3-Fluorobenzyl Bromide 3-氟苄溴

CAS 456-41-7 MFCD00000340

化学结构图

456-41-7
SMILES: Fc1cccc(CBr)c1

化学属性

Mol. FormulaC7H6BrF
Mol. Weight189
Boiling Point200°C(lit.)
TSCAT
Density1.541
Refractive indexn20/D 1.546(lit.)
Flash Point61°C(lit.)
Stability对光敏感
Appearance 无色液体。

别名和识别编码

Chemical Name3-Fluorobenzyl Bromide
CAS Number456-41-7
Alfabeta NameFLUOROBENZYLBROMIDE 3-
MDL NumberMFCD00000340
Synonym 3-Fluorobenzylbromide,98% ALPHA-BROMO-3-FLUOROTOLUENE à-bromo-3-fluorotoluene alpha-Bromo-3-fluorotoluene 间氟溴苄，α-溴-3-氟甲苯 3-氟苄溴 C7 H6 BR F Benzene, 1-(bromomethyl)-3-fluoro- meta-Fluorobenzyl bromide ALPHA-BROMO-M-FLUOROTOLUENE 3-Fluorobenzyl bromide 98% α-Bromo-3-fluorotoluene -Bromo-3-fluorotoluene 3-FLUOROBENZYL BROMIDE 97% (GC) 3-FLUOROBENZYL BROMIDE M-FLUOROBENZYL BROMIDE 3-氟溴苄 3-氟苯甲溴 3-氟苯甲溴,98% 3-氟苄溴 3-溴氟苯 α-溴-3-氟甲苯 3-fluoro(bromomethyl)benzene 1-(bromomethyl)-3-fluoro-benzen
EC Number207-263-2
Beilstein Registry Number5(2)238
PubChem Substance ID87569988
Reaxys-RN636503
Chemical Name Translation3-氟苄溴
InChIKeySCBZBMXPJYMXRC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008662
InChIInChI=1S/C7H6BrF/c8-5-6-2-1-3-7(9)4-6/h1-4H,5H2
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C7, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

  • Beilstein:5(2)238

安全信息

Warnings LACHRYMATOR, CORROSIVE
UN Number UN3265 UN 3265 8/PG 2 3265
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Signal word
GHS Symbol
WGK Germany3
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P403+P235
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
Hazard Codes C
Storage condition 避光保存,有极强的催泪性 0-6°C
Hazard Class8

其他信息

  • Acros Organics:3-氟苄溴 3-Fluorobenzyl bromide, 95%(456-41-7)
  • Alfa Aesar:3-氟苯甲溴,98% 3-Fluorobenzyl bromide, 98%(456-41-7)
  • TCI Shanghai:3-氟苄溴 3-Fluorobenzyl Bromide,>;95.0%(GC)(456-41-7)
  • TSCA:T
  • Hazard Note:Corrosive/Lachrymatory
  • 存储注意事项:湿度敏感
  • 图谱信息:3-氟溴苄(456-41-7)质谱(MS) 3-氟溴苄(456-41-7)红外图谱(IR1)
  • Sigma Aldrich:456-41-7(sigmaaldrich)
  • 海关编码:29036990
  • MOL 文件:456-41-7.mol
  • MSDS 信息:3-Fluorobenzyl bromide(456-41-7).msds
  • 检测方法:GC,NMR
  • 3-氟溴苄价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0208 3-氟苄溴 3-Fluorobenzyl Bromide 25G 793元 2014/06/02 F0208 3-氟苄溴 3-Fluorobenzyl Bromide 250G 4110元 2014/06/02 F0208 3-氟苄溴 3-Fluorobenzyl Bromide 5G 302元
  • 敏感性:Lachrymatory

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C7 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C6

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