Nickel(II) acetylacetonate 二乙酰丙酮镍

CAS 3264-82-2 MFCD00000024

化学结构图

3264-82-2
SMILES: CC(=O)/C=C(/C)O[Ni]O/C(C)=C\C(C)=O

化学属性

Density1.422
SolubilitySoluble in water, alcohol, toluene
TSCAYes
Boiling Point220°C at 11 mmHg
Flash Point>200°C
Refractive index1.57-1.64
Mol. FormulaC10H14NiO4
Mol. Weight256.91
Appearance light green pwdr.
Stabilityhygroscopic
Melting Point230°C

别名和识别编码

Chemical NameNickel(II) acetylacetonate
EC Number221-875-7
Beilstein Registry Number4157970
Reaxys-RN4157970
PubChem Substance ID9834912
Merck Number6500
Synonym Nickelous acetylacetonate {LY} Nickelous acetylacetonate {} {LY} Nickelous acetylacetonate {} {} {LY} Nickelous acetylacetonate {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {}
Chemical Name Translation二乙酰丙酮镍
Wiswesser Line Notation1V1V1 &-NI-
LabNetwork Molecule IDLN02135171
InChIInChI=1S/2C5H8O2.Ni/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
MDL NumberMFCD00000024
CAS Number3264-82-2
Canonical SMILESCC1=O[Ni+2]2(O=C(C)[CH-]1)O=C(C)[CH-]C(C)=O2
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Nickel, Solution Deposition Precursors
  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; fused rings; 6RingOnly; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Nickel, Solution Deposition Precursors, 材料科学

产品应用

  • 有机反应的催化剂。

相关文献及参考

  • Short: II/25D
  • Catalyst for a variety of coupling reactions, e.g.: Coupling of Grignard reagents to give biaryls: J. Org. Chem., 41, 2252 (1976). Coupling of Grignards with silyl enol ethers of both aldehydes and ketones, to give alkenes. In contrast to Dichlorobis(triphenyl­phosphine)­nickel(II)­, 13930, this reagent gives the thermodynamically more stable alkene: Tetrahedron Lett., 3915 (1980). Cross-coupling of alkyl iodides with dialkylzinc reagents tolerates a variety of functionalities: Angew. Chem. Int. Ed., 34, 2723 (1995).
  • Merck: 14,6500 Beilstein: 1,IV,3677
  • Aryl phosphates couple with Grignards (aryl tosylates do not couple under these conditions), affording high yields of biaryls: Tetrahedron Lett., 22, 4449 (1981). Cross-coupling of aryl chlorides with arylzincs also yields biaryls: Tetrahedron Lett., 39, 6441, 7275 (1998).
  • Merck: 14,6500
  • For a brief feature on uses of the reagent in synthesis, see: Synlett, 1042 (2005).
  • For use in the condensation of active methylene compounds with lactims, see Isopropyl­idene malonate, A15603.
  • Catalyst for the conjugate addition of 1,3-dicarbonyl compounds to various Michael acceptors: J. Org. Chem., 45, 1246 (1980).

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P304+P340
  • P304+P340+P342+P311
  • P304+P341
  • P308+P313
  • P318
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P333+P317
  • P342+P311
  • P342+P316
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSSA2100000
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H350 May cause cancer 可能致癌
  • H351 Suspected of causing cancer 怀疑致癌
Hazard Codes T T,Xi,Xn Xn
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,231,1952

其他信息

  • 用途:用作催化剂
  • 图谱信息:二乙酰丙酮镍(3264-82-2)红外图谱(IR3) 二乙酰丙酮镍(3264-82-2)红外图谱(IR1)
  • EPA化学物质信息:Nickel, bis(2,4-pentanedionato-.kappa. O,.kappa.O')-, (SP-4-1)-(3264-82-2)
  • 敏感性:Hygroscopic
  • MOL 文件:3264-82-2.mol
  • NIST化学物质信息:Nickel acetylacetonate(3264-82-2)
  • 二乙酰丙酮镍价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0096 双(2,4-戊二酮酸)镍(II)水合物 Bis(2,4-pentanedionato)nickel(II) Hydrate 25G 383元 2014/06/02 N0096 双(2,4-戊二酮酸)镍(II)水合物 Bis(2,4-pentanedionato)nickel(II) Hydrate 500G 3270元 2010/06/21 128260050 二乙酰丙酮镍 Nickel acetylacetonate 96% 5 GR 317元
  • 海关编码:29420000
  • RTECS号:SA2100000
  • 溶于水，溶于乙醇、氯仿和苯，不溶于乙醚和轻石油
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Nickel - 镍催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Nickel - 镍催化剂
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Nickel - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. NHC Compounds
  1. CVD & ALD Precursors
  2. Nickel
  1. Metal Beta-diketonates
  2. Nickel
  1. Catalysts
  2. Nickel
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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