Phenylmagnesium Chloride 苯基氯化镁
CAS 100-59-4 MFCD00000464
化学结构图
SMILES: [Cl-].[Mg+2].[c-]1ccccc1
化学属性
| TSCA | Yes |
|---|---|
| Flash Point | 1°F (THF) |
| Appearance | liq. |
| Stability | air sensitive, moisture sensitive |
| Density | 1.05 |
| Mol. Formula | C6H5MgCl |
| Mol. Weight | 136.86 |
| Redox | Reduction |
别名和识别编码
| Chemical Name | Phenylmagnesium Chloride |
|---|---|
| EC Number | 250-023-7 |
| Beilstein Registry Number | 3587900 |
| PubChem Substance ID | 7513 |
| Synonym | Chlorphenylmagnesium Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN chlorophenylmagnesium PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER Phenylmagnesiumchloride,2-3MinTHF PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran 氯化苯基鎂 PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN 氯化苯鎂 PHENYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) 氯化苯基镁 chlorophenyl-magnesiu PHENYLMAGNESIUM CHLORIDE SOLUTION & Magnesium, chlorophenyl- PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN Phenylmagnesium chloride25 wt% solution in tetrahydrofuranAcroSeal§3 苯基氯化镁 Phenylchloromagnesium 苯基氯化镁 溶液 PHENYLMAGNESIUM CHLORIDE |
| Merck Number | 7298 |
| Chemical Name Translation | 苯基氯化镁 |
| Reaxys-RN | 4576984 |
| InChI | InChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1 |
| MDL Number | MFCD00000464 |
| CAS Number | 100-59-4 |
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分类
- {SNA} 12 Principles Aligned Products, 25mL Sure/Seal Reagents, Aryl, Chemical Synthesis, Greener Alternative Products, Grignard Reagents, Organometallic Reagents, Synthetic Reagents
- {SNA} 25mL Sure/Seal Reagents, Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
- {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
相关文献及参考
- Merck:7298
- Merck:7298 Beilstein:16,929
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S30 Never add water to this product 切勿将水加入该产品中；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R37 Irritating to respiratory system 刺激呼吸道
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
其他信息
- 苯基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1381 苯基氯化镁(27%的四氢呋喃溶液,约2mol/L) Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) 250G 643元 2010/06/21 252581000 苯基氯化镁 Phenylmagnesium chloride , 25 wt% solution in tetrahydrofuran, AcroSeal® 100 ML 457元 2010/06/21 252588000 苯基氯化镁 Phenylmagnesium chloride , 25 wt% solution in tetrahydrofuran, AcroSeal® 800 ML 1522元
- Acros Organics:苯基氯化镁 Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran, AcroSeal?(100-59-4)
- Sigma Aldrich:100-59-4(sigmaaldrich)
- MOL 文件:100-59-4.mol
- TCI Shanghai:苯基氯化镁(27%的四氢呋喃溶液,约2mol/L) Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)(100-59-4)
- F:10
- 下游产品:4-苯基吡啶
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