(Methylthio)Acetonitrile (甲硫基)乙腈

CAS 35120-10-6 MFCD00001925

化学结构图

35120-10-6
SMILES: CSCC#N

化学属性

Mol. FormulaC3H5NS
Mol. Weight87
Refractive index1.4800 to 1.4840
Boiling Point60°C/13mmHg(lit.)
Density1.039 g/mL at 25 °C(lit.)
Flash Point68°C(lit.)
TSCANo

别名和识别编码

Chemical Name(Methylthio)Acetonitrile
CAS Number35120-10-6
PubChem Substance ID87572922
EC Number252-383-0
MDL NumberMFCD00001925
Reaxys-RN1738015
Synonym (Methylmercapto)-acetonitril (Methylthio)-acetonitrile {uni_hamburg} (methylthio)acetonitrile (Methylmercapto)acetonitrile (甲硫基)乙腈 Cyanomethyl methyl sulfide methylsulfanyl-acetonitrile S-Methyl-thioglykolsäurenitril methylthioacetonitrile Acetonitrile, (methylthio)-
Beilstein Registry Number1738015
Chemical Name Translation(甲硫基)乙腈
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分类

  • {uni_hamburg} no charge; sulfide; 1fragment
  • Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
  • {SA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: EINECS
  • C-Silylation with TMS-OTf and Peterson olefination with carbonyl compounds provides a route to ɑ-cyano vinyl sulfides, which are useful, highly reactive Michael acceptors: Synth. Commun., 18, 2111 (1988):
  • Short: II/14a

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P304+P340+P310
  • P403+P235
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340+P312
  • P305+P351+P338
Signal word Warning
UN Number 1760
Storage condition 0-10 0-10°C
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupII
Hazard Class8

系列性分类


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