现货
Aldrich 372943-100ML
100mL 1,485
Aldrich 235067-5G
5g 428
Aldrich 235067-25G
25g 1,727
药明康德 WXCD00900538
100g 472

分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents GC, Protecting and Derivatizing Reagents, Protection and Derivatization, Reagents for Silylation, Silicon-Based, Silylation Reagents, Sy
  • {SNA} Chemical Synthesis, Derivatization Reagents, Derivatization Reagents GC, Protecting and Derivatizing Reagents, Protection and Derivatization, Reagents for Silylation, Silicon-Based, Silylation Reagents, Synthetic Reagents, 分析/色谱, 分析试剂
  • {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents,
  • {uni_hamburg} no charge; 1fragment
  • Miscellaneous Reagents
  • {SNA} Chemical Synthesi

产品应用

  • 和Grignard试剂一起用于钯催化的丙二烯的碳硅烷化。Grignard攻击丙二烯中间碳,从而是末端碳硅烷化。

相关文献及参考

  • Alvisi, C. et al.: J. Org. Chem., 63, 1330 (1998): Higashiya, S. et al.: J. Org. Chem., 69, 6326 (2004); Hicks, J.D. et al.: Org. Lett., 9, 5621 (2007);
  • Merck: 14,10397
  • Short: III/20b
  • Short: III/35F
  • Silylation of alcohols in the presence of e.g. pyridine: J. Chem. Soc., Chem. Commun., 156 (1979); imidazole-DMF: Helv. Chim. Acta, 64, 2002 (1981); or catalyzed by DMAP: J. Org. Chem., 52, 598 (1987) have been reported. The TES group is readily cleaved with TBAF or other F- reagents. Catalytic amounts of FeCl3 in MeOH has also been recommended: Synlett, 1260 (2006). Selective cleavage in the presence of TBDMS has been achieved with aqueous AcOH in THF: Liebigs Ann. Chem., 1281 (1986), or 2% HF in acetonirile: Tetrahedron Lett., 26, 5239 (1985).
  • Silylation reagent (see Appendix 4). Generally, triethylsilyl (TES) ethers are 10-100x more stable to hydrolysis than their TMS (see Chlorotrimethyl­silane, A13651) counterparts but much less so than TBDMS (see tert-Butyl­dimethyl­chlorosilane, A13064): J. Org. Chem., 48, 1970 (1983).

安全信息

Signal word
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S25 Avoid contact with eyes 避免眼睛接触;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37 Irritating to respiratory system 刺激呼吸道
  • R35 Causes severe burns 会导致严重灼伤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261305+351+338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+242+243
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280301+310305+351+338310
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 如果食入:立即呼叫中毒控制中心或医生/医师。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number
  • UN 2986 8/PG 2
Storage condition
  • Moisture Sensitive
  • Flammables area
Hazard Codes
  • F,C
Hazard Class8/3

其他信息

  • TCI Shanghai:三乙基氯硅烷 Chlorotriethylsilane,>;97.0%(GC)(994-30-9)
  • 海关编码:29310095
  • 三乙基氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010200 三乙基氯硅烷 100ml 550元 2011/04/16 T0589 三乙基氯硅烷 Chlorotriethylsilane 25G 1200元 2011/04/16 T0589 三乙基氯硅烷 Chlorotriethylsilane 5G 369元
  • F:10-21
  • 图谱信息:三乙基氯硅烷(994-30-9)质谱(MS) 三乙基氯硅烷(994-30-9)核磁图( 1 HNMR) 三乙基氯硅烷(994-30-9)红外图谱(IR1)
  • 用途一:用来合成有机硅的原料、中间体及用作乙基硅油、乙基硅橡胶的封端剂
  • 用途二:和Grignard试剂一起用于钯催化的丙二烯的碳硅烷化。Grignard攻击丙二烯中间碳,从而是末端碳硅烷化。
  • Acros Organics:三乙基氯硅烷 Chlorotriethylsilane, 99%(994-30-9)
  • TSCA:Yes
  • MOL 文件:994-30-9.mol
  • Sigma Aldrich:994-30-9(sigmaaldrich)
  • Alfa Aesar:三乙基氯硅烷,98+% Chlorotriethylsilane, 98+%(994-30-9)
  • MSDS 信息:Chlorotriethylsilane(994-30-9).msds
  • 敏感性:Moisture Sensitive
  • 水中分解.

化学结构图

CAS 994-30-9  MFCD00000507
SMILES: CC[Si](Cl)(CC)CC

化学属性

Mol. FormulaC6H15ClSi
Mol. Weight150.72
Density0.886
Refractive index1.4300 to 1.4320
Boiling Point142-144
Flash Point30°C(lit.)
TSCAYes
Melting Pointca -75°
Stability对湿度敏感
Appearance
  • 有刺激性的无色易燃液体。

    别名和识别编码

    Chemical NameChlorotriethylsilane
    CAS Number994-30-9
    Synonym
    • Triethylchlorosilane,99%
    • 氯三乙基甲硅烷
    • chlorotriethylsilane
    • Triethylsilylchlorid
    • TRIETHYLCHLOROSILANE SOLUTION, ~1 M IN THF
    • Triethylchlorosilane; TESCl; Triethylsilyl chloride
    • chlorotriethyl-silan
    • chloro-triethyl-silane
    • Triethylsilyl Chloride
    • 三乙基氯硅烷 溶液
    • Triethylchlorsilan
    • CT2520
    • TRIETHYL CHLOROSILANE ( TES-CHLORIDE )
    • silane, chlorotriethyl-
    • triethyl-chloro-silane
      MDL NumberMFCD00000507
      EC Number213-615-6
      Beilstein Registry Number1732860
      PubChem Substance ID 87576486
      Reaxys-RN1732860
      Chemical Name Translation三乙基氯硅烷
      LabNetwork Molecule IDLN00007961

      系列性分类


      相关产品推荐

      18162-48-6, MFCD00000501, 	tert-Butyldimethylchlorosilane
	叔丁基二甲基氯硅烷
      18162-48-6 / MFCD00000501
      tert-Butyldimethylchlorosilane
      叔丁基二甲基氯硅烷
      • SH-CN
      • TJ-CN
      • BJ-CN
      • LN-CN
      • CN-BJ
      • SH
      • L2
      • HB
      • CN-SH
      • CN
      N/A, MFCD00006418, 	4-(Dimethylamino)pyridine solution
	4-(二甲氨基)吡啶
      N/A / MFCD00006418
      4-(Dimethylamino)pyridine solution
      4-(二甲氨基)吡啶
      • SH-CN
      • TJ-CN
      • TK-JP
      • CN
      • SH
      • CN-BJ
      • BJ-CN
      • HB
      • CN-SH
      13154-24-0, MFCD00009656, 	Triisopropylchlorosilane
	三异丙基氯硅烷
      13154-24-0 / MFCD00009656
      Triisopropylchlorosilane
      三异丙基氯硅烷
      • SH-CN
      • TJ-CN
      • TK-JP
      • LN-CN
      • SH
      • CN-BJ
      • BY-CN
      • BJ-CN
      • L2
      • HB
      • CN-SH
      • CN