2-Isopropoxyphenol 2-异丙氧基苯酚

CAS 4812-20-8 MFCD00002184

化学结构图

4812-20-8
SMILES: CC(C)OC1CCCCC1O

化学属性

Mol. FormulaC9H12O2
Mol. Weight152.19
Refractive indexn20/D 1.514(lit.)
Boiling Point100-102 °C at 11 mmHg
Density1.03
Flash Point87°(188°F)
TSCAYes
Appearance 2-异丙氧基苯酚为无色透明的油状液体,b.p. 100~102℃/1.46 kPa,n 1.5140,相对密度 1.030,不溶于水,溶于苯等有机溶剂。 D 20

别名和识别编码

Chemical Name2-Isopropoxyphenol
CAS Number4812-20-8
PubChem Substance ID20949
EC Number225-379-1
MDL NumberMFCD00002184
Beilstein Registry Number1937063
Synonym 2-Isopropoxyphenol {LY} 2-Isopropoxyphenol {} {LY} 2-Isopropoxyphenol {} {} {LY} 2-Isopropoxyphenol {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation2-异丙氧基苯酚
LabNetwork Molecule IDLN00223403
InChIInChI=1S/C9H12O2/c1-7(2)11-9-6-4-3-5-8(9)10/h3-7,10H,1-2H3
Canonical SMILESOC1=CC=CC=C1OC(C)C
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分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 氨基甲酸酯类杀虫剂
  • {SNA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Beil. 6 ,III,4209
  • Aldrich MSDS 1 , 1117:A / Corp MSDS 1 (1), 2030:B / FT-IR 2 (2), 1840:B / FT-IR 1 (1), 1172:A / FT-NMR 1 (2), 248:A / IR-Spectra (3), 703:H / NMR-Reference 2 (1), 870:D / RegBook 1 (1), 1267:D / Structure Index 1 , 192:B:5 / Vapor Phase 3 , 1005:A

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 2-异丙氧基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 209220050 2-异丙氧基苯酚 2-Isopropoxyphenol 97% 5 GR 537元 2010/06/21 209220250 2-异丙氧基苯酚 2-Isopropoxyphenol 97% 25 GR 1115元 2010/05/25 L07360 2-异丙氧基苯酚, 97% 2-Isopropoxyphenol, 97% 5g 267元
  • 上游原料:碳酸钾 --> 邻苯二酚 --> 稀盐酸 --> 2-溴丙烷 --> 2-氯丙烷
  • 图谱信息:2-异丙氧基苯酚(4812-20-8)核磁图( 13 CNMR) 2-异丙氧基苯酚(4812-20-8)核磁图( 1 HNMR) 2-异丙氧基苯酚(4812-20-8)质谱(MS) 2-异丙氧基苯酚(4812-20-8)红外图谱(IR1)
  • MSDS 信息:2-(1-Methylethoxy)phenol(4812-20-8).msds
  • 下游产品:残杀威
  • Alfa Aesar:2-异丙氧基苯酚,97% 2-Isopropoxyphenol, 97%(4812-20-8)
  • MOL 文件:4812-20-8.mol
  • Sigma Aldrich:4812-20-8(sigmaaldrich)
  • 用途一:2-异丙氧基苯酚又名2-(1-甲基乙氧基)苯酚,是合成氨基甲酸酯类杀虫剂残杀威的重要中间体。
  • 方法一:2-异丙氧基苯酚是由邻苯二酚和异丙基溴反应制得。 将异丙基溴慢慢滴加到正在回流的邻苯二酚、碳酸钾、丁酮和相转移催化剂的混合物中,继续回流一定的时间,然后蒸出绝大部分丁酮(85%),加足量的水溶解固体盐,再以苯萃取,萃取液用稀氢氧化钠溶液萃取,该萃取液用稀盐酸中和后再用苯萃取,氯化钙干燥,蒸去绝大部分苯,减压蒸馏,收集100~102℃/1.46kPa的馏分,收率>;60%(回流32h产率>;60%,回流8h产率为54%)。若用异丙基氯代替异丙基溴,可以降低成本,但工艺上要采用高压釜反应,国内邻异丙氧基苯酚采用异丙基氯与邻苯二酚反应的工艺。
  • Acros Organics:2-异丙氧基苯酚 2-Isopropoxyphenol, 97%(4812-20-8)

系列性分类


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