Phenylacetyl Chloride 苯乙酰氯

CAS 103-80-0 MFCD00000729

化学结构图

103-80-0
SMILES: O=C(Cl)Cc1ccccc1

化学属性

Mol. FormulaC8H7ClO
Mol. Weight154.59
Density1.169
Refractive index1.5320 to 1.5340
Boiling Point94-95
Flash Point102.78°C
TSCAYes
Solubility易溶于乙醚。
Stability对湿度敏感
Melting Point35-38 °C(lit.)

别名和识别编码

Chemical NamePhenylacetyl Chloride
MDL NumberMFCD00000729
CAS Number103-80-0
EC Number203-146-5
Beilstein Registry Number742254
Synonym Phenylacetyl chloride {LY} Phenylacetyl chloride {} {LY} Phenylacetyl chloride {} {} {LY} Phenylacetyl chloride {} {} {} { {} {} {} {LY} Phenylacetyl chloride {} {} {} {} {LY} Phenylacetyl chloride {} {} {} {} {} {LY} Phenylacetyl chloride {} {} {} {} {} {} {LY} Phenylacetyl chloride {} {} {} {} {} {} {} {LY} Phenylacetyl chloride {} {} {} {} {} {} {} {} {Chemicalbook} PHENYLACETYL CHLORIDE {} {} {} {} {} {} {} {} {} {Chemicalbook} PHENYLACETIC ACID CHLORIDE {} {} {} {} {} {} {} {} {} {} {Chemicalbook} PHENYL ACETY1[E] CHLORIDE {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} PHENACETYL CHLORIDE {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} N-苯苄胺 {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} N-苯基苯甲胺 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} N-苯基苄胺 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} N-苄胺苯 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID7679
Chemical Name Translation苯乙酰氯
Reaxys-RN742254
Merck Number1126
LabNetwork Molecule IDLN00192959
InChIInChI=1S/C8H7ClO/c9-8(10)6-7-4-2-1-3-5-7/h1-5H,6H2
Canonical SMILESO=C(Cl)CC1=CC=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbonyl chloride; 1fragment
  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 酰胺类杀菌剂
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

产品应用

  • 有机合成。酰化剂。

相关文献及参考

  • Beilstein:9,436
  • Short: II/27B
  • Short: III/20b

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 2577
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes 8 C C,Xi
Hazard Class8
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 上游原料:苄基氯
  • 方法二:由苯乙酸与氯化亚砜反应制得。将等摩尔的苯乙酸辣氯化亚砜混合，于室温下反应放出二氧化硫和氯化氢气体。不再有大量气体放出时，将反应混合物热至30-40℃，保温25h，加入混合物体积四分之一的苯。采用低温
  • {Chemical
  • MSDS 信息:Benzylaniline(103-32-2).msds
  • 外观性质:无色到浅黄色发烟液体。
  • 用途四:该品为香料及其他有机合成的中间体。
  • F:
  • TCI Shanghai:N-苄基苯胺 N-Phenylbenzylamine,>;98.0%(GC)(103-32-2)
  • 下游产品:洛开酰胺 --> 溴鼠灵 --> 6-苄基-2-硫脲嘧啶 --> 苯霜灵 --> 苯乙酰丙二酸二乙酯 --> 二苯基乙酮 --> (E)-苯乙酸-3,7-二甲-2,6-辛二烯
  • Acros Organics:N-苯基苄胺 N-Phenylbenzylamine, 99%(103-32-2)
  • Sigma Aldrich:103-80-0(sigmaaldrich)
  • 用途三:苯乙酰氯是杀菌剂苯霜灵和杀鼠剂溴鼠灵的中间体。
  • {C
  • 对湿敏感。遇水、乙醇分解。易溶于乙醚，与氨、酸类发生反应。具有强烈的刺激性气味
  • N-苄基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0159 N-苄基苯胺 N-Phenylbenzylamine 25G 398元 2014/06/02 P0159 N-苄基苯胺 N-Phenylbenzylamine 500G 2090元 2010/06/21
  • Alfa Aesar:苯乙酰氯,98% Phenylacetyl chloride, 98%(103-80-0)
  • 方法一:由氯苄与苯胺缩合而得。将碳酸氢钠、水、苯胺混合搅拌，加热至90-95℃，慢慢加入氯苄。在90-95℃反应3h。冷却，过滤。滤液分层，取有机层用饱和食盐水洗涤，无水硫酸钠干燥。然后减压蒸馏，收集81℃（1.6kPa）馏分为回收苯胺，170-190℃（1.6kPa）馏分冷却、固化得苄基苯胺。精制时可用石油醚重结晶。收率80%以上。
  • 海关编码:29163900
  • MSDS 信息:苯乙酰氯(103-80-0).msds
  • TCI Shanghai:苯乙酰氯 Phenylacetyl Chloride,>;98.0%(GC)(T)(103-80-0)
  • 海关编码:29214980
  • 苯乙酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80099428 苯乙酰氯;氯化苯乙酰 500ml 105元 2011/04/16 P0129 苯乙酰氯 Phenylacetyl Chloride 25G 187元 2011/04/16 P0129 苯乙酰氯 Phenylacetyl Chloride 500G 990元
  • 上游原料:氧氯化硫 --> 氯 --> 二氧化硫 --> 苯乙酸
  • 方法一:其制备方法是在反应釜中加入苯乙酸和氯化亚砜，加热回流数小时，加热减压除去剩余的氯化亚砜得粗品，减压蒸馏得成品。
  • 图谱信息:N-苄基苯胺(103-32-2)红外图谱(IR2) N-苄基苯胺(103-32-2)Raman光谱 N-苄基苯胺(103-32-2)核磁图( 1 HNMR) N-苄基苯胺(103-32-2)质谱(MS) N-苄基苯胺(103-32-2)核磁图( 13 CNMR) N-苄基苯胺(103-32-2)红外图谱(IR1)
  • 图谱信息:苯乙酰氯(103-80-0)核磁图( 1 HNMR) 苯乙酰氯(103-80-0)核磁图( 13 CNMR) 苯乙酰氯(103-80-0)Raman光谱 苯乙酰氯(103-80-0)质谱(MS) 苯乙酰氯(103-80-0)红外图谱(IR1)
  • MOL 文件:103-80-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. C14 to C16 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonates/Sulfinates - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  1. Acyl halide
  2. acyl chloride