1-Chloro-2-Methyl-1-Oxopropan-2-Yl Acetate 2-乙酰氧基异丁酰氯
CAS 40635-66-3 MFCD00000708
化学结构图
SMILES: CC(=O)OC(C)(C)C(=O)Cl
化学属性
| Mol. Formula | C6H9ClO3 |
|---|---|
| Mol. Weight | 165 |
| Refractive index | 1.4280 to 1.4310 |
| Boiling Point | 70°C/17mmHg(lit.) |
| Density | 1.136 g/mL at 25 °C(lit.) |
| Flash Point | 68°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | 1-Chloro-2-Methyl-1-Oxopropan-2-Yl Acetate |
|---|---|
| Synonym | 2-乙酰氧基异丁酰氯 2-乙酸基-2-甲基丙酰氯 2-Acetoxy-2-methylpropionyl chloride 2-乙酰氧基异丁酰氯 2-乙酸基-2-甲基丙酰氯 |
| PubChem Substance ID | 87562604 |
| EC Number | 255-016-2 |
| Beilstein Registry Number | 507772 |
| MDL Number | MFCD00000708 |
| CAS Number | 40635-66-3 |
| Chemical Name Translation | 2-乙酰氧基异丁酰氯 |
| Reaxys-RN | 507772 |
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分类
- {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
相关文献及参考
- Reaction of the chloroalkyl acetate (from a cis-glycol) with azide ion provides a route to the cis-amino alcohol: Tetrahedron Lett., 37, 2529 (1996). Compare O-Acetylsalicyloyl chloride, L00919.
- Reagent for conversion of cis-1,2-diols, including nucleosides, via cyclic dioxolanone intermediates, into trans-chloroalkyl acetates. The reaction is selective for the 2'-OH of uridine derivatives and converts pyrimidine nucleosides to their anhydro forms: J. Am. Chem. Soc., 95, 4016 (1973). Application to synthesis of deoxy-sugars, by dechlorination with Bu3SnH: J. Chem. Soc., Chem. Commun., 677 (1978).
安全信息
GHS Symbol
- H227 Combustible liquid 可燃液体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P305+P351+P338
- P304+P340+P310
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P308+P313
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- R37 Irritating to respiratory system 刺激呼吸道
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
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