1,3-Dichloropropane 1,3-二氯丙烷

CAS 142-28-9 MFCD00000999

化学结构图

142-28-9
SMILES: ClCCCCl

化学属性

Mol. FormulaC3H6Cl2
Mol. Weight113
Density1.19
Refractive index1.4460 to 1.4490
Boiling Point120-122
Melting Point-99
Flash Point21°C(lit.)
TSCAYes
Solubility0.8 G/L (20 ºC)

别名和识别编码

Chemical Name1,3-Dichloropropane
Synonym 1 1,3-DICHLOROPROPANE 1,3-DICHLOROPROPANE, 1X1ML, MEOH, 5000UG /ML 1,3-Dichlor-propan 1,3-Dichlorpropan 1,3-Propylenechloride 1,3-dichloropropane solution 1,3-dichlroropropane 1.3-二氯丙烷 1.3-DICHLOROPROPANE 1,3-二氯丙烷 AKOS BBS-00004406 CH2ClCH2CH2Cl PROPYLENE DICHLORIDE TRIMETHYLENE DICHLORIDE Trimethylendichlorid Trimethylene dichloride propane, 1,3-dichloro- propane,1,3-dichloro propylendichloride trimethylene dichloride 二氯三亚甲基
CAS Number142-28-9
EC Number205-531-3
Beilstein Registry Number1(4)196
MDL NumberMFCD00000999
PubChem Substance ID87567082
Reaxys-RN505960
Chemical Name Translation1,3-二氯丙烷
Wiswesser Line NotationG3G
LabNetwork Molecule IDLN00223977
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分类

  • {SNA} Analytical Standards, Chromatography, D, Environmental Standards, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} Analytical St
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards,
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, D, DIA - DIC, Environmental Standards, 农残和代谢标准品, 按照字母排序
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Chromatography,

产品应用

  • 用作有机合成中间体,溶剂。

相关文献及参考

  • Short: II/25C
  • Short: III/20a
  • Beilstein: 1,IV,196

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S29 Do not empty into drains 不要排入下水道;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20 Harmful by inhalation 吸入有害
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R52/53
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTX9660000
Packing GroupII
UN Number 1279 1993
Hazard Codes 3 F,Xn,T
Storage condition 0-10 Refrigerator 储存温度2-8℃ 0-10°C 2-8°C
Hazard Class3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Liver - other changes
   Blood - hemorrhage
REFERENCE :
   AJHYA2 American Journal of Hygiene.  (Baltimore, MD)  V.1-80, 1921-64.  For
   publisher information, see AJEPAS.  Volume(issue)/page/year: 16,325,1932

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3600 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - ulceration or bleeding from stomach
   Gastrointestinal - ulceration or bleeding from small intestine
REFERENCE :
   ESKGA2 Eisei Kagaku.  Hygienic Chemistry.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  V.1-    1953-
   Volume(issue)/page/year: 28,P31,1982

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 371,185,1996

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 umol/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 2,59,1980

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 371,185,1996

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 6600 umol/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9,401,1987

其他信息

  • 毒性分级:中毒
  • 下游产品:1,3-双(二苯基膦)丙烷 --> 1,3-双(二苯基膦丙烷)二氯化镍 --> 双(二亚芐基丙酮)钯 --> 二(乙酰丙酮)钯(II) --> 杀虫磺
  • 可燃性危险特性:遇明火、高温、氧化剂较易燃; 受热分解有毒光气; 燃烧产生有毒氯化物烟雾
  • TCI Shanghai:1,3-二氯丙烷(1mg/ml的甲醇溶液)[用于水分析] 1,3-Dichloropropane (1mg/ml in Methanol) [for Water Analysis](142-28-9)
  • Acros Organics:1,3-二氯丙烷 1,3-Dichloropropane, 99%(142-28-9)
  • Sigma Aldrich:142-28-9(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 上游原料:盐酸 --> 丙二醇 --> 1,3-丙二醇 --> D-D混剂
  • MOL 文件:142-28-9.mol
  • 外观性质:无色液体,有类似氯仿的气味。
  • 用途二:用作溶剂和洗涤剂及色谱分析标准物质
  • 急性毒性:口服- 狗 LDL0: 3000 毫克/ 公斤
  • 类别:易燃液体
  • 挥发性有机化合物(VOCs)单组分标准液
  • 图谱信息:1,3-二氯丙烷(142-28-9)红外图谱(IR1) 1,3-二氯丙烷(142-28-9)质谱(MS) 1,3-二氯丙烷(142-28-9)核磁图( 13 CNMR)
  • 方法一:由丙二醇与盐酸作用而得。
  • 1,3-二氯丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K8227001 1.2-二氯丙烷 250ml 450元 2011/08/23 40013761 1,3-二氯丙烷 2ml 45元 2011/04/16 D0399 1,3-二氯丙烷 1,3-Dichloropropane 250ML 2060元
  • 易溶于醇和醚,微溶于水,水中溶解度:0.8 g/L (20°C)
  • 用途一:用于有机合成
  • Alfa Aesar:1,3-二氯丙烷,95% 1,3-Dichloropropane, 95%(142-28-9)
  • MSDS 信息:1,3-二氯丙烷(142-28-9).msds
  • 用途三:用作有机合成中间体,溶剂。

系列性分类


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