1,2-Dichloropropane 1,2-二氯丙烷
CAS 78-87-5 MFCD00000868
化学结构图
SMILES: CC(Cl)CCl
化学属性
| Mol. Formula | C3H6Cl2 |
|---|---|
| Mol. Weight | 113 |
| Autoignition Point | 1035 °F |
| Refractive index | 1.4380 to 1.4400 |
| Vapor Density | 3.89 (vs air) |
| Boiling Point | 97°C |
| Vapor Pressure | 40 mmHg ( 19.4 °C) |
| Density | 1.156 |
| Melting Point | -100°C |
| Flash Point | 14°C(lit.) |
| TSCA | Yes |
| Solubility | 3 G/L (20 ºC) |
| Appearance | 无色透明液体，可燃。能与水、醇、醚、酯、苯、三氯甲烷和芳香化合物等有机溶剂任意混合。冰点-20℃，沸点166℃，96℃（10.7kPa），85-87℃（4.4kPa），74-74.5℃（3.47kPa），66-67℃（2.0kPa），62-63℃（1.6kPa），相对密度0.9366（25/4℃），0.9599（0/4℃），折射率1.4380。闪点（开杯）70℃。 |
别名和识别编码
| Chemical Name | 1,2-Dichloropropane |
|---|---|
| Synonym | CH3CON(CH3)2 Pr bichloruredepropylene n,n-dimethylacetamides { 1,2-二氯丙烷;氯化丙烯 (±)-1,2-dichloro-propane {Chemica 1,2-二氯丙烷 {Chemi 1,2-Dichlorpropan {Chemicalb SK 7176 PROPYLENE DICHLORIDE 乙酰二甲胺 Chlorinated C3 hydrocarbons bichloruredepropylene(french) 1,2-Dichloropropane Acetic acid dimethylacetamide NSC 3138 Bichlorure de propylene B 二氯丙烷 α,β-Dichloropropane nsc3138 N-乙酰二甲胺 {C N,N-二甲基乙酰胺, HPLC GRADE, 99.5+% 氯化丙烯 D-d Mixture alpha,beta-Propylene dichloride dichloro-1,2-propane NCI-C55141 1,2-二氯丙烷, 98% |
| MDL Number | MFCD00000868 |
| CAS Number | 78-87-5 |
| PubChem Substance ID | 87567081 |
| EC Number | 201-152-2 |
| Beilstein Registry Number | 1(4)195 |
| Merck Number | 7854 |
| Reaxys-RN | 1718880 |
| Chemical Name Translation | 1,2-二氯丙烷 |
| Wiswesser Line Notation | GY1&1G |
| LabNetwork Molecule ID | LN00223891 |
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分类
- {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
- {SA} Alpha Sort, Analytical Standards, Analytical/Chromatography, Chromatography, D, Environmental Standards, Fumigants, Insecticides, Nematicides,
- {SNA} Alpha Sort, Analytical
- {SNA} Alpha Sort, Analytical Standards, Analytical/Chromatography, Chromatography, D, Environmental Standards, Fumigants, Insecticides, Nematicides, Volatiles/ Semivolatiles, 农残和代谢标准品, 农残标准品
- {SNA} Additional St
产品应用
- 油类和脂肪的溶剂。干洗剂。脱脂剂。杀虫熏蒸混合剂。
相关文献及参考
- Short: II/25C
- Short: III/20a
- Short: II/5
- Merck: 14,7854
安全信息
GHS Symbol
- H332 Harmful if inhaled 吸入有害
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H302+H332
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P301+P312+P330
- P337+P313
- P403+P233
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P303+P361+P353
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P302+P352+P333+P313+P362+P364
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P304+P340+P312
- P273 Avoid release to the environment. 避免释放到环境中。
- P305+P351+P338+P337+P313
- P308+P311
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
- R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
- S24 Avoid contact with skin 避免皮肤接触；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- S2 Keep out of the reach of children 避免儿童触及；
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 130 gm/kg/2Y-I TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Skin and Appendages - tumors REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NTP-TR-263,1986
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 5 gm/kg TOXIC EFFECTS : Behavioral - sleep Liver - other changes REFERENCE : AJHYA2 American Journal of Hygiene. (Baltimore, MD) V.1-80, 1921-64. For publisher information, see AJEPAS. Volume(issue)/page/year: 16,325,1932
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 960 mg/kg TOXIC EFFECTS : Gastrointestinal - ulceration or bleeding from stomach Gastrointestinal - ulceration or bleeding from small intestine REFERENCE : ESKGA2 Eisei Kagaku. Hygienic Chemistry. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) V.1- 1953- Volume(issue)/page/year: 28,P31,1982
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rod
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 2 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C253,1991
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 860 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,98,1986
TYPE OF TEST : LCLo - Lowest
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 100 ug/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 5(Suppl 1),3,1983
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Rodent - mouse Lymphocyte DOSE/DURATION : 11600 ug/L REFERENCE : SCIEAS Science. (American Assoc. for the Advancement of Science, 1333 H St., NW, Washington, DC 20005) V.1- 1895- Volume(issue)/page/year: 236,933,1987
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 660 mg/L REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NTP-TR-263,1986
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Lung DOSE/DURATION : 3300 umol/L REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 9,401,1987
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 113 mg/L REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rabbit DOSE : 1950 mg/kg SEX/DURATION : female 7-19 day(s) after conception TOXIC EFFECTS : Reproductive - Maternal Effects - other effects REFERENCE : FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 28,18,1995
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 1250 mg/kg SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Maternal Effects - other effects REFERENCE : FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 28,18,1995
其他信息
- 下游产品:4-氟苯胺 --> 二苯基乙炔 --> 1-硫代磺酸钠基
- 用途四:用于药物合成的反应溶剂，合成纤维纺丝与合成树脂的溶剂，感光化学品发色剂的溶剂，涂料等的溶剂。催化剂。
- 蒸气密度:3.89 (vs air)
- F:
- 毒性分级:中毒
- MSDS 信息:1,2-二氯丙烷(78-87-5).msds
- Alfa Aesar:N,N-二甲基乙酰胺,HPLCGrade,99.5+% N,N-Dimethylacetamide, HPLC Grade, 99.5+%(127
- MOL 文件:127-19-5.mol
- 方法一:由丙烯与氯气在二氯丙烷中液相低温氯化
- 用途二:用作有机合成原料，油类、脂肪的溶剂，洗涤剂，树脂、农药的原料。经氨化可制得丙二胺。1,2-二氯丙烷和1,3-二氯丙烯，作为农药即滴滴混剂、D-D、Vidden D，[8003-19-8]。D-D为播前杀线虫剂，能有效地防治土壤线虫，包括根瘤线虫、草地线虫、刺线虫、剑线虫、螺旋线虫和甜菜线虫。当药剂施入15-20cm土壤深
- 有害影响和中毒症状:经常暴露于二甲基乙酰胺中的工人，观察到黄疸、肝损伤，但一般可迅速恢复。有人用本品作为抗癌药而大剂量口服时，引起的症状有抑郁、嗜眠、视听幻觉; 还可能出现心、肾和脑变性。DMA对鼠胚胎有毒性作用，对兔有致畸作用。
- 医学监护:就
- Acros Organics:N,N-二甲基乙酰胺 N,N-Dimethylacetamide, extra pure, 99.5%(127-19-5)
- 下游产品:1,2-丙二胺 --> 杀虫环 --> 1,3-二氯丙烯 --> 四氯丙烯 --> 2-氯丙酰氯
- 1,2-二氯丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 S0634 1,2-二氯丙烷(1mg/ml的甲醇溶液)[用于水分析] 1,2-Dichloropropane (1mg/ml in Methanol) [for Water Analysis] 1ML 240元 2014/06/02 D0398 1,2-二氯丙烷 1,2-Dichloropropane 25G 159元 2014/06/02 D0398 1,2-二氯丙烷 1,2-Dichloropropane 500G 658元
- MOL 文件:78-87-5.mol
- 上游原料:N,N-二甲基乙
- 爆炸物危险特性:与空气混合可爆
- 灭火剂:泡沫、干粉、二氧化碳
- 概述:N,N-二甲基乙酰胺又称乙酰基二甲胺、乙酰二甲胺，简称DMAC，是一种非质子高极性溶剂，有微氨气味，溶解力很强，可溶解的物质范围很广，能与水、芳香族化合物、酯、酮、醇、醚、苯和三氯甲烷等任意混溶，且能使化合物分子活化，因此广泛用作溶剂及催化剂。在溶剂方面作为高沸点、高闪点、热稳定性高、化学性
- MSDS 信息:Acetdimethylamide(127-19-5).msds
- 外观性质:无色液体，有类似氯仿的气味。
- Alfa Aesar:1，2-二氯丙烷,98% 1,2-Dichloropropane, 98%(78-87-5)
- N,N-二甲基乙酰胺价格(试剂级):更新日期 产品
- 有氯仿气味。微溶于水，水中溶解度: 3 g/L (20°C) ，溶于大多数常规有机溶剂。易燃。低毒，半数致死量（大鼠，经口）1900mg/kg。有刺激性。
- Sigma Aldrich:78-87-5(sigmaaldrich)
- 可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧排放有毒氮氧化物烟雾
- 海关编码:29241900
- 上游原料:N,N-二甲基乙酰胺 --> 丙烯
- 职业标准:TWA 350 毫克/ 立方米
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