Tert-Butyl 2-chloroacetate 氯乙酸叔丁酯
CAS 107-59-5 MFCD00000930
化学结构图
SMILES: CC(C)(C)OC(=O)CCl
化学属性
| Mol. Formula | C6H11ClO2 |
|---|---|
| Mol. Weight | 150.60 |
| Refractive index | 1.4210 to 1.4250 |
| Boiling Point | 60°C/15mmHg |
| Density | 1.053 |
| Flash Point | 28°C(lit.) |
| TSCA | Yes |
| Solubility | 溶于乙醚。 |
别名和识别编码
| Chemical Name | Tert-Butyl 2-chloroacetate |
|---|---|
| CAS Number | 107-59-5 |
| PubChem Substance ID | 66052 |
| EC Number | 203-506-1 |
| Beilstein Registry Number | 2(3)444 |
| MDL Number | MFCD00000930 |
| Reaxys-RN | 1753006 |
| Merck Number | 1563 |
| Synonym | 3-Amino-1,4-dimethyl-5h-pyrido[4,3-β]indole-13C2,15N Acetate 氯乙酸第三丁酯 aceticacid,chloro-,1,1-dimethylethylester CHLOROACETIC ACID TERT-BUTYL ESTER tert.-Butylchloracetat t-butyl 2-chloroacetate chloro-acetic acid tert-butyl ester 氯乙酸叔丁酯 Chloressigsäure-tert-butylester TERT-BUTYL CHLOROACETATE Chloroacetic acid 1,1-dimethylethyl ester |
| Chemical Name Translation | 氯乙酸叔丁酯 |
| LabNetwork Molecule ID | LN01306963 |
| InChI | InChI=1S/C6H11ClO2/c1-6(2,3)9-5(8)4-7/h4H2,1-3H3 |
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- {uni_hamburg} no charge; ester; 1fragment
- {SNA} Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
- Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
产品应用
- 用于缩水甘油酸酯的缩合。
相关文献及参考
- The reaction with imines has also been used in the preparation of aziridines by a nitrogen analogue of the Darzens reaction: J. Chem. Soc., Chem. Commun., 602 (1977).
- Merck:14,1563 Beilstein:2(3)444
- Short: III/38B
- Short: EINECS
- Merck:14,1563
- Darzens condensation (see Ethyl chloroacetate, A15554) with carbonyl compounds gives t-butyl glycidic esters, which readily undergo decarboxylative elimination to the homologous aldehydes. See, for example: Rec. Trav. Chim., 89, 18 (1970).
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H331 Toxic if inhaled 吸入中毒
- H312 Harmful in contact with skin 皮肤接触有害
- H302 Harmful if swallowed 吞食有害
- H302+H312
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P301+P312+P330
- P337+P313
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P303+P361+P353
- P302+P352+P312+P362+P364
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P403+P235
- P304+P340+P312
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P305+P351+P338+P337+P313
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R50/53
- R34 Causes burns 会导致灼伤
其他信息
- MOL 文件:107-59-5.mol
- 用途一:用作医药、农药、染料中间体
- Acros Organics:氯乙酸叔丁酯 tert-Butyl chloroacetate, 97%(107-59-5)
- 图谱信息:氯乙酸叔丁酯(107-59-5)红外图谱(IR1) 氯乙酸叔丁酯(107-59-5)质谱(MS) 氯乙酸叔丁酯(107-59-5)核磁图( 1 HNMR) 氯乙酸叔丁酯(107-59-5)核磁图( 13 CNMR)
- 海关编码:29154000
- Sigma Aldrich:107-59-5(sigmaaldrich)
- 上游原料:氯乙酰氯
- Alfa Aesar:氯乙酸叔丁酯,98% tert-Butyl chloroacetate, 98%(107-59-5)
- 外观性质:无色液体。
- F:19-21
- TCI Shanghai:氯乙酸叔丁基酯 tert-Butyl Chloroacetate,>;96.0%(GC)(107-59-5)
- 氯乙酸叔丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1267 氯乙酸叔丁酯 tert-Butyl Chloroacetate 25ML 331元 2014/06/02 C1267 氯乙酸叔丁酯 tert-Butyl Chloroacetate 500ML 2820元 2010/06/21 347235000 氯乙酸叔丁酯 tert-Butyl chloroacetate 97% 500 GR 2743元
- 方法一:将叔丁醇加入氯乙酰氯和N,N-二甲基苯胺的混合物中，温度保持在30℃以下。将反应物倾入水中，洗涤、干燥后进行减压分馏，收集48-49℃（1.46kPa）馏分，得氯乙酸叔丁酯，产率63%。
- 用途二:用于缩水甘油酸酯的缩合。
- MSDS 信息:氯醋酸特丁酯(107-59-5).msds
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