• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} Light-Emitting Dopants and Fluorescent Dyes, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials, 材料科学
• {SNA} Light-Emitting Dopants and Fluorescent Dyes, Materials Science, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials
• {SA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
• {Chemicalbook} 染料: 溶剂染料: 溶剂染料
• Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
• {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 14ring; ketone; alcohol; 1fragment

产品应用

• 有机合成，制造蒽醌还原染料及其他中间体。本身为分散棕GL（C.I.58050）。

相关文献及参考

• Merck: 14,8064 Beilstein:8,450
• Merck: 14,8064
• Short: III/35D2
• Short: III/20a
• Short: II/3

安全信息

GHS Symbol

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(7),93,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03274

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A067-313

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 21(12),27,1977

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,203,1976

其他信息

• 上游原料:硫酸 --> 苯酐 --> 1,4-苯二酚 --> 硼酸 --> 4-氯苯酚
• 常规方法:用铁桶内衬塑料袋包装。每桶净重20～50kg。贮存在干燥、通风处。应防晒、防潮。按危险物品规定贮运。
• MOL 文件:81-64-1.mol
• 方法二:苯酐和对苯二酚在硼酸存在下于浓硫酸中缩合，再经稀释、水洗、中和、氧化、压滤，得成品。原料消耗定额：对苯二酚550kg/t、苯酐1280kg/t、硼酸550kg/t、硫酸4300kg/t。
• 下游产品:1,4-二氨基蒽醌 --> 酸性蓝80 --> 1,4-二氨基蒽醌隐色体 --> 酸性媒介灰 BS --> 弱酸嫩黄G --> 分散蓝 3 --> 弱酸绿GS --> 酸性绿 25 --> 透明蓝 --> 溶剂蓝 36 --> 溶剂蓝 104 --> 溶剂绿 3 --> 溶剂蓝 35 --> 溶剂紫 13 --> 溶剂蓝 97 --> C.I.酸性绿27 --> 溶剂蓝 122 --> 溶剂蓝 59 --> 酸性紫43 --> 分散蓝 14 --> 分散染料
• 方法一:以苯酐和对氯苯酚为原料，将两者缩合、闭环，经水解得产物。经过滤、干燥、粉碎得成品。也可以苯酐和对苯二酚为原料，经缩合、闭环得产物。经过滤、干燥、粉碎得成品。
• 在高真空中升华。1g溶于13g的沸冰乙酸。溶于乙醇呈红色，溶于乙醚呈棕色并显黄色荧光，溶于碱和氨水呈紫色。遇二氧化碳生成黑色沉淀。有刺激性。
• 用途二:透明橙 2G 主要用于油品着色。也可用于各种塑料，树脂及其制品着色。
• MSDS 信息:1,4-Dihydroxy-9,10-anthracenedione(81-64-1).msds
• TCI Shanghai:1,4-二羟基蒽醌 Quinizarin,>;95.0%(LC)(81-64-1)
• Alfa Aesar:1,4-二羟基蒽醌,96% 1,4-Dihydroxyanthraquinone, 96%(81-64-1)
• 用途四:有机合成，制造蒽醌还原染料及其他中间体。本身为分散棕GL（C.I.58050）。
• 1,4-二羟基蒽醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30062780 1，4-二羟基蒽醌;1,4-二羟基-9,10-蒽二酮 25g 52元 2011/08/23 30062781 1，4-二羟基蒽醌;1,4-二羟基-9,10-蒽二酮 25g 49元 2011/04/16 D0243 醌茜 Quinizarin 25G 146元
• 用途一:用于制造还原染料、分散染料及活性染料的中间体
• 图谱信息:1,4-二羟基蒽醌(81-64-1)质谱(MS) 1,4-二羟基蒽醌(81-64-1)核磁图( 13 CNMR) 1,4-二羟基蒽醌(81-64-1)红外图谱(IR1) 1,4-二羟基蒽醌(81-64-1)核磁图( 1 HNMR) 1,4-二羟基蒽醌(81-64-1)红外图谱(IR2)
• 用途三:该品是重要的染料中间体。本身为分散棕GL（C.I.58050）。用来制造分散蓝HSR、分散蓝5R、分散蓝B、分散深蓝RB、酸性蒽醌蓝R、弱酸艳蓝RAW弱酸绿GS、还原灰BG、还原棕BR等；以及用来生产中间体1,4-二氨基蒽醌。由1,4-二羟基醌经磺化可得1,4-二羟基蒽醌-2-磺酸。
• Sigma Aldrich:81-64-1(sigmaaldrich)
• color:red-brown
• 蒸气密度:8.3 (vs air)
• 蒸气压:1 mm Hg ( 196.7 °C)
• 防护措施:毒性和蒽醌相似。燃烧时火焰带有腐蚀性。对皮肤能引起过敏。操作人员应穿戴防护用具。当皮肤与之接触时需用大量水冲洗。参见“蒽醌”。
• Acros Organics:1,4-二羟基蒽醌 1,4-Dihydroxyanthraquinone, 96%(81-64-1)
• 色指数:58050