Bis(cyclohexanone)oxaldihydrazone 双环己酮草酰二腙

CAS 370-81-0 MFCD00001659

化学结构图

370-81-0
SMILES: O=C(NN=C1CCCCC1)C(=O)NN=C1CCCCC1

化学属性

Mol. FormulaC14H22N4O2
Mol. Weight278.35
Melting Point210-214 °C
TSCAYes
Density1.29
SolubilityInsoluble in water.
Boiling Point421.17 °C at 760 mmHg

别名和识别编码

Chemical NameBis(cyclohexanone)oxaldihydrazone
Synonym Cuprizone {LY} Cuprizone {} {LY} Cuprizone {} {} {LY} Cuprizone {} {} {} {LY} Cuprizone {} {} {} {} {LY} Cuprizone {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprizone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00001659
PubChem Substance ID9723
Beilstein Registry Number2388004
CAS Number370-81-0
EC Number206-729-2
Reaxys-RN2388004
Chemical Name Translation双环己酮草酰二腙
Wiswesser Line NotationL6YTJ AUNMVVMNU- AL6YTJ
LabNetwork Molecule IDLN00196002
InChIInChI=1S/C14H22N4O2/c19-13(17-15-11-7-3-1-4-8-11)14(20)18-16-12-9-5-2-6-10-12/h1-10H2,(H,17,19)(H,18,20)
Canonical SMILESO=C(C(N/N=C1CCCCC\1)=O)N/N=C2CCCCC/2
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分类

  • {SNA} B, Cell Biology, Hematology and Histology, Stains & Dyes, A to Z, Stains and Dyes
  • {SNA} Analytical/Chromatography, Ion Sensor Materials, Ionophores Potentiometric for ISE
  • {SA} Analytical/Chromatography, Ion Sensor Materials, Ionophores Potentiometric for ISE
  • {SNA} B, Hematology and Histology, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学
  • Analytical Reagents, Analytical/Chromatography, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {SNA} Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱, 分析试剂
  • {SNA} B, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学,

产品应用

  • A stain used in the quantitative spectroscopic determination of copper.

相关文献及参考

  • Beilstein: 7,IV,25
  • Reagent for spectrophotometric determination of Cu(II): Anal. Chem., 38, 911 (1966).

安全信息

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSRO2520000
WGK Germany3
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
GHS Symbol
Storage condition 2-8°C {LY} 2-8°C 2-8℃储存 Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-
Hazard Codes Xn
TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 14 gm/kg/14D (Continuous)
REFERENCE :
   EJBCAI European Journal of Biochemistry.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  V.1-    1967-
   Volume(issue)/page/year: 47,313,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 40 gm/kg
SEX/DURATION            : female 3-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - stillbirth
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   8,512,1966

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 24 gm/kg
SEX/DURATION            : female 3-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - live birth index (measured after birth)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   8,512,1966

其他信息

  • 用途一:比色分析铜,光谱测定高铜及氨基酸。
  • MSDS 信息:Bis(cyclohexanone)oxaldihydrazone(370-81-0).msds
  • 有毒。能溶于热甲醇和乙醇,不溶于水。有刺激性。
  • Alfa Aesar:双(环己酮)草酸二腙酯,98% Bis(cyclohexanone) oxaldihydrazone, 98%(370-81-0)
  • Acros Organics:草酰双(环己基亚肼) Oxalic acid bis(cyclohexylidenehydrazide), 98%(370-81-0)
  • Sigma Aldrich:370-81-0(sigmaaldrich)
  • 图谱信息:双环己酮草酰二腙(370-81-0)红外图谱(IR1) 双环己酮草酰二腙(370-81-0)核磁图( 1 HNMR) 双环己酮草酰二腙(370-81-0)质谱(MS) 双环己酮草酰二腙(370-81-0)核磁图( 13 CNMR) 双环己酮草酰二腙(370-81-0)红外图谱(IR2)
  • MOL 文件:370-81-0.mol
  • 外观性质:白色结晶。有毒。能溶于热甲醇和乙醇,不溶于水。有刺激性。熔点:213℃
  • 海关编码:29280090
  • TCI Shanghai:双环己酮草酰二腙 Bis(cyclohexanone) Oxalyldihydrazone,>;98.0%(N)(370-81-0)
  • 双环己酮草酰二腙价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30023014 双环己酮草酰二腙 25g 38.6元 2011/04/16 B0476 双(环己酮)草酰二腙 Bis(cyclohexanone) Oxalyldihydrazone 25G 517元 2011/04/16 B0476 双(环己酮)草酰二腙 Bis(cyclohexanone) Oxalyldihydrazone 1G 102元

系列性分类


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