Phenylselenyl bromide 苯基溴化硒
CAS 34837-55-3 MFCD00000047
化学结构图
SMILES: Br[Se]c1ccccc1
化学属性
| Mol. Formula | C6H5SeBr |
|---|---|
| Mol. Weight | 236 |
| Density | 1.422 |
| Melting Point | 56.0 to 60.0 deg-C |
| TSCA | No |
| Flash Point | 107-108°C/15mm |
| Boiling Point | 107°C/15mmHg(lit.) |
别名和识别编码
| Chemical Name | Phenylselenyl bromide |
|---|---|
| CAS Number | 34837-55-3 |
| EC Number | 252-238-1 |
| Beilstein Registry Number | 6(3)1111 |
| MDL Number | MFCD00000047 |
| Reaxys-RN | 2039772 |
| PubChem Substance ID | 87575410 |
| Synonym | Benzeneselenenyl bromide benzeneselenyl bromide Phenylselenylbromid bromoselenobenzene phenylselenenyl bromide phenylselenium bromide 苯基溴化硒 Benzolselenylbromid phenyl selenyl bromide Benzeneselenyl bromide 苯硒基溴化物 phenyl selenide bromide |
| Chemical Name Translation | 苯基溴化硒 |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Selenium Compounds
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- Building Blocks, Chemical Synthesis, Organic Building Blocks, Selenium Compounds
相关文献及参考
- Short: II/25D
- Reagent for the introduction of the phenylseleno group. Compare following entry (phenylselenenyl chloride) and Diphenyl diselenide, A13919.
- Addition to alkenes gives the kinetic product at low temperature in THF but the thermodynamic product at room temperature in acetonitrile: J. Org. Chem., 42, 2950 (1977):
- Short: III/35G
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R33 Danger of cumulative effects 有累积作用的危险
- R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
- R50/53
- P303+P361+P353+P310+P363
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P304+P340+P310
- P273 Avoid release to the environment. 避免释放到环境中。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P405 Store locked up. 上锁保管。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P303+P361+P353
- P403+P233
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P301+P310
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P305+P351+P338+P310
- P301+P330+P331+P310
- H300+H330
- H290 May be corrosive to metals 可能腐蚀金属。
- H301+H331
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
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