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• 试剂商城
• 直接询价

分类

• {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Micro/NanoElectronics, Non-Precious Metal Catalysis, Solution Deposition Precursors, 材料科学
• {SNA}
• {SNA} Catalysis and Inorganic Chemistry,
• {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis,
• {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
• {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron
• Catalysis and Inorganic Chemistry,
• {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Materials Science, Micro/NanoElectronics, Non-Precious Metal Catalysis, Solution Deposition Precursors

产品应用

• 用作树脂交联剂合固化促进基；橡胶添加剂；石油裂解催化剂；燃料油添加剂，可改善润滑性和燃烧性；有机合成催化剂。

相关文献及参考

• In combination with Na metal at room temperature in benzene, cyano groups are cleaved from alkyl nitriles to give the corresponding hydrocarbons: J. Am. Chem. Soc., 93, 7113 (1971).
• Short: III/5b
• Catalyzes the nitration of non-activated arenes, e.g. halogenobenzenes, and moderately activated arenes, e.g. alkylbenzenes and naphthalenes under non-acidic, non-aqueous conditions with NO2 in the presence of O2; no nitration occurs in the absence of the Fe(III) catalyst: J. Chem. Soc., Perkin 1, 2385 (1996).
• Catalyst for the coupling of Grignard reagents with aryl halides: J. Am. Chem. Soc., 124, 13856 (2002); Org. Lett., 6, 1227 (2004), with vinyl sulfones to give alkenes: Tetrahedron Lett., 23, 2469 (1982); Tetrahedron, 44, 111 (1988), and with acyl halides to give ketones in good yield: Tetrahedron Lett., 25, 4805 (1984). Alkenyl halides couple with aryl Grignards to give 1-aryl alkenes: Synlett, 1901 (2001). For leading references and improved reaction conditions for the coupling of alkyl and aryl Grignards with a varirtety of enol triflates and acid chlorides, and also for selective monoalkylation of dichlroarenes and heteroarenes, see: J. Org. Chem., 69, 3743 (2004).
• Beilstein: 1,IV,3675

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 76 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CHTHBK Chemotherapy (Basel).  (S. Karger Pub., Inc., 79 Fifth Ave., New
   York, NY 10003) V.13-    1968-  Volume(issue)/page/year: 16,371,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02372

其他信息

• 微溶于水和庚烷，易溶于乙醇、苯、氯仿、丙酮,少量溶于醚，溶解度:2 g/l 水(20°C),40.1 g/kg 乙醇(20°C)、53.54 G/100G 苯 (20 C)。