2,3-Dichloro-1,4-Naphthoquinone 2,3-二氯-1,4-萘醌

CAS 117-80-6 MFCD00001677

化学结构图

117-80-6
SMILES: O=C1C(Cl)=C(Cl)C(=O)c2ccccc21

化学属性

Mol. FormulaC10H4Cl2O2
Mol. Weight227
Melting Point194.0 to 198.0 deg-C
Density1.54
TSCAYes
Boiling Point275°C
Solubility0.008 G/L
Flash Point275°C/2mm

别名和识别编码

Chemical Name2,3-Dichloro-1,4-Naphthoquinone
Synonym 2,3-DICHLORO-1,4-NAPHTHAQUINONE 1,4-naphthalenedione, 2,3-dichloro- CNQ Sanquinon Dichlone USR 604 {hazar 2,3-dichloronaphthoquinone Dichloronaphthoquinone 2，3-Dichloro-1，4-naphthalenedione U.s. rubber 604 2,3-二氯-1,4-萘醌 二氯萘醌 3-二氯-1 dichlone (ISO) Phygon DICHLON 2,3-二氯-1,4-萘醌 2,3-DICHLORO-1,4-NAPHTHOQUINONE Phygon Seed Protectant Quintar Dichlon (ISO) 2，3-二氯-1，4-萘二酮 dichlone USR 604(R) {uni 2 4-萘醌 二氯萘醌 'LGC' (1114) Algistat ENT 3,776 2,3-dichloro-1,4-naphthoquinone 2,3-dichloro-(1,4)naphthoquinone 非冈 三氯萘醌 2,3-Dichloro-1,4-naphthaquinone 2,3-Dichloro-1,4-naphthoquinone (dichlone) Uniroyal 2,3-dichloro-1,4-naphthalenedione AURORA KA-5010 Phygon paste Phygon seed protectant 2,3-Dichloro-1,4-naphthoquinone 2,3-Dichlor-1,4-naphthalindion Phygon XL PHYGON PASTE(R) 1,4-Naphthoquinone, 2,3-dichloro- 2,3-Dichloro-1,4-dihydro-1,4-dioxonaphthalene Latka 604 PHYGON XL(R) 1,4-naphthoquinone, 2,3-dichloro- PHYGON(R) 2,3-Dichloro-1,4-naphthoquinone; Dichloronaphthoquinone 2,3-Dichlor-1,4-naphthochinon 2,3-Dichloro-1,4-naphthalenedione 2,3-Dichloronaphthoquin 2,3-Dichlor-1,4-naftochinon 2,3-Dichloro-alpha-naphthoquinone
CAS Number117-80-6
PubChem Substance ID8342
EC Number204-210-5
Beilstein Registry Number7,729
MDL NumberMFCD00001677
Reaxys-RN1073511
Merck Number3045
Chemical Name Translation2,3-二氯-1,4-萘醌
Wiswesser Line NotationL66 BV EVJ CG DG
LabNetwork Molecule IDLN00192127
InChIInChI=1S/C10H4Cl2O2/c11-7-8(12)10(14)6-4-2-1-3-5(6)9(7)13/h1-4H
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分类

  • {SNA} Algicides, Analytical Standards, D, Fungicides, Quinones,
  • Algicides, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, D, DIA - DIC, Environmental Standards, Fungicides, Pesticides, Pesticides & Metabolites, Quinones
  • {SNA} Algicides, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography,
  • {SNA} Algicides,
  • {SNA} Building Blocks, C10, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • 非内吸性杀菌剂，主要用于种子处理和叶面喷洒，但不能用于豆科植物种子处理。叶面喷洒对防治苹果的黑星病、豆的炭疽病、蕃茄晚疫病有效。该品也可作水田除草剂的原料，木、棉纤维、橡胶等的防霉剂。

相关文献及参考

  • Short: III/20a
  • Merck: 14,3045 Beilstein:7,729
  • Short: III/20b
  • Reagent for the spectrophotometric determination of hydrazides: Anal. Chem., 48, 1536 (1976).
  • Merck: 14,3045

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn;N Xn,N
Hazard statements
  • H301+H311
  • H315 Causes skin irritation 会刺激皮肤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSQL7525000
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P302+P350
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
UN Number UN 2811 6.1/PG 3 2761/2811 2811
Packing GroupIII
Hazard Class6.1
Storage condition 密封保存
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 22 mg/kg
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3300 mg/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A137,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 440 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,47,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 16(5),52,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Tumorigenic - active as anti-cancer agent
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 26

其他信息

  • 外观性质:黄色针状结晶，无气味。
  • 可燃性危险特性:受热分解有毒氯化物气体
  • Sigma Aldrich:117-80-6(sigmaaldrich)
  • MOL 文件:117-80-6.mol
  • Acros Organics:2,3-二氯-1,4-萘醌 2,3-Dichloro-1,4-naphthoquinone, 98%(117-80-6)
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • Alfa Aesar:2,3-二氯-1,4-萘醌,98% 2,3-Dichloro-1,4-naphthoquinone, 98%(117-80-6)
  • 图谱信息:2,3-二氯-1,4-萘醌(117-80-6)红外图谱(IR1) 2,3-二氯-1,4-萘醌(117-80-6)核磁图( 1 HNMR) 2,3-二氯-1,4-萘醌(117-80-6)质谱(MS) 2,3-二氯-1,4-萘醌(117-80-6)红外图谱(IR2)
  • 上游原料:溴 --> 发烟硫酸 --> 铁粉 --> 三氯化铁 --> 稀硫酸 --> 1,3-二硝基苯 --> 对氨基萘磺酸 --> 1,4-萘醌
  • TCI Shanghai:2,3-二氯-1,4-萘醌 2,3-Dichloro-1,4-naphthoquinone,>;95.0%(GC)(T)(117-80-6)
  • MSDS 信息:二氯萘醌(117-80-6).msds
  • 能升华，可溶于邻二甲苯（4%），邻二氯苯，微溶于丙酮，苯及醚类，难溶于冷乙醇，易溶于热乙醇，25℃水中溶解度为0.1ppm。对酸稳定，遇碱会水解。
  • 灭火剂:砂土、干粉、泡沫
  • 2,3-二氯-1,4-萘醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0384 2,3-二氯-1,4-萘醌 2,3-Dichloro-1,4-naphthoquinone 500G 1430元 2014/06/02 D0384 2,3-二氯-1,4-萘醌 2,3-Dichloro-1,4-naphthoquinone 25G 200元 2010/06/21 113480250 2,3-二氯-1,4-萘醌 2,3-Dichloro-1,4-naphthoquinone 98% 25 GR 116元
  • 类别:农药
  • 海关编码:29147090
  • 职业标准:STEL 0.5 毫克/立方米
  • 用途一:用作医药、农药、染料中间体
  • 毒性分级:高毒
  • 急性毒性:口服-大鼠 LD50: 160 毫克/公斤; 口服-小鼠 LD50: 440 毫克/公斤
  • 方法一:由1,4-萘醌氯化而得。氯化操作在乙酐或二硝基苯或醇类、酚类、碳氢化合物溶剂中进行，催化剂为溴素或铁粉和氯化铁。也可由1，4-氨基萘磺酸在50%稀硫酸溶液中，以铁为催化剂，在80℃进行氯化而得。
  • 用途二:非内吸性杀菌剂，主要用于种子处理和叶面喷洒，但不能用于豆科植物种子处理。叶面喷洒对防治苹果的黑星病、豆的炭疽病、蕃茄晚疫病有效。该品也可作水田除草剂的原料，木、棉纤维、橡胶等的防霉剂。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C10 - Ketones
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Fungicides - Pesticides
  8. Quinones - Fungicides
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents

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