Chloropentafluorobenzene 1-chloro-2,3,4,5,6-pentafluorobenzene

CAS 344-07-0 MFCD00000534

化学结构图

344-07-0
SMILES: Fc1c(F)c(F)c(Cl)c(F)c1F

化学属性

TSCAT
Refractive index1.4220 to 1.4260
Flash Point116-118°C
Mol. FormulaC6ClF5
Mol. Weight202.509216
Density1.568
Appearance colorless liq.
Boiling Point122-123 °C at 750 mmHg
Melting Point-15.66 °C

别名和识别编码

Chemical Name1-chloro-2,3,4,5,6-pentafluorobenzene
Alfabeta NameCHLOROPENTAFLUOROBENZENE
Beilstein Registry Number1819389
PubChem Substance ID9579
EC Number206-450-6
Reaxys-RN1819389
Synonym Chloropentafluorobenzene {LY} Chloropentafluorobenzene {} {LY} Chloropentafluorobenzene {} {} {LY} Chloropentafluorobenzene {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloropentafluorobenzene {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation1-chloro-2,3,4,5,6-pentafluorobenzene
InChIKeyKGCDGLXSBHJAHZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00119088
InChIInChI=1S/C6ClF5/c7-1-2(8)4(10)6(12)5(11)3(1)9
MDL NumberMFCD00000534
CAS Number344-07-0
Canonical SMILESFC1=C(Cl)C(F)=C(F)C(F)=C1F
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

  • Short: III/20a
  • For preparation of pentafluorophenyl Grignard by reaction with magnesium in THF at -10o, see: J. Organomet. Chem., 17, 145 (1969).
  • Short: III/20c

安全信息

Warnings IRRITANT
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P317
  • P337+P317
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany2
Signal word Danger Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSCZ1225500
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R20 Harmful by inhalation 吸入有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C Refrigerator {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Hazard Codes Xn;Xi Xi Xn,Xi
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >4840 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,220,1992

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,220,1992

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 10 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A165-849

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - mouse Cells - not otherwise specified
DOSE/DURATION           : 100 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A187-233

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 30 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A165-849

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 62500 ug/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A187-233

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 10500 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 12,105,1992

其他信息

  • Acros Organics:氯五氟苯 Chloropentafluorobenzene, 99%(344-07-0)
  • 外观性质:固体。
  • 用途一:医药、农药、液晶材料中间体。
  • 图谱信息:氯五氟苯(344-07-0)红外图谱(IR1) 氯五氟苯(344-07-0)Raman光谱 氯五氟苯(344-07-0)质谱(MS)
  • MOL 文件:344-07-0.mol
  • TSCA:T
  • TCI Shanghai:氯五氟苯 Chloropentafluorobenzene,>;95.0%(GC)(344-07-0)
  • Alfa Aesar:五氟氯苯,98+% Chloropentafluorobenzene, 98+%(344-07-0)
  • Sigma Aldrich:344-07-0(sigmaaldrich)
  • Hazard Note:Irritant
  • 氯五氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0850 氯五氟苯 Chloropentafluorobenzene 25G 493元 2010/06/21 186070250 氯五氟苯 Chloropentafluorobenzene 99% 25 GR 614元 2010/06/21 186070050 氯五氟苯 Chloropentafluorobenzene 99% 5 GR 300元
  • MSDS 信息:一氯五氟化苯(344-07-0).msds
  • 氯五氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 P0850 氯五氟苯 Chloropentafluorobenzene 25G 623元 2010/06/21 186070250 氯五氟苯 Chloropentafluorobenzene 99% 25 GR 614元 2010/06/21 186070050 氯五氟苯 Chloropentafluorobenzene 99% 5 GR 300元

系列性分类


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