9-(Chloromethyl)Anthracene 9-氯甲基蒽

CAS 24463-19-2 MFCD00001263

化学结构图

24463-19-2
SMILES: ClCC1C2=CC=CC=C2C=C2C=CC=CC2=1

化学属性

Mol. FormulaC15H11Cl
Mol. Weight227
Melting Point136-141
TSCANo
Density1.422

别名和识别编码

Chemical Name9-(Chloromethyl)Anthracene
MDL NumberMFCD00001263
PubChem Substance ID87563152
Beilstein Registry Number1873394
EC Number246-274-7
CAS Number24463-19-2
Synonym ICR 448 9-氯甲基蒽 9-Chloromethylanthracene
Reaxys-RN1873394
Chemical Name Translation9-氯甲基蒽
Wiswesser Line NotationL C666J B1G
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分类

  • {SNA} Alphabetical, Carbohydrate Labels, Carbohydrate Labels for Chromatography, Detection, Fluorescent Labels, Functional Group Reactive Labels, Functional Group Reactive Labels for Chromatography, Wavelength Index, 发光化合物及其检测, 生化试剂, 荧光探针,标记,粒子和染色剂
  • {SNA} Alphabetical, Biochemicals and Reagents, Carbohydrate Labels, Carbohydrate Labels for Chromatography, Detection, Fluorescent Labels,
  • {SNA} Derivatization agents, Organic and Printed Electronics, Synthetic Intermediates, Synthetic Tools and Reagents, 发光化合物及其检测, 材料科学, 生化试剂

产品应用

  • Protecting reagent for carboxylic acids, phenols, thiophenols, and mercaptans.

相关文献及参考

  • Reagent for the protection of carboxylic acids, alcohols, phenols and thiols as their 9-anthrylmethyl derivatives, which are stable to mild acid or base, but specifically cleaved by NaSMe: J. Am. Chem. Soc., 96, 590 (1974). For use in N-protection, see: Aust. J. Chem., 18, 1699 (1965).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSCA9600000
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Packing GroupII
UN Number 3261
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Light Sensitive
Hazard Codes 8
Hazard Class8
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2267 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   36,2423,1976

系列性分类